Synthesis and Crystal Structure of Mono-, Binuclear Copper(Ⅱ)  Ternary Complexes Based on 5-Sulfosalicylic Acid

Abstract

Abstract: Mono- and binuclear structure of ternary complexes of Cu(Ⅱ):[Cu(H₂biim)(Hssal) (H₂O)₂]·H₂O(1) and {[Cu(MeHbiim)(Hssal)(H₂O)]·0.5H₂O}₂ (2) (H₃ssal=5-sulfonylsalicylic acid, H₂biim=2,2′-diimidazole, MeHbiim=N-methyl-2,2′-diimidazole) were synthesized using 5-sulfosalicylic acid and imidazole derivatives as the ligands. The structures were characterized by elemental analysis, IR, UV-Vis, single crystal X-ray diffraction and TG analysis. X-ray crystallographic studies show that complex 1 belongs to monoclinic, P2₁/C space group. Each Cu (Ⅱ) ion is coordinated with one 5-sulfosalicylic acid anion, two water molecules and one biimidazole molecule to form five-coordinated mononuclear structural unit of distorted square pyramidal configuration. Binuclear Cu(II) complex 2 exhibits orthorhombic, P2(1)2(1)2(1) space group. One Cu(II) ion of binuclear structural unit is five-coordinated with geometry of square pyramid same as complex 1 and another Cu(II) ion is four-coordinated with geometry of quadrilateral plane. Compared to complex 1, 5-sulfonyl salicylic acid anion acted as a μ₂ bis-monodentate bridging ligand in complex 2. The fluorescence spectrum analysis shows that the complex 2 has good fluorescence property.

Key words: Cu(Ⅱ) complex, 5-sulfosalicylic acid, biimidazole, crystal structure, fluorescence property, bis-monodentate

CLC Number:

O614.121

YANG Lining, CHENG Zhao, MIAO Yanqing, LIANG Lingling. Synthesis and Crystal Structure of Mono-, Binuclear Copper(Ⅱ) Ternary Complexes Based on 5-Sulfosalicylic Acid[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(2): 331-337.

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Synthesis and Crystal Structure of Mono-, Binuclear Copper(Ⅱ) Ternary Complexes Based on 5-Sulfosalicylic Acid

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