Hydrothermal Synthesis of CsxWO3 Nanorods and Their Infrared Absorption Properties

Abstract

Abstract: Cs_xWO₃ nanrods have attracted extensive attention due to their excellent near-infrared absorption properties. However, the Cs_xWO₃ nanorods synthesized via hydrothermal method are easy to form equiaxed nanoparticles, and the reaction temperature is high, followed by post-treatment. The Cs_0.2WO₃ nanorods with diameter and length of 10~20 nm and 100~250 nm were successfully hydrothermal synthesized via using ammonium tungstate ((NH₄)₆ W₇O₂₄·6H₂O), cesium chloride (CsCl), hydrochloride acid (HCl), oleylamine (C₁₈H₃₇N) as reactants in this paper. The effects of solvents, reaction route and amount of HCl on the phase and morphology of Cs_0.2WO₃ nanorods were investigated, followed by the discussion of the formation mechanism of Cs_0.2WO₃ nanorods and the test of infrared absorption properties of Cs_0.2WO₃ nanorods. The results show adding excess or little HCl are harmful for the synthesis of Cs_0.2WO₃. Changing the addition order of HCl and CsCl, following the decrease of reaction rate among (NH₄)₆ W₇O₂₄, CsCl and HCl, is benefit for the formation of Cs_0.2WO₃ nanorods. The infrared absorption test show Cs_0.2WO₃ nanorods are better than equiaxed Cs_0.2WO₃ nanoparticles.

Key words: nanorod, hydrothermal synthesis, infrared absorption, Cs_xWO₃, formation mechanism

CLC Number:

TB383.1

XIONG Yuanpeng, LI Ruixing, ZHANG Yue, KONG Fandong, ZHONG Qi. Hydrothermal Synthesis of Cs_xWO₃ Nanorods and Their Infrared Absorption Properties[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(6): 1036-1043.

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Hydrothermal Synthesis of Cs_xWO₃ Nanorods and Their Infrared Absorption Properties

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