非线性光学晶体Na_5[B_2P_3O_(13)]和BaAlBO_3F_2的水热合成

人工晶体学报 ›› 2009, Vol. 38 ›› Issue (6): 1446-1449.

非线性光学晶体Na_5[B_2P_3O_(13)]和BaAlBO_3F_2的水热合成

李志华;张继辉

山东师范大学化学化工与材料科学学院,济南,250014

出版日期:2009-12-15 发布日期:2021-01-20

Synthesis of Nonlinear Optical Crystal Na_5[B_2P_3O_(13)] and BaAlBO_3F_2 by Hydrothermal Method

LI Zhi-hua;ZHANG Ji-hui

Online:2009-12-15 Published:2021-01-20

摘要/Abstract

摘要： 采用水热法合成了Na_5[B_2P_3O_(13)](NBP)和BaAlBO_3F_2(BABF),确定了合成NBP的最佳反应条件,确立并分析了合成纯相BABF时反应物浓度的适宜配比及其对产物的影响.同时对合成的NBP和BABF进行了XRD、SEM及倍频效应等性质的表征.

关键词: 水热合成;Na_5[B_2P_3O_(13)];BaAlBO_3F_2;非线性光学晶体

Abstract: Na_5[B_2P_3O_(13)](NBP)and BaAlBO_3F_2(BABF)nonlinear optical crystals have been synthesized by hydrothermal method, the moderate reaction conditions have also been determined. The feasible initial charging ratio has been investigated in order to fabricate pure BABF. The as-synthesized NBP and BABF are characterized by XRD, SEM and second harmornic generation effect measurement, respectively.

Key words: Na_5[B_2P_3O_(13)](NBP)and BaAlBO_3F_2(BABF)nonlinear optical crystals have been synthesized by hydrothermal method, the moderate reaction conditions have also been determined. The feasible initial charging ratio has been investigated in order to fabricate pure BABF. The as-synthesized NBP and BABF are characterized by XRD, SEM and second harmornic generation effect measurement, respectively.

中图分类号:

TQ131

李志华;张继辉. 非线性光学晶体Na_5[B_2P_3O_(13)]和BaAlBO_3F_2的水热合成[J]. 人工晶体学报, 2009, 38(6): 1446-1449.

LI Zhi-hua;ZHANG Ji-hui. Synthesis of Nonlinear Optical Crystal Na_5[B_2P_3O_(13)] and BaAlBO_3F_2 by Hydrothermal Method[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2009, 38(6): 1446-1449.

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