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JOURNAL OF SYNTHETIC CRYSTALS ›› 2009, Vol. 38 ›› Issue (6): 1522-1526.

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Influence of Zn~(2+) on the Structure and Magnetic Properties of Hexagonal Strontium Ferrite

JIN Ming-lin;ZHU Cun-fu;BAO Zong-hong;QIAN Hui-chun;CHEN Qi-zhong   

  • Online:2009-12-15 Published:2021-01-20

Abstract: Strontium ferrites with La, Co and Zn substitution were prepared by conventional ceramic method, and the influence of Zn~(2+)on the structure and magnetic properties of hexagonal strontium ferrites had been investigated. The XRD results show that ferrites remain a hexagonal structure with the content of Zn~(2+)increasing, lattice parameter a was gradual increased and c first increased,then decreased with x increasing. SEM results show the grains represented an orderly plate, many of them even were hexagonal shape. The sizes of grains were gradual increased with the increasing content of Zn~(2+). By magnetic properties measurement, Br and Hcj both were 436 mT, 343 kA/m when x=0.15. It demonstrates the antiparallel magnetic moments can be effective decreased and saturation magnetization is increased, so the magnetic properties have been improved.

Key words: Strontium ferrites with La, Co and Zn substitution were prepared by conventional ceramic method, and the influence of Zn~(2+)on the structure and magnetic properties of hexagonal strontium ferrites had been investigated. The XRD results show that ferrites remain a hexagonal structure with the content of Zn~(2+)increasing, lattice parameter a was gradual increased and c first increased,then decreased with x increasing. SEM results show the grains represented an orderly plate, many of them even were hexagonal shape. The sizes of grains were gradual increased with the increasing content of Zn~(2+). By magnetic properties measurement, Br and Hcj both were 436 mT, 343 kA/m when x=0.15. It demonstrates the antiparallel magnetic moments can be effective decreased and saturation magnetization is increased, so the magnetic properties have been improved.

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