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JOURNAL OF SYNTHETIC CRYSTALS ›› 2022, Vol. 51 ›› Issue (5): 865-874.

Special Issue: 超硬材料与特殊环境晶体生长技术

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Doping, Surface/Interface Regulation and Properties of Nanocrystalline Diamond Films

HU Xiaojun, ZHENG Yuhao, CHEN Chengke, LU Shaohua, JIANG Meiyan, LI Xiao   

  1. College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • Received:2022-02-21 Online:2022-05-15 Published:2022-06-17

Abstract: In this paper, doping, electric conductivity, field emission and electrochemical properties of nanocrystalline diamond films are reviewed, which contain n-type nanocrystalline diamond (NCD) films prepared by chemical vapor deposition, improvement of n-type electrical conductivity in NCD films by ion implantation, excellent field emission properties of NCD films prepared by metal ion implantation, high mobility n-type conductivity obtained by low dose ion implantation and oxygen termination on grain surface, regulation of the structure of NCD/graphene and its influence on electrical and electrochemical properties, microstructure and electrochemical regulation of boron-doped NCD film electrodes and so on. It shows through comprehensive analysis that grain doping and surface/interface coordination can improve the electrical properties, field emission properties and electrochemical properties of thin films, which has important application prospects in the fields of diamond-based nano-electronic devices and electrochemical electrodes.

Key words: nanocrystalline diamond film, doping, surface state, electrical property, n-type conductivity, p-type conductivity

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