Abstract: A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2)(named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O = 1:2:1:1:555.The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101]direction.

Key words: A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2)(named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O = 1:2:1:1:555.The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101]direction.