Gd2O3掺杂BiFeO3陶瓷的漏电流特性及磁性能研究

人工晶体学报 ›› 2023, Vol. 52 ›› Issue (6): 1161-1167.

Gd₂O₃掺杂BiFeO₃陶瓷的漏电流特性及磁性能研究

刘璇^1,2, 郭菲菲¹, 龙伟¹, 惠增哲¹, 何爱国¹, 徐瑰宇²

1.西安工业大学材料与化工学院,陕西省光电功能材料与器件重点实验室,西安 710021;
2.商洛学院化学工程与现代材料学院,陕西省矿产资源清洁高效转化与新材料工程技术研究中心,商洛 726000

收稿日期:2023-01-04 出版日期:2023-06-15 发布日期:2023-06-30
通信作者: 惠增哲,博士,教授。E-mail:zzhxi@xatu.edu.cn
作者简介:刘璇(1989—),男,陕西省人,博士研究生,副教授。E-mail:mmjjcs168@qq.com
基金资助:
国家自然科学基金(51472197,51602242); 陕西省教育厅专项科研项目(21JK0619)

Leakage Current Characteristics and Magnetic Properties of Gd₂O₃ Doped BiFeO₃ Ceramics

LIU Xuan^1,2, GUO Feifei¹, LONG Wei¹, XI Zengzhe¹, HE Aiguo¹, XU Guiyu²

1. Shaanxi Key Laboratory of Photoelectric Functional Materials and Devices, School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China;
2. Shaanxi Engineering Research Center for Mineral Resources Clean & Efficient Conversion and New Materials, School of Chemical Engineering and Modern Materials, Shangluo University, Shangluo 726000, China

Received:2023-01-04 Online:2023-06-15 Published:2023-06-30

摘要/Abstract

摘要： 本文采用快速液相烧结法制备了Gd₂O₃掺杂BiFeO₃陶瓷,并对陶瓷样品进行了物相、形貌、漏电流特性和磁性能研究。XRD分析结果表明,Gd₂O₃的加入促进了富铋相(Bi₂₅FeO₄₀)的形成且使晶胞体积减小,同时陶瓷的物相由三方相向正交相转变;SEM分析结果表明,Gd₂O₃掺杂能起到细化陶瓷晶粒的作用;电学性能分析表明,陶瓷样品漏电流较大,但Gd₂O₃的掺杂可显著降低陶瓷的漏电流;漏电流特性分析结果表明,陶瓷在低电场下的漏电流特性是欧姆传导机制,在高电场下纯BiFeO₃陶瓷的漏电流特性为肖特基发射机制,但随着Gd₂O₃掺杂量的增加而逐渐变为空间电荷限制电流传导(SCLC)机制;磁性研究结果表明,掺杂引入的磁性Gd₂O₃颗粒均匀分布在陶瓷的晶界处从而显著提高陶瓷磁性能。

关键词: BiFeO₃陶瓷, Gd₂O₃掺杂, 液相烧结法, 电学性能, 漏电流特性, 磁性能

Abstract: In this paper, the phase, morphology, leakage current, and magnetic properties of Gd₂O₃ doped BiFeO₃ ceramics prepared by fast liquid-phase sintering method were studied. XRD results show that Gd₂O₃ doping promotes the formation of a bismuth-rich phase (Bi₂₅FeO₄₀) and reduces the cell volume. At the same time, the phase of the ceramics transforms from three sides to opposite side, and Gd₂O₃ doping causes the rhombohedral structure distorts and transforms into an orthorhombic structure. SEM analysis shows that Gd₂O₃ doping can refine the ceramic grains. The analysis of the electrical properties show that the leakage current of ceramic samples is large, but the doping of Gd₂O₃ can significantly reduce the leakage current. The leakage current characteristic analysis shows that the leakage current characteristic of ceramics under low electric field is ohmic conduction, and the leakage current characteristic of pure BiFeO₃ ceramics under high electric field is Schottky emission mechanism, which gradually changes into space charge limited current (SCLC) mechanism with the increase of Gd₂O₃ doping amount. The magnetic studies show that the magnetic Gd₂O₃ particles introduced by doping are uniformly distributed in the grain boundaries of ceramics, which significantly improves the magnetic properties of ceramics.

Key words: BiFeO₃ ceramics, Gd₂O₃ doping, liquid-phase sintering method, electrical property, leakage current characteristic, magnetic property

中图分类号:

TQ174

刘璇, 郭菲菲, 龙伟, 惠增哲, 何爱国, 徐瑰宇. Gd₂O₃掺杂BiFeO₃陶瓷的漏电流特性及磁性能研究[J]. 人工晶体学报, 2023, 52(6): 1161-1167.

LIU Xuan, GUO Feifei, LONG Wei, XI Zengzhe, HE Aiguo, XU Guiyu. Leakage Current Characteristics and Magnetic Properties of Gd₂O₃ Doped BiFeO₃ Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(6): 1161-1167.

参考文献

[1] RAMESH R, SPALDIN N A. Multiferroics: progress and prospects in thin films[J]. Nature Materials, 2007, 6(1): 21-29.
[2] TOKURA Y. Materials science. multiferroics as quantum electromagnets[J]. Science, 2006, 312(5779): 1481-1482.
[3] YOO Y J, HWANG J S, LEE Y P, et al. High ferromagnetic transition temperature in multiferroic BiFe_0.95Ni₀_.₀₅O₃ compound[J]. Journal of Applied Physics, 2013, 114(16): 163902.
[4] MAZUMDAR S, DATTA S, ALAM F. Structural, magnetic and transport properties of Gd and Cu Co-doped BiFeO₃ multiferroics[J]. Journal of Applied Mathematics and Physics, 2022, 10(006): 2026-2039.
[5] JHA V K, SIJO A K, ALAM S N, et al. Effect of Nd doping on structural, electrical, thermal and magnetic properties of multifunctional BiFeO₃ ceramics[J]. Journal of Superconductivity and Novel Magnetism, 2020, 33(2): 455-461.
[6] DURGA RAO T, RAJA KANDULA K, KUMAR A, et al. Improved magnetization and reduced leakage current in Sm and Sc co-substituted BiFeO₃[J]. Journal of Applied Physics, 2018, 123(24): 244104.
[7] SONG S H, ZHU Q S, WENG L Q, et al. A comparative study of dielectric, ferroelectric and magnetic properties of BiFeO₃ multiferroic ceramics synthesized by conventional and spark plasma sintering techniques[J]. Journal of the European Ceramic Society, 2015, 35(1): 131-138.
[8] SPALDIN N A. Multiferroics: past, present, and future[J]. MRS Bulletin, 2017, 42(5): 385-390.
[9] SHI X, LIU X, CHEN X. Readdressing of magnetoelectric effect in bulk BiFeO₃ [J]. Advanced Functional Materials, 2017, 27(12):1604037.1-1604037.9.
[10] DAS R, KHAN G G, MANDAL K. Enhanced ferroelectric, magnetoelectric, and magnetic properties in Pr and Cr co-doped BiFeO₃ nanotubes fabricated by template assisted route[J]. Journal of Applied Physics, 2012, 111(10): 104115.
[11] YUAN G L, OR S W. Multiferroicity in polarized single-phase Bi_0.875Sm_0.125FeO₃ ceramics[J]. Journal of Applied Physics, 2006, 100(2): 024109.
[12] ZHANG S X, WANG L, CHEN Y, et al. Observation of room temperature saturated ferroelectric polarization in Dy substituted BiFeO₃ ceramics[J]. Journal of Applied Physics, 2012, 111(7): 074105.
[13] YUAN G L, OR S W. Enhanced piezoelectric and pyroelectric effects in single-phase multiferroic Bi_1-xNd_xFeO₃ (x=0~0.15) ceramics[J]. Applied Physics Letters, 2006, 88(6): 062905.
[14] JEON N, ROUT D, KIM I W, et al. Enhanced multiferroic properties of single-phase BiFeO₃ bulk ceramics by Ho doping[J]. Applied Physics Letters, 2011, 98(7): 072901.
[15] GUO R Q, FANG L, DONG W, et al. Enhanced photocatalytic activity and ferromagnetism in Gd doped BiFeO₃ nanoparticles[J]. The Journal of Physical Chemistry C, 2010, 114(49): 21390-21396.
[16] PAPI H D, AHMADVAND H, SHAHBAZ M T, et al. Dielectric and magnetoelectric properties of (BiBa)(FeTiZn)O₃/CoFe₂O₄ lead-free particulate composites[J]. Journal of Magnetism and Magnetic Materials, 2021, 521: 167484.
[17] WU J G, FAN Z, XIAO D Q, et al. Multiferroic bismuth ferrite-based materials for multifunctional applications: ceramic bulks, thin films and nanostructures[J]. Progress in Materials Science, 2016, 84: 335-402.
[18] ABLAT A, WU R, MAMAT M, et al. Structural analysis and magnetic properties of Gd doped BiFeO₃ ceramics[J]. Ceramics International, 2014, 40(9): 14083-14089.
[19] KUMAR M, CHANDRA SATI P, CHHOKER S, et al. Electron spin resonance studies and improved magnetic properties of Gd substituted BiFeO₃ ceramics[J]. Ceramics International, 2015, 41(1): 777-786.
[20] WEI J, LIU Y, BAI X F, et al. Crystal structure, leakage conduction mechanism evolution and enhanced multiferroic properties in Y-doped BiFeO₃ ceramics[J]. Ceramics International, 2016, 42(12): 13395-13403.
[21] IAKOVLEV S, SOLTERBECK C H, KUHNKE M, et al. Multiferroic BiFeO₃ thin films processed via chemical solution deposition: structural and electrical characterization[J]. Journal of Applied Physics, 2005, 97(9): 094901.
[22] PABST G W, MARTIN L W, CHU Y H, et al. Leakage mechanisms in BiFeO₃ thin films[J]. Applied Physics Letters, 2007, 90(7): 072902.
[23] PRADHANI N, MAHAPATRA P K, CHOUDHARY R N P. Structural, impedance, and leakage current characteristics of stannum modified Bi_0.5Na_0.5TiO₃ ceramic[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2021, 31(2): 591-598.
[24] XUE F, TIAN Y H, JIAN G, et al. Ferroelectromagnetic pseudocubic BiFeO₃-LaFeO₃-PbFeO_2.5: leakage current, dielectric, and multiferroic properties at room temperature[J]. Ceramics International, 2020, 46(1): 930-936.
[25] LUO J M, LIN S P, ZHENG Y, et al. Nonpolar resistive switching in Mn-doped BiFeO₃ thin films by chemical solution deposition[J]. Applied Physics Letters, 2012, 101(6): 062902.
[26] KUMAR S. Structural, dielectric and magnetic characterization of large scale template synthesized Gd doped BiFeO₃ nanowires[J]. Journal of Materials Science: Materials in Electronics, 2013, 24(6): 2112-2115.

Gd₂O₃掺杂BiFeO₃陶瓷的漏电流特性及磁性能研究

Leakage Current Characteristics and Magnetic Properties of Gd₂O₃ Doped BiFeO₃ Ceramics

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