三维网络结构NiCo2S4@NiCo2O4复合电极的制备及其性能

摘要/Abstract

摘要： 超级电容器具有更大的功率密度、优秀的循环稳定性、极快的充放电速度、超长的循环寿命以及环境友好等突出特点,其性能与构件关系密切,其中最根本的就是组成它的电极材料。本研究主要采用传统的水热法制备出钴酸镍(NiCo₂O₄)电极材料,进而通过离子交换(二次水热)制得镍钴硫(NiCo₂S₄),最后利用化学浴沉积(CBD)法使其与钴酸镍复合,得到最终所需的三维网络结构NiCo₂S₄@NiCo₂O₄复合电极。经过表面形貌表征、循环伏安测试、恒电流充放电测试以及比电容计算分析等可以证明:三维网络结构NiCo₂S₄@NiCo₂O₄复合电极的比电容及循环稳定性等远远优于复合前单一的纯NiCo₂O₄电极材料,具有极大应用前景。

关键词: 超级电容器, 电极材料, 三维网络结构, NiCo₂S₄, NiCo₂O₄, NiCo₂S₄@NiCo₂O₄, 电化学性能

Abstract: Supercapacitors with outstanding power density, excellent cycle stability, extremely fast rate performance and environmental friendliness have been widely studied. The performance of supercapacitors is highly dependent on the electrode materials. In this study, Ni-Co-S system was selected and composited as electrode material. Firstly, the NiCo₂O₄ electrode was prepared by hydrothermal method, and it was then transformed into NiCo₂S₄ electrode by ion exchanging method. Then, with chemical bath deposition (CBD) method, the NiCo₂S₄@NiCo₂O₄ composite electrode with 3D network structure was obtained. Further electrochemical studies (CV/Charge-Discharge curves) and SEM images confirm the better specific capacitance and cycle stability of NiCo₂S₄@NiCo₂O₄ composite electrode than that of the single component NiCo₂O₄ electrode, showing great application prospect.

Key words: supercapacitor, electrode material, 3D network structure, NiCo₂S₄, NiCo₂O₄, NiCo₂S₄@NiCo₂O₄, electrochemical performance

中图分类号:

TB383.1

戚佳斌, 邱飞龙. 三维网络结构NiCo₂S₄@NiCo₂O₄复合电极的制备及其性能[J]. 人工晶体学报, 2021, 50(12): 2332-2338.

QI Jiabin, QIU Feilong. Preparation and Characterization of NiCo₂S₄@NiCo₂O₄ Composite Electrode with 3D Network Structure[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(12): 2332-2338.

参考文献

[1] 朱文慧.超级电容器改善同步发电机系统稳定性能的研究[D].长沙:湖南大学,2010.
ZHU W H. The research on super capacitys to improve the performance of the synchronous generator system stability[D]. Changsha: Hunan University, 2010(in Chinese).
[2] CONWAY B E. Electrochemical supercapacitors: scientific fundamentals and technological applications[M]. New York: Springer: 1999.
[3] PANDOLFO A G, HOLLENKAMP A F. Carbon properties and their role in supercapacitors[J]. Journal of Power Sources, 2006, 157(1): 11-27.
[4] ZHAO B, SONG J S, LIU P, et al. Monolayer graphene/NiO nanosheets with two-dimension structure for supercapacitors[J]. Journal of Materials Chemistry, 2011, 21(46): 18792.
[5] CONWAY B E. Transition from ‘supercapacitor’ to ‘battery’ behavior in electrochemical energy storage[J]. Proceedings of the 34th International Power Sources Symposium, 1990: 319-327.
[6] WANG X F, WANG D Z, LIANG J, et al. Carbon nanotube capacitor materials loaded with different amounts of ruthenium oxide[J]. Acta Physico-Chimica Sinica, 2003, 19(6): 509-513.
[7] WEI Y Y, CHEN S Q, SU D W, et al. 3D mesoporous hybrid NiCo₂O₄@graphene nanoarchitectures as electrode materials for supercapacitors with enhanced performances[J]. J Mater Chem A, 2014, 2(21): 8103-8109.
[8] SUN J, XUE H, GUO N, et al. Synergetic metal defect and surface chemical reconstruction into NiCo₂S₄ /ZnS heterojunction to achieve outstanding oxygen evolution performance[J]. Angewandte Chemie, 2021, 60(35): 19435-19441.
[9] GUAN B Y, YU L, WANG X, et al. Formation of onion-like NiCo₂S₄ particles via sequential ion-exchange for hybrid supercapacitors[J]. Advanced Materials, 2017, 29(6): 1605051.
[10] CHEN H, JIANG J, ZHANG L, et al. Highly conductive NiCo₂S₄ urchin-like nanostructures for high-rate pseudocapacitors[J]. Nanoscale, 2013, 5(19): 8879-8883.
[11] 程杰,曹高萍,杨裕生.活性炭/氧化镍干凝胶超级电容器研究[J].电源技术,2007,31(3):183-185.
CHENG J, CAO G P, YANG Y S. Study on electrochemical hybrid supercapacitors composed with activated carbon and nickel oxide xerogels electrodes[J]. Chinese Journal of Power Sources, 2007, 31(3): 183-185(in Chinese).
[12] FUSALBA F, GOUEÉREC P, VILLERS D, et al. Electrochemical characterization of polyaniline in nonaqueous electrolyte and its evaluation as electrode material for electrochemical supercapacitors[J]. Journal of the Electrochemical Society, 2001, 148(1): A1.
[13] ZHANG G H, WANG T H, YU X Z, et al. Nanoforest of hierarchical Co₃O₄@NiCo₂O₄ nanowire arrays for high-performance supercapacitors[J]. Nano Energy, 2013, 2(5): 586-594.
[14] YU L, ZHANG G, YUAN C, et al. Hierarchical NiCo₂O₄@MnO₂ core-shell heterostructured nanowire arrays on Ni foam as high-performance supercapacitor electrodes[J]. Chemical Communications, 2013, 49(2): 137-139.

[1]	栾照金, 闫共芹, 谈尚华. SnO₂/石墨分级纳米异质结构的合成及其电化学性能研究[J]. 人工晶体学报, 2021, 50(8): 1503-1510.
[2]	郑彧, 张怡, 童亚琦, 玄真武. 掺硼金刚石膜研究进展及应用[J]. 人工晶体学报, 2021, 50(6): 1138-1148.
[3]	张杰. 氢氧化镍/还原氧化石墨烯复合材料的制备及其电化学性能[J]. 人工晶体学报, 2021, 50(5): 915-919.
[4]	周阳阳, 张子英, 翁滢. ZnO超细纳米线阵列的制备及其电化学性能[J]. 人工晶体学报, 2021, 50(3): 536-541.
[5]	望军, 赵雨, 范保艳, 张均, 邢安, 刘晓燕. 锂离子电池CoO多孔纳米片阵列/碳布柔性负极材料[J]. 人工晶体学报, 2021, 50(11): 2150-2155.
[6]	牛丽丽, 王培, 张丽, 刘彦彬, 付凤艳. Ti₃C₂T_x MXene制备及在超级电容器中的应用研究进展[J]. 人工晶体学报, 2021, 50(11): 2183-2191.
[7]	吴旭;唐晓宁. 硫/碳复合材料在锂硫电池正极中的应用[J]. 人工晶体学报, 2020, 49(9): 1752-1763.
[8]	覃爱苗;郑爽;魏立学;刘志森. 生物质炭的杂元素掺杂及其在电极中的应用[J]. 人工晶体学报, 2020, 49(7): 1326-1335.
[9]	郭颢;张荣良;鲁琴瑶;曾加;李聪. 常压水解-离子交换法制备TiO2负极材料及其电化学性能研究[J]. 人工晶体学报, 2020, 49(6): 1129-1133.
[10]	侯朝霞;王健;屈晨滢;王晓慧. 电化学法制备石墨烯基复合材料及其在超级电容器中的研究进展[J]. 人工晶体学报, 2020, 49(5): 930-939.
[11]	李星星;肖绍军;马亚楠;罗时军. 高性能MXene基微型超级电容器电化学性能的研究[J]. 人工晶体学报, 2020, 49(3): 526-531.
[12]	周伶俐, 兰翠玲, 谢瑞刚, 杨一松, 秦冯详. 花状NiCo-LDH/CB复合材料的制备及其电化学性能研究[J]. 人工晶体学报, 2020, 49(12): 2331-2335.
[13]	张克诚, 马强, 王健, 马龙, 卢强, 韦琪龙, 魏智强, 乔宏霞. 核壳结构CdS@C纳米复合材料的光催化性能研究[J]. 人工晶体学报, 2020, 49(12): 2336-2343.
[14]	于利民, 缪畅, 李锐, 谭燚, 肖围. 电沉积制备金属锡薄膜负极材料及其电化学性能研究[J]. 人工晶体学报, 2020, 49(12): 2344-2349.
[15]	李东, 高彩云. 功能模板导向合成介孔三氧化钨及其光电化学性能[J]. 人工晶体学报, 2020, 49(12): 2350-2357.

三维网络结构NiCo₂S₄@NiCo₂O₄复合电极的制备及其性能

Preparation and Characterization of NiCo₂S₄@NiCo₂O₄ Composite Electrode with 3D Network Structure

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价