Ti3C2Tx MXene制备及在超级电容器中的应用研究进展

摘要/Abstract

摘要： 二维材料(2D)MXenes因其具有高比表面积、高导电率、可溶液加工等特性,作为超级电容器电极材料受到广泛关注。本文中总结了基于HF和氟化盐的刻蚀、基于碱的刻蚀、电化学刻蚀、路易斯酸熔融盐刻蚀等几种Ti₃C₂T_x MXene的制备方法,综述了真空辅助过滤、阳离子自组装、逐层组装工艺、印刷工艺、组装MXene气凝胶和水凝胶等Ti₃C₂T_xMXene基电极材料的组装策略及其在超级电容器的应用。研究表明,不同制备方法和电极组装策略将会影响电极材料的结构和电化学性能。对Ti₃C₂T_x MXene的制备方法和电极组装策略进行了对比总结,指出了研究中存在的问题,并展望了MXene今后的研究方向。

关键词: 电极材料, 二维材料, MXene, Ti₃C₂T_x MXene, 超级电容器, 电极, 组装

Abstract: Two dimensional (2D) material Mxenes has attracted extensive attention as supercapacitor electrode materials because of its high specific surface area, high conductivity and solution processability. Several preparation methods of Ti₃C₂T_x MXene such as HF and fluoride based etching, alkali based etching, electrochemical etching and Lewis acid molten salt etching are summarized. The assembly strategies of Ti₃C₂T_x MXene electrode materials such as vacuum assisted filtration, cationic self-assembly, layer by layer assembly, printing process, assembly of MXene aerogels, hydrogels, and their applications in supercapacitors are reviewed. Many studies have shown that the structure and the electrochemical performance of MXene electrodes is considerably affected by different preparation methods and electrode assembly strategies. The preparation methods and electrode assembly strategies of Ti₃C₂T_x MXene are compared and summarized, the existing problems in the research are pointed out, and the future research direction of MXene is prospected.

Key words: electrode material, 2D material, MXene, Ti₃C₂T_x MXene, supercapacitor, electrode, assembly

中图分类号:

TQ152
TB34

牛丽丽, 王培, 张丽, 刘彦彬, 付凤艳. Ti₃C₂T_x MXene制备及在超级电容器中的应用研究进展[J]. 人工晶体学报, 2021, 50(11): 2183-2191.

NIU Lili, WANG Pei, ZHANG Li, LIU Yanbin, FU Fengyan. Research Progress on Preparation of Ti₃C₂T_x MXene and Its Application in Supercapacitors[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(11): 2183-2191.

参考文献

[1] HWANG C, CHUNG T L, SANDERS E A. Attitudes and purchase intentions for smart clothing[J]. Clothing and Textiles Research Journal, 2016, 34(3): 207-222.
[2] HUANG Q Y, WANG D R, ZHENG Z J. Textile-based electrochemical energy storage devices[J]. Advanced Energy Materials, 2016, 6(22): 1600783.
[3] JIA L C, LI Y K, YAN D X. Flexible and efficient electromagnetic interference shielding materials from ground tire rubber[J]. Carbon, 2017, 121: 267-273.
[4] NOVOSELOV K S, MISHCHENKO A, CARVALHO A, et al. 2D materials and van der Waals heterostructures[J]. Science, 2016, 353(6298): aac9439.
[5] NAGUIB M, KURTOGLU M, PRESSER V, et al. Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂[J]. Advanced Materials, 2011, 23(37): 4248-4253.
[6] MASHTALIR O, NAGUIB M, MOCHALIN V N, et al. Intercalation and delamination of layered carbides and carbonitrides[J]. Nature Communications, 2013, 4: 1716.
[7] NAGUIB M, UNOCIC R R, ARMSTRONG B L, et al. Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”[J]. Dalton Transactions, 2015, 44(20): 9353-9358.
[8] ANASORI B, LUKATSKAYA M R, GOGOTSI Y. 2D metal carbides and nitrides (MXenes) for energy storage[J]. Nature Reviews Materials, 2017, 2: 16098.
[9] DEYSHER G, SHUCK C E, HANTANASIRISAKUL K, et al. Synthesis of Mo₄VAlC₄ MAX phase and two-dimensional Mo₄VC₄ MXene with five atomic layers of transition metals[J]. ACS Nano, 2020, 14(1): 204-217.
[10] TAO Q Z, DAHLQVIST M, LU J, et al. Two-dimensional Mo_1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering[J]. Nature Communications, 2017, 8: 14949.
[11] ZHOU J, ZHA X, ZHOU X, et al. Synthesis and electrochemical properties of two-dimensional hafnium carbide[J]. ACS Nano, 2017, 11(4): 3841-3850.
[12] PANG S Y, WONG Y T, YUAN S, et al. Universal strategy for HF-free facile and rapid synthesis of two-dimensional MXenes as multifunctional energy materials[J]. Journal of the American Chemical Society, 2019, 141(24): 9610-9616.
[13] LI Y B, SHAO H, LIN Z F, et al. A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte[J]. Nature Materials, 2020, 19(8): 894-899.
[14] MASHTALIR O, NAGUIB M, DYATKIN B, et al. Kinetics of aluminum extraction from Ti₃AlC₂ in hydrofluoric acid[J]. Materials Chemistry and Physics, 2013, 139(1): 147-152.
[15] WANG X F, SHEN X, GAO Y R, et al. Atomic-scale recognition of surface structure and intercalation mechanism of Ti₃C₂X[J]. Journal of the American Chemical Society, 2015, 137(7): 2715-2721.
[16] GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al. Conductive two-dimensional titanium carbide ‘clay' with high volumetric capacitance[J]. Nature, 2014, 516(7529): 78-81.
[17] HALIM J, LUKATSKAYA M R, COOK K M, et al. Transparent conductive two-dimensional titanium carbide epitaxial thin films[J]. Chemistry of Materials, 2014, 26(7): 2374-2381.
[18] XIE X, XUE Y, LI L, et al. Surface Al leached Ti₃AlC₂ as a substitute for carbon for use as a catalyst support in a harsh corrosive electrochemical system[J]. Nanoscale, 2014, 6(19): 11035-11040.
[19] LI G, TAN L, ZHANG Y, et al. Highly efficiently delaminated single-layered MXene nanosheets with large lateral size[J]. Langmuir, 2017, 33(36): 9000-9006.
[20] ZHANG B, ZHU J F, SHI P, et al. Fluoride-free synthesis and microstructure evolution of novel two-dimensional Ti₃C₂(OH)₂ nanoribbons as high-performance anode materials for lithium-ion batteries[J]. Ceramics International, 2019, 45(7): 8395-8405.
[21] LI T F, YAO L L, LIU Q L, et al. Fluorine-free synthesis of high-purity Ti₃C₂T_x (T=OH, O) via alkali treatment[J]. Angewandte Chemie International Edition, 2018, 57(21): 6115-6119.
[22] HUANG L J, LI T F, LIU Q L, et al. Fluorine-free Ti₃C₂T_x as anode materials for Li-ion batteries[J]. Electrochemistry Communications, 2019, 104: 106472.
[23] YANG S, ZHANG P P, WANG F X, et al. Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using A binary aqueous system[J]. Angewandte Chemie International Edition, 2018, 57(47): 15491-15495.
[24] LI M, LU J, LUO K, et al. Element replacement approach by reaction with lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes[J]. Journal of the American Chemical Society, 2019, 141(11): 4730-4737.
[25] KAMYSBAYEV V, FILATOV A S, HU H C, et al. Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes[J]. Science, 2020, 369(6506): 979-983.
[26] GOGOTSI Y. Transition metal carbides go 2D[J]. Nature Materials, 2015, 14(11): 1079-1080.
[27] LUKATSKAYA M R, KOTA S, LIN Z F, et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides[J]. Nature Energy, 2017, 2: 17105.
[28] PAN X H, SHINDE N M, LEE M, et al. Controlled nanosheet morphology of titanium carbide Ti₃C₂T_x MXene via drying methods and its electrochemical analysis[J]. Journal of Solid State Electrochemistry, 2020, 24(3): 675-686.
[29] HU Y, WANG L, LIN T R, et al. Radiation-induced self-assembly of Ti₃C₂T_x with improved electrochemical performance for supercapacitor[J]. Advanced Materials Interfaces, 2020, 7(6): 1901839.
[30] MA Y L, SHENG H W, DOU W, et al. Fe₂O₃ nanoparticles anchored on the Ti₃C₂T_x MXene paper for flexible supercapacitors with ultrahigh volumetric capacitance[J]. ACS Applied Materials & Interfaces, 2020, 12(37): 41410-41418.
[31] FU J, YUN J, WU S, et al. Architecturally robust graphene-encapsulated MXene Ti₂CT_x@Polyaniline composite for high-performance pouch-type asymmetric supercapacitor[J]. ACS Applied Materials & Interfaces, 2018, 10(40): 34212-34221.
[32] ZHAO D, CLITES M, YING G, et al. Alkali-induced crumpling of Ti₃C₂T_x (MXene) to form 3D porous networks for sodium ion storage[J]. Chemical Communications, 2018, 54(36): 4533-4536.
[33] ZHANG X F, LIU X D, YAN R Z, et al. Ion-assisted self-assembly of macroporous MXene films as supercapacitor electrodes[J]. Journal of Materials Chemistry C, 2020, 8(6): 2008-2013.
[34] FAN Z M, WANG Y S, XIE Z M, et al. Modified MXene/holey graphene films for advanced supercapacitor electrodes with superior energy storage[J]. Advanced Science, 2018, 5(10): 1800750.
[35] YU P, CAO G, YI S, et al. Binder-free 2D titanium carbide (MXene)/carbon nanotube composites for high-performance lithium-ion capacitors[J]. Nanoscale, 2018, 10(13): 5906-5913.
[36] LI H Y, HOU Y, WANG F X, et al. Flexible all-solid-state supercapacitors with high volumetric capacitances boosted by solution processable MXene and electrochemically exfoliated graphene[J]. Advanced Energy Materials, 2017, 7(4): 1601847.
[37] ZHAO C J, WANG Q, ZHANG H, et al. Two-dimensional titanium carbide/RGO composite for high-performance supercapacitors[J]. ACS Applied Materials & Interfaces, 2016, 8(24): 15661-15667.
[38] VAHIDMOHAMMADI A, MONCADA J, CHEN H Z, et al. Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance[J]. Journal of Materials Chemistry A, 2018, 6(44): 22123-22133.
[39] ZHANG X B, SHAO B Y, GUO A P, et al. MnO₂ nanoshells/Ti₃C₂T_x MXene hybrid film as supercapacitor electrode[J]. Applied Surface Science, 2021, 560: 150040.
[40] ZHOU Z H, PANATDASIRISUK W, MATHIS T S, et al. Layer-by-layer assembly of MXene and carbon nanotubes on electrospun polymer films for flexible energy storage[J]. Nanoscale, 2018, 10(13): 6005-6013.
[41] TIAN Y P, YANG C H, QUE W X, et al. Ni foam supported quasi-core-shell structure of ultrathin Ti₃C₂ nanosheets through electrostatic layer-by-layer self-assembly as high rate-performance electrodes of supercapacitors[J]. Journal of Power Sources, 2017, 369: 78-86.
[42] YUN J, ECHOLS I, FLOUDA P, et al. Layer-by-layer assembly of reduced graphene oxide and MXene nanosheets for wire-shaped flexible supercapacitors[J]. ACS Applied Materials & Interfaces, 2021, 13(12): 14068-14076.
[43] ZHANG C F, MCKEON L, KREMER M P, et al. Additive-free MXene inks and direct printing of micro-supercapacitors[J]. Nature Communications, 2019, 10: 1795.
[44] ORANGI J, HAMADE F, DAVIS V A, et al. 3D printing of additive-free 2D Ti₃C₂T_x (MXene) ink for fabrication of micro-supercapacitors with ultra-high energy densities[J]. ACS Nano, 2020, 14(1): 640-650.
[45] SHAO L, XU J J, MA J Z, et al. MXene/RGO composite aerogels with light and high-strength for supercapacitor electrode materials[J]. Composites Communications, 2020, 19: 108-113.
[46] LIU D S, ASHCRAFT J N, MANNARINO M M, et al. Spray layer-by-layer electrospun composite proton exchange membranes[J]. Advanced Functional Materials, 2013, 23(24): 3087-3095.
[47] TIAN W, VAHIDMOHAMMADI A, WANG Z, et al. Layer-by-layer self-assembly of pillared two-dimensional multilayers[J]. Nature Communications, 2019, 10(1): 2558.
[48] WU C W, UNNIKRISHNAN B, CHEN I W P, et al. Excellent oxidation resistive MXene aqueous ink for micro-supercapacitor application[J]. Energy Storage Materials, 2020, 25: 563-571.
[49] ZHENG S H, WANG H, DAS P, et al. Multitasking MXene inks enable high-performance printable microelectrochemical energy storage devices for all-flexible self-powered integrated systems[J]. Advanced Materials, 2021, 33(10): 2005449.
[50] CHEN H, MA H, ZHANG P, et al. Pristine titanium carbide MXene hydrogel matrix[J]. ACS Nano, 2020, 14(8): 10471-10479.
[51] YUE Y, LIU N, MA Y, et al. Highly self-healable 3D microsupercapacitor with MXene-graphene composite aerogel[J]. ACS Nano, 2018, 12(5): 4224-4232.
[52] MU X P, WANG D S, DU F, et al. Revealing the pseudo-intercalation charge storage mechanism of MXenes in acidic electrolyte[J]. Advanced Functional Materials, 2019, 29(29): 1902953.
[53] GUO B Y, TIAN J, YIN X L, et al. A binder-free electrode based on Ti₃C₂T_x-rGO aerogel for supercapacitors[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 595: 124683

Ti₃C₂T_x MXene制备及在超级电容器中的应用研究进展

Research Progress on Preparation of Ti₃C₂T_x MXene and Its Application in Supercapacitors

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