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Journal of Synthetic Crystals ›› 2025, Vol. 54 ›› Issue (4): 629-635.DOI: 10.16553/j.cnki.issn1000-985x.2024.0245

• Research Articles • Previous Articles     Next Articles

First-Principles Study of Multiferroic Properties of V and Cr Doped TiOCl2 Monolayer

XU Huakai, LAI Guoxia, SU Kunren, XU Xiangfu, CHE Youda, HE Yan, CHEN Xingyuan   

  1. School of Science, Guangdong University of Petrochemical Technology, Maoming 525000, China
  • Received:2024-10-14 Online:2025-04-15 Published:2025-04-28

Abstract: Two-dimensional multiferroic materials with both ferroelectric and magnetic properties show significant applications in next-generation memory storage and spintronics. TiOCl2 monolayer has potential ferroelectric properties. However, due to the 3d0 electron configuration of Ti ions, it exhibits weaker magnetic properties, in order to enhance ferromagnetism, the multiferroic properties of V and Cr doped TiOCl2 monolayer are calculated by the first-principles simulations in this paper. The results demonstrate that double-site doping with V ions favors the formation of a spatially dispersed structural configuration, leading to an electronic structure characterized by antiferromagnetic coupling while maintaining a high ferroelectric polarization strength in the system. In the case of Cr ion double-site doping, analysis of spin charge density and Bader charge reveals that the two Cr ions form a nearest-neighbor Cr—O—Cr ferromagnetic coupling, TiOCl2 monolayer achieves the coexistence of strong ferromagnetism and high-speed iron polarization, and the bandgap also shows a decreasing trend due to Cr doping. These findings provide a reference for extending the TiOCl2 monolayer to achieve multiferroic behavior.

Key words: 2D multiferroic material, TiOCl2, magnetic, ferroelectric, V doping, Cr doping

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