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JOURNAL OF SYNTHETIC CRYSTALS ›› 2023, Vol. 52 ›› Issue (2): 208-219.

Special Issue: 钙钛矿单晶与薄膜材料

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Research Progress of Perovskite Solar Cells Based on ZnO as Electron Transport Layer

LU Hui1,2, WEN Qian1, WANG Jiaqi1, SHA Simiao1, WANG Kang1, SUN Weidong2, WU Jiandong1,2, MA Jinfu1, HOU Chunping1, SHENG Zhilin1, FENG Weiguang3   

  1. 1. Ningxia Research Center of Silicon Target and Silicon-Carbon Negative Materials Engineering Technology, School of Materials Science and Engineering, North Minzu University, Yinchuan 750021, China;
    2. Yinchuan Aini Industrial Technology Development Co., Ltd., Yinchuan 750299, China;
    3. Qingdao Ruihai Property Management Co., Ltd., Qingdao 266041, China
  • Received:2022-10-27 Online:2023-02-15 Published:2023-03-08

Abstract: Perovskite solar cells (PSCs) with CH3NH3PbX3 (MAPbX3, X=Br, I, Cl) as light-absorbing layer are used as a new generation of low-cost, high-efficiency photovoltaic devices. Compared with other types of photovoltaic devices, this type of cell has the advantages of abundant raw materials, simple process, etc., and its efficiency has risen rapidly from 3.8% to 25.7% in less than 15 years. It is almost comparable to commercial silicon solar cells and has become a new star in the field of energy applications. Normally, zinc oxide (ZnO) has been widely studied as the most important electron transport layer (ETL) of PSCs because of its advantages such as easy processed, high electron mobility, low manufacturing cost, and diverse morphology and structure. In this paper, ETL of ZnO nano film with different structures is taken as the research object, and its application in PSCs is summarized. The research progress of PSCs based on different morphology ZnO nano structures is introduced in detail, and the main problems faced by this type of solar cells are analyzed. In addition, the development trend of this device is proposed.

Key words: perovskite solar cell, ZnO, electron transport layer, nano structure, CH3NH3PbX3, photoelectric conversion efficiency

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