Journal of Synthetic Crystals ›› 2026, Vol. 55 ›› Issue (9): 1377-1388.DOI: 10.16553/j.cnki.issn1000-985x.2026.0018
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ZHU Shihao(
), NIU Ruirui, XIE Jinglong, ZHANG Chuyi, ZHANG Shiyu, SUN Yu, LU Hong(
)
Received:2026-02-09
Online:2026-09-20
Published:2026-09-29
Contact:
LU Hong
CLC Number:
ZHU Shihao, NIU Ruirui, XIE Jinglong, ZHANG Chuyi, ZHANG Shiyu, SUN Yu, LU Hong. Research Progress and Market Development Prospect of Mid-Infrared Interband Cascade Lasers[J]. Journal of Synthetic Crystals, 2026, 55(9): 1377-1388.
| Molecule | MIR wavelength/μm | Line intensity/(cm-1/(molecule·cm-2)) | NIR wavelength/μm | Line intensity/(cm-1/(molecule·cm-2)) | Line strength ratio (MIR versus NIR) |
|---|---|---|---|---|---|
| CO | ~4.60 | ~10-19 | ~2.33 | ~10-21 | ~100 |
| CO2 | ~4.23 | ~10-18 | ~2.00 | ~10-21 | ~1 000 |
| CH4 | ~3.27 | ~10-19 | ~1.65 | ~10-21 | ~100 |
| H2O | ~5.94 | ~10-19 | ~1.39 | ~10-20 | ~10 |
| SO2 | ~7.29 | ~10-19 | — | — | — |
| NO | ~5.26 | ~10-20 | ~1.80 | ~10-23 | ~1 000 |
Table 1 Absorption peak intensity of typical gas molecules in MIR and NIR bands (data from the HITRAN database[4])
| Molecule | MIR wavelength/μm | Line intensity/(cm-1/(molecule·cm-2)) | NIR wavelength/μm | Line intensity/(cm-1/(molecule·cm-2)) | Line strength ratio (MIR versus NIR) |
|---|---|---|---|---|---|
| CO | ~4.60 | ~10-19 | ~2.33 | ~10-21 | ~100 |
| CO2 | ~4.23 | ~10-18 | ~2.00 | ~10-21 | ~1 000 |
| CH4 | ~3.27 | ~10-19 | ~1.65 | ~10-21 | ~100 |
| H2O | ~5.94 | ~10-19 | ~1.39 | ~10-20 | ~10 |
| SO2 | ~7.29 | ~10-19 | — | — | — |
| NO | ~5.26 | ~10-20 | ~1.80 | ~10-23 | ~1 000 |
| Industry | Security | Defense | Environment | Healthcare | Transport |
|---|---|---|---|---|---|
| Process control | Explosives | Infrared countermeasure | Continuous emission | Blood/proteins | Engine design |
| Exploration | Harmful material | Infrared countermeasure | Greenhouse | Breath | Fuels |
| Surveillance | Bio/chemical agents | Infrared countermeasure | Gas/indoor air monitoring | Life science | Vehicle emissions monitoring (VEM) |
Table 2 Application fields of MIR CLs
| Industry | Security | Defense | Environment | Healthcare | Transport |
|---|---|---|---|---|---|
| Process control | Explosives | Infrared countermeasure | Continuous emission | Blood/proteins | Engine design |
| Exploration | Harmful material | Infrared countermeasure | Greenhouse | Breath | Fuels |
| Surveillance | Bio/chemical agents | Infrared countermeasure | Gas/indoor air monitoring | Life science | Vehicle emissions monitoring (VEM) |
| Year | Institution/key contributor | Key achievement | Performance |
|---|---|---|---|
| 1994[ | Yang | Concept proposed | |
| 1997[ | UH & Sandia | First ICL demonstrated | 170 K |
| 1997[ | UH | Quantum efficiency(> 100%) | |
| 1997[ | NRL & UH | “W” type-Ⅱ QW | |
| 2002[ | Yang | First room temperature (RT) ICL (pulsed mode) | 3.5 μm; >6 kA/cm2 |
| 2003—2004[ | JPL | RT pulsed: 1 kA/cm2; CW: 200 K | |
| 2008[ | NRL | First RT CW lasing | 319 K; 400 A/cm2 at RT |
| 2009[ | OU | First InAs based ICL | |
| 2010[ | Würzburg University | Shortened injector region | |
| 2011[ | NRL | Rebalancing internally generated carriers | |
| 2012[ | NASA | ICL space application | Detected 0.41 ppb methane |
| 2013[ | Würzburg University | Cascade period optimization & new waveguide | 98 A/cm2 at RT; AlGaAsSb waveguide |
Table 3 Key achievements in ICLs
| Year | Institution/key contributor | Key achievement | Performance |
|---|---|---|---|
| 1994[ | Yang | Concept proposed | |
| 1997[ | UH & Sandia | First ICL demonstrated | 170 K |
| 1997[ | UH | Quantum efficiency(> 100%) | |
| 1997[ | NRL & UH | “W” type-Ⅱ QW | |
| 2002[ | Yang | First room temperature (RT) ICL (pulsed mode) | 3.5 μm; >6 kA/cm2 |
| 2003—2004[ | JPL | RT pulsed: 1 kA/cm2; CW: 200 K | |
| 2008[ | NRL | First RT CW lasing | 319 K; 400 A/cm2 at RT |
| 2009[ | OU | First InAs based ICL | |
| 2010[ | Würzburg University | Shortened injector region | |
| 2011[ | NRL | Rebalancing internally generated carriers | |
| 2012[ | NASA | ICL space application | Detected 0.41 ppb methane |
| 2013[ | Würzburg University | Cascade period optimization & new waveguide | 98 A/cm2 at RT; AlGaAsSb waveguide |
| Performance | ICLs | QCLs |
|---|---|---|
| Lasing mechanism | Interband transitions | Intersubband transitions |
| Wavelength range | 3~6.5 μm | 4~25 μm, including THz |
| Supplier | Nanoplus, Thorlabs, Alpes Lasers | Thorlabs, Alpes Lasers, Hamamatsu, AdTech Optics |
| Market share (MIR lasers) | ~25% | ~75% |
| Key application | Portable gas sensing, battery-operated devices | High-power countermeasures, free-space optics |
| Current limitation | Complex epitaxial growth and limited wafer-scale | High power consumption |
| Wavelength extension ongoing | Thermal management overhead, high system cost | |
| Future development focus | Wavelength extension, Si-based integration | QCL frequency combs, room-temperature THz QCLs |
| Manufacturing scale-up | Si-based integration |
Table 4 Advantages and disadvantages comparison and development direction of ICLs and QCLs
| Performance | ICLs | QCLs |
|---|---|---|
| Lasing mechanism | Interband transitions | Intersubband transitions |
| Wavelength range | 3~6.5 μm | 4~25 μm, including THz |
| Supplier | Nanoplus, Thorlabs, Alpes Lasers | Thorlabs, Alpes Lasers, Hamamatsu, AdTech Optics |
| Market share (MIR lasers) | ~25% | ~75% |
| Key application | Portable gas sensing, battery-operated devices | High-power countermeasures, free-space optics |
| Current limitation | Complex epitaxial growth and limited wafer-scale | High power consumption |
| Wavelength extension ongoing | Thermal management overhead, high system cost | |
| Future development focus | Wavelength extension, Si-based integration | QCL frequency combs, room-temperature THz QCLs |
| Manufacturing scale-up | Si-based integration |
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