微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构

人工晶体学报 ›› 2007, Vol. 36 ›› Issue (5): 1035-1038.

微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构

杨玉林;胡伟;刘新荣;李琳;姜兆华

哈尔滨工业大学材料科学与工程学院应用化学系,哈尔滨,150001

出版日期:2007-10-15 发布日期:2021-01-20
基金资助:
国家自然科学基金(20671025);Department of Education Foundation of Heilongjiang Province(10551335);黑龙江省自然科学基金(13200603);Harbin Science and Technolongy Bureau Foundation of China(2005AFXXJ034)

Self-assembly and Crystal Structure of Microporous Fluorogallophosphate Ga3P3O12F·0.5( 1,8-C8H22N2) under Hydrothermal Conditions

YANG Yu-lin;HU Wei;LIU Xin-rong;LI Lin;JIANG Zhao-hua

Online:2007-10-15 Published:2021-01-20

摘要/Abstract

摘要： 采用水热合成法制备了一个三维微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)(简称Hit-6).反应起始原料摩尔配比为∶GaOOH∶H3PO4∶HF∶1,8-辛二胺∶H2O=1∶2∶1∶1∶555.Hit-6的骨架是由Ga3P3六聚体结构单元通过共顶点联接构成三维纳米孔结构,在[101]方向呈现8-元环孔道.

关键词: 水热合成;微孔;氟化磷酸镓;晶体结构

Abstract: A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2)(named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O = 1:2:1:1:555.The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101]direction.

Key words: A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2)(named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O = 1:2:1:1:555.The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101]direction.

中图分类号:

杨玉林;胡伟;刘新荣;李琳;姜兆华. 微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构[J]. 人工晶体学报, 2007, 36(5): 1035-1038.

YANG Yu-lin;HU Wei;LIU Xin-rong;LI Lin;JIANG Zhao-hua. Self-assembly and Crystal Structure of Microporous Fluorogallophosphate Ga3P3O12F·0.5( 1,8-C8H22N2) under Hydrothermal Conditions[J]. Journal of Synthetic Crystals, 2007, 36(5): 1035-1038.

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