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JOURNAL OF SYNTHETIC CRYSTALS ›› 2023, Vol. 52 ›› Issue (7): 1169-1194.

Special Issue: 激光与非线性光学晶体

• Key Technologies of Crystal Growth and Applications of Large Size Laser Crystal Materials • Previous Articles     Next Articles

Research Progress of Sesquioxide Crystals and Its Laser Performances in the Band of 1~3 μm

WANG Mengmeng1, YIN Yanru1, DING Xiaoyuan1, ZHANG Jing2, FU Xiuwei1, JIA Zhitai1,3, TAO Xutang1   

  1. 1. State Key Laboratory of Crystal Material, Shandong University, Jinan 250100, China;
    2. GK Optoelectronics Co., Ltd., Beijing 100094, China;
    3. Shandong Research Institute of Industrial Technology, Jinan 250100, China
  • Received:2023-06-25 Online:2023-07-15 Published:2023-08-16

Abstract: Sesquioxides are ideal host materials for mid-infrared laser with high power and energy for their excellent thermal properties, stable physical and chemical properties, low maximum phonon energy and strong crystal field. It is very difficult to prepare large crystals with high quality due to the extremely high melting point of sesquioxides. Researchers have conducted long-term research and exploration on the crystal growth of the sesquioxides. The fast development of laser technology in recent years, which put forward urgent requires for high-quality sesquioxide single crystals, has prompted a breakthrough in crystal growth technology. In this paper, based on the brief introduction of the properties and structures of sesquioxides, the research progress on crystal growth methods and defects of sesquioxides Lu2O3, Sc2O3 and Y2O3 are reviewed in detail. Further, the laser performances of rare earth ion-doped sesquioxides in the mid-infrared band from 1 μm to 3 μm are systematically summarized. Finally, the development of the sesquioxide single crystals in the future is also prospected.

Key words: sesquioxide, host material for laser, crystal growth, crystal defect, laser performance, Lu2O3, Sc2O3, Y2O3

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