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JOURNAL OF SYNTHETIC CRYSTALS ›› 2021, Vol. 50 ›› Issue (3): 435-440.

• Research Articles • Previous Articles     Next Articles

Preparation and Properties of Transparent Eu:Lu2O3 Scintillation Ceramics

WANG Jing1, GE Ye1, XIE Weifeng1,2, CHEN Haohong2, LI Jiang2   

  1. 1. College of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 231001, China;
    2. Key Laboratory of Inorganic Materials with Transparent Light Function, Shanghai Institute of Ceramics,Chinese Academy of Sciences, Shanghai 200050, China
  • Received:2020-12-14 Online:2021-03-15 Published:2021-04-15

Abstract: The 5% Eu:Lu2O3 ceramic precursor was synthesized by wet chemical method, and the morphologies, microstructures and phases of both Eu:Lu2O3 ceramic precursor and the calcined Eu:Lu2O3 ceramic powders were studied by SEM and XRD. The results show that the powders are spherical, well-dispersed and good crystalline. The particle size is calculated to be about 68.5 nm. Using the powders calcined at 1 100 ℃ for 4 h as raw material, the highly transparent Eu:Lu2O3 ceramics were successfully fabricated by vacuum sintering at 1 650 ℃ for 30 h.The grain size is calculated to be about 46 μm, and in-line transmittance of the Eu:Lu2O3 ceramics reaches 66.3% at 611 nm. What's more, the absorption curve, the excitation spectrum, the emission spectrum and the X-ray excited emission spectrum of the Eu:Lu2O3 ceramics were studied. It can be observed that the absorption curve of Eu:Lu2O3 ceramics is consisted of the matrical absorption and active ion absorption. It can be seen from the photo-luminescence emission spectrum and X-ray excited emission spectrum of the Eu:Lu2O3 ceramics that an extremely strong peak is located at 611 nm, corresponding to the 5D07F2 transition of Eu3+. By comparison with the BGO crystal, the light output of the Eu:Lu2O3 ceramics is estimated to be about 85 000 ph/MeV. Eu:Lu2O3 ceramics have an excellent X-ray stopping power due to its high density and effective atomic number. It is indicated that Eu:Lu2O3 ceramics are a potential ceramic scintillator for the application of X-ray detection imaging combined with the characteristics of high light output.

Key words: Eu:Lu2O3, scintillation ceramics, transparent ceramics, vacuum sintering, photo-luminescence, emission spectrum, light output

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