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人工晶体学报 ›› 2007, Vol. 36 ›› Issue (5): 1132-1135.

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衬底温度对直流反应磁控溅射法制备的N掺杂p型ZnO薄膜性能的影响

王超;季振国;韩玮智;席俊华;张品   

  1. 河南大学物理与电子学院微系统物理研究所,开封,475004;杭州电子科技大学电子信息学院,杭州,310018;浙江大学材料与化工学院硅材料国家重点实验室,杭州,310027
  • 出版日期:2007-10-15 发布日期:2021-01-20
  • 基金资助:
    the Scientific Research Foundation from Henan University(06YBZR007);国家自然科学基金(60576063);the PhD Project of the Chinese Education Ministry(20050335036)

Effects of Substrate Temperature on the Properties of N-doped p-type ZnO Films Deposited by DC Reactive Sputtering

WANG Chao;JI Zhen-guo;HAN Wei-zhi;XI Jun-hua;ZHANG Pin   

  • Online:2007-10-15 Published:2021-01-20

摘要: 利用直流反应磁控溅射法(纯金属锌作为靶材,Ar-N2-O2混合气体作为溅射气体)在石英玻璃衬底上制备了N掺杂p型ZnO薄膜.通过XRD、Hall和紫外可见透射谱分别研究了衬底温度对ZnO薄膜结构性能、电学性能和光学性能的影响.XRD结果显示所有制备的薄膜都具有垂直于衬底的c轴择优取向,并且随着衬底温度的增加,薄膜的晶体质量得到了提高.Hall测试表明衬底温度对p型ZnO薄膜的电阻率具有较大影响,400℃下生长的p型ZnO薄膜由于具有较高的迁移率(1.32 cm2/Vs)和载流子浓度(5.58×1017cm-3),因此表现出了最小的电阻率(8.44Ω·cm).

关键词: ZnO薄膜;P型;直流反应磁控溅射

Abstract: N-doped ZnO thin films were prepared on glass substrates by DC reactive magnetron sputtering using a pure zinc disk as target and Ar-N2-O2 mixture as sputtering gas. The effects of substrate temperature on the structural, electrical and optical characteristics of the ZnO films were studied by XRD, Hall effect measurement and UV-vis transmittance spectra, respectively. The results of XRD indicate that all the thin films had a preferred orientation with the c-axis perpendicular to the substrates,and the crystalline quality of the films was improved as the substrate temperature increased. Hall effect measurements show that the resistivity of the p-type ZnO thin films is dependent on the substrate temperature during deposition. The resistivity of the thin film grown at 400℃ had a minimum resistivity of 8.44 Ω·cm due to its higher mobility (1.32cm2/Vs) and hole concentration (5.58 × 1017cm-3).

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