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JOURNAL OF SYNTHETIC CRYSTALS ›› 2001, Vol. 30 ›› Issue (2): 123-128.

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Study on Cooperation Effect of Dopant Ions in Growth of KTNNP Crystals

CHANG Xin-An;ZANG He-gui;XIAO Wei-qiang;ZHANG Xiao-hong;JIANG Shao-lin;WANG Xi-min;ZHANG Ke-cong   

  • Online:2001-02-15 Published:2021-01-20

Abstract: The Nd3+ and Nb5+ doped KTP(KTNNP) crystals with different dopant concentrations have been grown in high temperature solutions.The lattice parameter of the crystals have been determined by X-ray diffractometer,and the concentrations of the dopants in the crystals have been measured systematically by ICP-AES.The result of the experiments shows that the growth habit and the morphology of KTP crystal have changed greatly and the distribution coefficient of Nd3+ has increased obviously after the doping of Nd3+ and Nb5+ in the crystal growth system,the latter incarnates the cooperation effect of Nb5+ on Nd3+.Otherwise,the volume of the crystal unit cell increase slightly with no regularity after doping.

Key words: The Nd3+ and Nb5+ doped KTP(KTNNP) crystals with different dopant concentrations have been grown in high temperature solutions.The lattice parameter of the crystals have been determined by X-ray diffractometer,and the concentrations of the dopants in the crystals have been measured systematically by ICP-AES.The result of the experiments shows that the growth habit and the morphology of KTP crystal have changed greatly and the distribution coefficient of Nd3+ has increased obviously after the doping of Nd3+ and Nb5+ in the crystal growth system,the latter incarnates the cooperation effect of Nb5+ on Nd3+.Otherwise,the volume of the crystal unit cell increase slightly with no regularity after doping.

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