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JOURNAL OF SYNTHETIC CRYSTALS ›› 2023, Vol. 52 ›› Issue (5): 842-848.

Special Issue: 半导体薄膜与外延技术

• Novel Thin Film Materials • Previous Articles     Next Articles

Effect of Annealing Method and Temperature on Structure, Morphology and Photoelectric Properties of CuI Thin Films by Layer by Layer Iodization

GENG Fangjuan1, YANG Lei2, ZHU Jiaqi1   

  1. 1. Center for Composite Materials and Structures, School of Astronautics, Harbin Institute of Technology, Harbin 150080, China;
    2. Center of Analysis Measurement, Harbin Institute of Technology, Harbin 150001, China
  • Received:2023-01-31 Online:2023-05-15 Published:2023-06-05

Abstract: CuI films can be prepared by the iodization of Cu metal films. In order to optimize the photoelectric properties of iodized CuI film, the CuI films were prepared with layer by layer iodization method, and then the CuI films were treated by post annealing and layer by layer annealing process. The structure, surface morphology and photoelectric properties of the samples by different annealing process were analyzed. The crystallinity of the CuI film is improved significantly after layer by layer annealing process. The surface density increases under the post annealing process, which can be ascribed to the movement of CuI grains along the two-dimensional plane. The transmittance of the CuI film increases to 80%~90% after post annealing process, and the resistivity of the CuI film is optimized to 0.034 Ω·cm after layer by layer annealing.

Key words: p-type, CuI, post annealing, layer by layer annealing, transmittance, electrical property, photoelectric property

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