Synthesis and Up-Conversion Luminescence Characteristics Study of Rb3GaF6∶Er3+,Yb3+ with Double Perovskite Structure

Abstract

Abstract: Double perovskite compounds are an excellent up-conversion host material with high chemical stability, low phonon energy, easy doping of rare earth ions and a variety of tunable crystallographic lattices. In this paper, Rb₃GaF₆∶Er³⁺, Yb³⁺ up-conversion luminescent materials with the double perovskite structure were synthesized by high-temperature solid-phase method at 600 ℃, and the composition, structure and luminescence characteristic were systematically characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (SEM) and fluorescence spectrometer. Under 980 nm excitation, the prepared samples produced green emission at 521 and 548/561 nm attributes to electron transitions on the ²H_11/2-⁴I_15/2 and ⁴S_3/2-⁴I_15/2 level of Er³⁺, respectively, and the red emission at 656 nm corresponding to electron transitions on the ⁴F_9/2-⁴I_15/2 level of Er³⁺. In addition, the up-conversion luminescence mechanism of Rb₃GaF₆∶Er³⁺,Yb³⁺ was also investigated.

Key words: double perovskite, Rb₃GaF₆∶Er³⁺,Yb³⁺, up-conversion, luminescence characteristic, rare earth doping, high-temperature solid-phase method, luminescence mechanism

CLC Number:

O482.31

LI Jingyuan. Synthesis and Up-Conversion Luminescence Characteristics Study of Rb₃GaF₆∶Er³⁺,Yb³⁺ with Double Perovskite Structure[J]. Journal of Synthetic Crystals, 2023, 52(2): 327-333.

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Synthesis and Up-Conversion Luminescence Characteristics Study of Rb₃GaF₆∶Er³⁺,Yb³⁺ with Double Perovskite Structure

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