Cu(I) Organic Framework Based on Semi-Rigid Imidazolium  Carboxylate Ligand: Synthesis, Crystal Structure and Property

Abstract

Abstract: Under solvothermal conditions, a new Cu(I) coordination polymer [Cu(H₂O)(MIBA)]_n was synthesized by using semi-rigid imidazole carboxylic acid ligand 4-(2-methylimidazole) benzoic acid and copper, in which MIBA is the negative monovalent anionic coordination polymer of 4-(2-methylimidazole) benzoic acid. The solid-state fluorescence properties of Cu(I) organic skeleton coordination polymer based on semi-rigid imidazole carboxylic acid ligands were studied at room temperature. The maximum emission peak of MIBA ligand is 433 nm, and the maximum emission peak of coordination polymer [Cu(H₂O)(MIBA)]_n is 412 nm, all of which show fluorescence properties. In addition, its crystal structure was characterized by X-ray single crystal diffractometer, infrared spectrum, thermogravimetric analysis and elemental analysis. X-ray single crystal diffraction shows that the polymer is a 3D→3D double interpenetrating network with a (6⁴·8²) four-connected single-node topology.

Key words: Cu(I) coordination polymer, semi-rigid imidazole carboxylic acid ligand, solvothermal method, topological structure, X-ray diffraction, fluorescence performance

CLC Number:

O641.4

PAN Huibin, WU Tingting, GAO Xia, LU Jiufu. Cu(I) Organic Framework Based on Semi-Rigid Imidazolium Carboxylate Ligand: Synthesis, Crystal Structure and Property[J]. Journal of Synthetic Crystals, 2023, 52(10): 1836-1841.

References

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Cu(I) Organic Framework Based on Semi-Rigid Imidazolium Carboxylate Ligand: Synthesis, Crystal Structure and Property

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