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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 2073-2076.

• • 上一篇    下一篇

高温高压退火对碳化硅性能的影响

郑友进;王丽娟;王方标;左桂鸿;黄海亮   

  1. 牡丹江师范学院,黑龙江省新型碳基功能与超硬材料重点实验室,牡丹江157011
  • 发布日期:2021-01-20
  • 基金资助:
    牡丹江师范学院项目(GG2017001,GP201605,SY2014007);黑龙江省自然基金(E201341)

Influence of Annealing on the Properties of Silicon Carbide at High Temperature and High Pressure Condition

ZHENG You-jin;WANG Li-juan;WANG Fang-biao;ZUO Gui-hong;HUANG Hai-liang   

  • Published:2021-01-20

摘要: 以CVD生产的碳化硅为原料在高温高压下进行退火处理,探究退火温度对碳化硅性能的影响.实验结果表明:随着退火温度的增加,碳化硅的颜色由浅绿色变为无色;体积有明显的缩小、密度增加;退火后碳化硅的抗压强度显著增强,机械强度有所增加;退火后的SiC结构并没有发生变化,15R-SiC在798.6 cm-1处拉曼峰强度减少,4H-SiC在970 cm-1拉曼峰强度有所增强.

关键词: 碳化硅;高温高压;退火

Abstract: The silicon carbide synthesized by CVD method was as raw materials under high temperature and high pressure conditions , which was to explore the influence of annealing temperature on the properties of silicon carbide .The result show that the color of the silicon carbide change from pale green to colorless with the increase of annealing temperature , meanwhile , the density and the compressive strength of silicon carbide increase greatly .By Raman spectroscopy detection , the structure of anneal silicon carbide has not change , and the intensity of Raman peak of 15R-SiC at 798.6 cm-1 decrease, at the same tame , the intensity of Raman peak of 4 H-SiC at 970 cm-1 increase .

Key words: The silicon carbide synthesized by CVD method was as raw materials under high temperature and high pressure conditions , which was to explore the influence of annealing temperature on the properties of silicon carbide .The result show that the color of the silicon carbide change from pale green to colorless with the increase of annealing temperature , meanwhile , the density and the compressive strength of silicon carbide increase greatly .By Raman spectroscopy detection , the structure of anneal silicon carbide has not change , and the intensity of Raman peak of 15R-SiC at 798.6 cm-1 decrease, at the same tame , the intensity of Raman peak of 4 H-SiC at 970 cm-1 increase .

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