Pr3+掺杂碱土混合氟化物激光晶体的生长与发光性能研究

人工晶体学报 ›› 2023, Vol. 52 ›› Issue (7): 1258-1269.

• 大尺寸激光晶体材料制备的关键技术与应用研究 • 上一篇下一篇

Pr³⁺掺杂碱土混合氟化物激光晶体的生长与发光性能研究

王无敌¹, 王庆国¹, 薛艳艳¹, 唐慧丽¹, 徐子寒¹, 张晨波¹, 房前成¹, 吴锋¹, 罗平¹, 徐晓东², 苏良碧³, 李岩⁴, 韩建峰⁴, 逯占文⁴, 徐军¹

1.同济大学物理科学与工程学院,上海 200092;
2.江苏师范大学物理与电子工程学院,徐州 221116;
3.中国科学院上海硅酸盐研究所,上海 201899;
4.连城凯科斯科技有限公司,无锡 214000)

收稿日期:2023-05-20 出版日期:2023-07-15 发布日期:2023-08-16
通信作者: 唐慧丽,副教授。E-mail:tanghl@tongji.edu.cn
徐军,教授。E-mail:15503@tongji.edu.cn
作者简介:王无敌(1996—),男,河南省人,博士研究生。E-mail:wdwangw@163.com
基金资助:
国家重点研发计划(2022YFB3605701);国家自然科学基金(61621001,62075166,61805177)

Growth and Luminescence Properties of Pr³⁺ Doped Alkaline Earth Mixed Fluoride Laser Crystals

WANG Wudi¹, WANG Qingguo¹, XUE Yanyan¹, TANG Huili¹, XU Zihan¹, ZHANG Chenbo¹, FANG Qiancheng¹, WU Feng¹, LUO Ping¹, XU Xiaodong², SU Liangbi³, LI Yan⁴, HAN Jianfeng⁴, LU Zhanwen⁴, XU Jun¹

1. School of Physics Science and Engineering, Tongji University, Shanghai 200092, China;
2. School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
3. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China;
4. Linton Kayex Technology Co., Ltd., Wuxi 214000, China

Received:2023-05-20 Online:2023-07-15 Published:2023-08-16

摘要/Abstract

摘要： 采用多孔坩埚温度梯度法生长了0.6%Pr∶Ca_xSr_1-xF₂ (x=0, 0.3, 0.5, 0.7, 1.0)和0.6%Pr,5%R∶Ca_0.5Sr_0.5F₂(R=Y, Lu, Gd)系列碱土氟化物激光晶体,对其晶体结构、吸收和可见波段的荧光光谱及荧光衰减寿命进行了系统研究。通过吸收截面、发射截面、荧光寿命、荧光半峰全宽等光谱参数分析发现,0.6%Pr,5%Y∶Ca_0.5Sr_0.5F₂混晶与其他掺杂混晶相比,具有最佳的光谱效果,443 nm处吸收截面和640 nm处红光发射截面分别为1.63×10^-20和3.39×10^-20 cm²,相应荧光半峰全宽和荧光寿命分别为4.50 nm和42.8 μs,光谱参数与0.6%Pr∶Ca_xSr_1-xF₂ (x=0, 0.3, 0.5, 0.7, 1.0)混晶相比有显著的提升。结果表明,0.6%Pr,5%Y∶Ca_0.5Sr_0.5F₂晶体具有极大的潜力作为新型Pr³⁺掺杂宽带激光材料的增益介质。

关键词: 激光晶体, 碱土氟化物, Pr³⁺掺杂, 可见激光, 发光性能

Abstract: In this paper, 0.6%Pr∶Ca_xSr_1-xF₂ (x=0, 0.3, 0.5, 0.7, 1.0) and 0.6%Pr, 5%R∶Ca_0.5Sr_0.5F₂ (R=Y, Lu, Gd) crystals were grown by porous crucible temperature gradient technology. The crystal structure, absorption spectra, fluorescence spectra and fluorescence lifetime were systematically analyzed and discussed. Through the analysis of spectral parameters such as absorption cross section, emission cross section, fluorescence lifetime and fluorescence full width at half maximum (FWHM), it is concluded that 0.6%Pr,5%Y∶Ca_0.5Sr_0.5F₂ mixed crystals have the best spectral parameter compared with other doped mixed crystals. The corresponding absorption cross sections at 443 nm and red emission cross sections at 640 nm are 1.63×10^-20 and 3.39×10^-20 cm², respectively. The FWHM and fluorescence lifetime are fitted to be 4.50 nm and 42.8 μs, respectively. The spectral parameters have been greatly improved compared with 0.6%Pr∶Ca_xSr_1-xF₂ (x=0, 0.3, 0.5, 0.7, 1.0) mixed crystals. All results show that 0.6%Pr,5%Y∶Ca_0.5Sr_0.5F₂ crystals have great potential as gain media for novel Pr³⁺ doped broadband laser material.

Key words: laser crystal, alkaline earth fluoride, Pr³⁺ doping, visible laser, luminescence property

中图分类号:

O78
O734

王无敌, 王庆国, 薛艳艳, 唐慧丽, 徐子寒, 张晨波, 房前成, 吴锋, 罗平, 徐晓东, 苏良碧, 李岩, 韩建峰, 逯占文, 徐军. Pr³⁺掺杂碱土混合氟化物激光晶体的生长与发光性能研究[J]. 人工晶体学报, 2023, 52(7): 1258-1269.

WANG Wudi, WANG Qingguo, XUE Yanyan, TANG Huili, XU Zihan, ZHANG Chenbo, FANG Qiancheng, WU Feng, LUO Ping, XU Xiaodong, SU Liangbi, LI Yan, HAN Jianfeng, LU Zhanwen, XU Jun. Growth and Luminescence Properties of Pr³⁺ Doped Alkaline Earth Mixed Fluoride Laser Crystals[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(7): 1258-1269.

参考文献

[1] 徐军. 激光晶体材料的发展和思考[J]. 激光与光电子学进展, 2006, 43(9): 17-24.
XU J. Recent developments and research frontier of laser crystals[J]. Laser & Optoelectronics Progress, 2006, 43(9): 17-24 (in Chinese).
[2] 徐军. 新型激光晶体材料及其应用[M]. 北京: 科学出版社, 2016.
XU J. New laser crystal materials and their applications[M]. Beijing: Science Press, 2016 (in Chinese).
[3] TANAKA H, KALUSNIAK S, BADTKE M, et al. Visible solid-state lasers based on Pr³⁺ and Tb³⁺[J]. Progress in Quantum Electronics, 2022, 84: 100411.
[4] KRÄNKEL C, MARZAHL D T, MOGLIA F, et al. Out of the blue: semiconductor laser pumped visible rare-earth doped lasers[J]. Laser & Photonics Reviews, 2016, 10(4): 548-568.
[5] LIN X J, CHEN M P, FENG Q C, et al. LD-pumped high-power CW Pr³⁺∶YLF laguerre-gaussian lasers at 639 nm[J]. Optics & Laser Technology, 2021, 142: 107273.
[6] LIN X J, ZHU Y, JI S H, et al. Highly efficient LD-pumped 607 nm high-power CW Pr³⁺∶YLF lasers[J]. Optics & Laser Technology, 2020, 129: 106281.
[7] METZ P W, HASSE K, PARISI D, et al. Continuous-wave Pr³⁺∶BaY₂F₈ and Pr³⁺∶LiYF₄ lasers in the cyan-blue spectral region[J]. Optics Letters, 2014, 39(17): 5158-5161.
[8] METZ P W, REICHERT F, MOGLIA F, et al. High-power red, orange, and green Pr³⁺∶LiYF₄ lasers[J]. Optics Letters, 2014, 39(11): 3193-3196.
[9] LIU X R, LI Z A, SHI C K, et al. LD-pumped high-power continuous-wave Pr³⁺∶YLF deep red lasers at 718.5 and 720.8 nm[J]. Laser Physics, 2022, 32(2): 025801.
[10] ZHOU L B, ZOU J Y, ZHENG W X, et al. More than 2.3 W diode-pumped quasi-continuous-wave Pr, Mg∶SrAl₁₂O₁₉ bulk laser and the first demonstration of Co∶ZnSe-based passively Q-switched deep red laser at 724 nm[J]. Optics & Laser Technology, 2022, 145: 107471.
[11] FUJITA S, TANAKA H, KANNARI F. Output characteristics of Pr∶YAlO₃ and Pr∶YAG lasers pumped by high-power GaN laser diodes[J]. Applied Optics, 2020, 59(17): 5124.
[12] RUAN S, CHAI B H T, SUTHERLAND J M, et al. Kerr-lens mode-locked visible transitions of a Pr∶YLF laser[J]. Optics Letters, 1995, 20(9): 1041.
[13] SUTHERLAND J M, CHAI B H T, FRENCH P M W, et al. Visible continuous-wave laser transitions in Pr³⁺∶YLF and femtosecond pulse generation[J]. Optics Letters, 1996, 21(11): 797.
[14] ZHANG Y X, YU H H, ZHANG H J, et al. Laser-diode pumped self-mode-locked praseodymium visible lasers with multi-gigahertz repetition rate[J]. Optics Letters, 2016, 41(12): 2692.
[15] ZHANG Y X, YU H H, ZHANG R, et al. Broadband atomic-layer MoS₂ optical modulators for ultrafast pulse generations in the visible range[J]. Optics Letters, 2017, 42(3): 547.
[16] ZHANG Y X, MIAO R L, LU D Z, et al. Kerr-lens mode-locked Pr³⁺∶LuLiF₄ laser[J]. Optics Letters, 2019, 44(15): 3665.
[17] ZHENG W X, ZOU J Y, WANG D, et al. Exploring the potential of Pr³⁺∶LiY_0.3Lu_0.7F₄ mixed crystal for diode-pumped watt-level continuous-wave lasers in the visible region[J]. Optics & Laser Technology, 2022, 151: 108023.
[18] LUO S Y, GU H, GENG X, et al. A diode-pumped femtosecond Pr∶YLF laser emitting at the near-infrared 915 nm[J]. Optics & Laser Technology, 2022, 151: 107993.
[19] LI N, HUANG J J, XU B, et al. Direct generation of an ultrafast vortex beam in a CVD-graphene-based passively mode-locked Pr∶LiYF₄ visible laser[J]. Photonics Research, 2019, 7(11): 1209.
[20] 苏良碧. 稀土掺杂氟化物激光晶体的局域结构设计与应用[C]//第二届全国光电材料与器件学术研讨会摘要集, 2021:27.
SU L B. Local Structure design and application of rare earth doped fluoride laser crystals[C]//The 2nd National Symposium on Optoelectronic Materials and Devices, 2021:27.
[21] MA F K, ZHANG Z, JIANG D P, et al. Neodymium cluster evolution in fluorite laser crystal: a combined DFT and synchrotron X-ray absorption fine structure study[J]. Crystal Growth & Design, 2022, 22(7): 4480-4493.
[22] 刘景和. 晶体生长与相变驱动力[J]. 长春光学精密机械学院学报, 1985, 8(3): 68-77.
LIU J H. The crystal growth and driving force of transition[J]. Journal of Changchun Institute of Optics and Fine Mechanics, 1985, 8(3): 68-77 (in Chinese).
[23] YU P R, BEARD M C, ELLINGSON R J, et al. Absorption cross-section and related optical properties of colloidal InAs quantum dots[J]. The Journal of Physical Chemistry B, 2005, 109(15): 7084-7087.
[24] SWINEHART D F. The beer-lambert law[J]. Journal of Chemical Education, 1962, 39(7): 333.
[25] AULL B, JENSSEN H. Vibronic interactions in Nd∶YAG resulting in nonreciprocity of absorption and stimulated emission cross sections[J]. IEEE Journal of Quantum Electronics, 1982, 18(5): 925-930.

Pr³⁺掺杂碱土混合氟化物激光晶体的生长与发光性能研究

Growth and Luminescence Properties of Pr³⁺ Doped Alkaline Earth Mixed Fluoride Laser Crystals

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王迪, 汤港, 张博, 王墉哲, 张中晗, 姜大朋, 寇华敏, 苏良碧. Nd,Y∶SrF₂激光晶体的位错缺陷表征及分布研究[J]. 人工晶体学报, 2023, 52(7): 1208-1218.
[2]	李兴旺, 韩剑锋, 芦佳, 邢晓文, 王永国, 魏磊, 徐学珍. 大尺寸Tm∶YAP复合激光晶体的生长与性能研究[J]. 人工晶体学报, 2023, 52(7): 1236-1242.
[3]	黄建华, 吴杰, 黄艺东, 林炎富, 龚兴红, 陈雨金. Er³⁺,Yb³⁺∶Ba₃Gd(PO₄)₃晶体的生长、光谱和1.5 μm激光性能[J]. 人工晶体学报, 2023, 52(7): 1286-1295.
[4]	李兴旺, 杨国利, 韩剑锋, 王永国, 毕海, 徐学珍. 提拉法生长直径10英寸优质Yb:YAG激光晶体[J]. 人工晶体学报, 2023, 52(4): 547-549.
[5]	尹子龙, 冯光文, 陈恒雷. 不同合成方法对LiMgPO₄∶Dy发光性能的影响[J]. 人工晶体学报, 2023, 52(2): 315-321.
[6]	郑万国, 齐红基. 人类首次实现聚变“点火”,激光聚变取得历史性突破[J]. 人工晶体学报, 2023, 52(1): 1-7.
[7]	张振, 樊仲维, 苏良碧. 高功率激光与“超热导”激光晶体[J]. 人工晶体学报, 2022, 51(9-10): 1560-1572.
[8]	赵呈春, 张沛雄, 李善明, 房倩楠, 徐民, 陈振强, 杭寅. 稀土离子掺杂氟化物激光晶体研究进展[J]. 人工晶体学报, 2022, 51(9-10): 1573-1587.
[9]	张文谦, 孙威, 曹铎, 牛亚杰, 吴文荣, 王东飞. 一种钡金属有机框架材料的合成及其晶体结构和发光性能的研究[J]. 人工晶体学报, 2022, 51(8): 1370-1377.
[10]	秦英恋, 秦建芳. 基于构象灵活的N-杂环配体构筑的3D拟卤化亚铜配合物的合成、结构和性质研究[J]. 人工晶体学报, 2022, 51(6): 1059-1068.
[11]	董建树, 王庆国, 徐军, 薛艳艳, 王无敌, 曹笑, 唐慧丽, 吴锋, 罗平. 多孔坩埚温度梯度法生长Ho,Y∶CaF₂晶体及其光谱性能[J]. 人工晶体学报, 2022, 51(2): 200-207.
[12]	夏士兴, 周龙, 许聪, 魏磊, 丁宇, 张丰发. 双温区热扩散掺杂Fe²⁺∶ZnSe激光晶体的制备及激光输出性能[J]. 人工晶体学报, 2022, 51(11): 1845-1850.
[13]	王贝贝, 刘文鹏, 任浩, 张传成, 刘海莲, 邹勇, 丁守军. 钆钪铝石榴石单晶缺陷的微观形貌与成因研究[J]. 人工晶体学报, 2022, 51(11): 1851-1857.
[14]	李浩来, 杨伟斌, 林易展, 凌爽, 熊飞兵. Sr₇Sb₂O₁₂∶Dy³⁺荧光粉的制备及其发光性能[J]. 人工晶体学报, 2022, 51(11): 1921-1928.
[15]	王俣欢, 陈永杰, 张文花, 耿秀娟, 杨英. Li(Na, K)Ba(Sr, Ca)B₉O₁₅∶Eu³⁺荧光粉的制备及发光性能[J]. 人工晶体学报, 2021, 50(9): 1694-1701.