Synthesis, Crystal Structure and Photocatalytic Properties of Nanosized La3+-Substituted Arsenotungstate Cluster

Abstract

Abstract: Based on the principle of molecular design and self-assembly, a novel rare earth based arsenotungstate was obtained by introducing rare earth La^Ⅲ ions into the lacunary polyoxotungstates clusters with vacancy structure by one-pot method with Na₂WO₄·2H₂O, NaAsO₂ and LaCl₃·6H₂O as the main materials. The structure and composition of this complex was confirmed by single-crystal X-ray diffraction, X-ray powder diffraction (PXRD), infrared spectroscopy (IR) and so on. The single crystal X-ray diffraction results show that the complex is in the monoclinic system, C2/c space group, and with the cell parameters of a=3.595 56(14) nm, b=1.222 48(4) nm, c=2.247 34(9) nm, β = 117.117 0(10)°, V=8.792 3(6) nm³, Z=4. The molecular formula of this compound is [(CH₃)₂NH₂]₈H_3.56[{LaO(H₂O)₂}{WO(H₂O)}{W_0.24(H₂O)₂}{AsW₉O₃₃}₂]. And the polyoxoanion [{LaO(H₂O)₂}{WO(H₂O)}{W_0.24(H₂O)₂}{AsW₉O₃₃}₂]^11.56- shows a novel sandwich type structure, which can be simply described as two trilacunary Keggin type{AsW₉O₃₃} units are linked by a {LaO(H₂O)₂} segment, a {WO(H₂O)} segment and a {W_0.24(H₂O)₂} segment. Catalytic degradation property of this compound for Rhodamine-B was further inverstigated. The results demonstrate that the compound shows good photocatalytic activity under the condition of 300 W Hg lamp irradiation, and the degradation efficiency reaches to 74%.

Key words: polyoxometalate, arsenotungstate, one-pot method, lanthanum complex, crystal structure, organic dye, photocatalytic degradation

CLC Number:

YANG Ling, SU Binbin, WANG Hongsheng, LI Jinzhao, LI Yesheng, CHEN Rui. Synthesis, Crystal Structure and Photocatalytic Properties of Nanosized La³⁺-Substituted Arsenotungstate Cluster[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1591-1598.

References

[1] DASHTIAN K, SHAHSAVARIFAR S, USMAN M, et al. A comprehensive review on advances in polyoxometalate based materials for electrochemical water splitting[J]. Coordination Chemistry Reviews, 2024, 504: 215644-215676.
[2] WANG Z M, XIN X, ZHANG M, et al. Recent advances of mixed-transition-metal-substituted polyoxometalates[J]. Science China Chemistry, 2022, 65(8): 1515-1525.
[3] WU H C, ZHI M N, SINGH V, et al. Elucidating white light emissions in Tm³⁺/Dy³⁺ codoped polyoxometalates: a color tuning and energy transfer mechanism study[J]. Dalton Transactions, 2018, 47(39): 13949-13956.
[4] 刘晓慧, 李慧, 徐娜. 还原型磷钼酸盐构筑的多酸基超分子化合物的合成及电催化性能研究[J]. 人工晶体学报, 2023, 52(11): 2034-2040.
LIU X H, LI H, XU N. Synthesis and electrocatalytic performance of a polyoxometalate-based supramolecular compound constructed with reduced phosphomolybdate[J]. Journal of Synthetic Crystals, 2023, 52(11): 2034-2040 (in Chinese).
[5] LIU X J, MA X, ZHANG J, et al. Synthesis, structure, and spectroscopic characterization of a 2-D organic-inorganic hybrid Cu^II-Er^III heterometallic arsenotungstate[J]. Arabian Journal of Chemistry, 2019, 12(8): 1925-1933.
[6] LIU J C, WANG J F, HAN Q, et al. Multicomponent self-assembly of a giant heterometallic polyoxotungstate supercluster with antitumor activity[J]. Angewandte Chemie, 2021, 60(20): 11153-11157.
[7] SONG N Z, LU M Y, LIU J C, et al. A giant heterometallic polyoxometalate nanocluster for enhanced brain-targeted glioma therapy[J]. Angewandte Chemie, 2024, 63(10): e202319700-e202319708.
[8] 孙佳馨, 李爽, 李晓慧, 等. 3-(3-吡啶)丙烯酸配体杂化的Keggin型多酸基超分子化合物的合成、结构及光催化性能[J]. 人工晶体学报, 2023, 52(8): 1485-1490.
SUN J X, LI S, LI X H, et al. Synthesis, structure and photocatalytic properties of a Keggin-type polyoxometalate-based supramolecular complex hybridized by 3-pyridineacrylic acid ligand[J]. Journal of Synthetic Crystals, 2023, 52(8): 1485-1490 (in Chinese).
[9] 王静怡, 张众, 王梓兰, 等. 吡啶鎓盐配体构筑的多钼酸基配合物的合成、结构及光催化性能[J]. 人工晶体学报, 2022, 51(7): 1227-1232.
WANG J Y, ZHANG Z, WANG Z L, et al. Synthesis, structure and photocatalytic properties of polymolybdate-based complex constructed by pyridinium ligand[J]. Journal of Synthetic Crystals, 2022, 51(7): 1227-1232 (in Chinese).
[10] LIU J C, HAN Q, CHEN L J, et al. A brief review of the crucial progress on heterometallic polyoxotungstates in the past decade[J]. CrystEngComm, 2016, 18(6): 842-862.
[11] SUNADA Y, YAMAGUCHI K, SUZUKI K. “Template synthesis” of discrete metal clusters with two- or three-dimensional architectures[J]. Coordination Chemistry Reviews, 2022, 469: 214673-214701.
[12] KAPURWAN S, SAHU P K, RAIZADA M, et al. [α-AsW₉O₃₃]^9- bridged hexagonal clusters of Ln(III) showing field induced SMM behavior: experimental and theoretical insight[J]. Dalton Transactions, 2023, 52(27): 9377-9388.
[13] CUI K Y, LI F Y, XU L, et al. Lanthanide-tungstobismuthate clusters based on[BiW₉O₃₃]^9- building units: synthesis, crystal structures, luminescent and magnetic properties[J]. Dalton Transactions, 2012, 41(16): 4871-4877.
[14] YANG L, LI L, GUO J P, et al. A nanosized gly-decorated praseodymium-stabilized selenotungstate cluster: synthesis, structure, and oxidation catalysis[J]. Chemistry, an Asian Journal, 2017, 12(18): 2441-2446.
[15] LI S Z, WANG Y, MA P T, et al. From a versatile arsenotungstate precursor to a large lanthanide-containing polyoxometalate-carboxylate hybrid[J]. CrystEngComm, 2014, 16(47): 10746-10749.
[16] CHEN W L, LI Y G, WANG Y H, et al. Building block approach to nanostructures: step-by-step assembly of large lanthanide-containing polytungstoarsenate aggregates[J]. Dalton Transactions, 2007(38): 4293-4301.
[17] RITCHIE C, SPELDRICH M, GABLE R W, et al. Utilizing the adaptive polyoxometalate [As₂W₁₉O₆₇(H₂O)]^14- to support a polynuclear lanthanoid-based single-molecule magnet[J]. Inorganic Chemistry, 2011, 50(15): 7004-7014.
[18] BROWN I D, ALTERMATT D. Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database[J]. Acta Crystallographica Section B Structural Science, 1985, 41(4): 244-247.
[19] LIU W T, THORP H H. Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes. 2. Refined distances and other enzymes[J]. Inorganic Chemistry, 1993, 32(19): 4102-4105.
[20] YANG L, LIU Q S, MA P T, et al. A CO^2-₃-containing, dimanganese-substituted silicotungstate trimer, K₉[H₁₄{SiW₁₀Mn^IIMn^IIIO₃₈}₃(CO₃)]·39H₂O[J]. Dalton Transactions, 2015, 44(30): 13469-13472.
[21] HUSSAIN F, GABLE R W, SPELDRICH M, et al. Polyoxotungstate-encapsulated Gd₆ and Yb₁₀ complexes[J]. Chemical Communications, 2009(3): 328-330.
[22] LI J, SHANG S X, LIN Z G, et al. Assembly of lanthanide-containing tungstotellurates(VI): syntheses, structures, and catalytic properties[J]. Frontiers in Chemistry, 2020, 8: 598961-598971.
[23] SHI D, SHANG S S, CHEN L J, et al. Three novel 2D organic-inorganic hybrid Cu^II-Ln^III heterometallic arsenotungstates[J]. Synthetic Metals. 2012;162(11-12):1030-1036.
[24] AN H Y, HU Y, WANG L, et al. 3D racemic microporous frameworks and 3D chiral supramolecular architectures based on Evans-Showell-type polyoxometalates controlled by the temperature[J]. Crystal Growth & Design, 2015, 15(1): 164-175.
[25] ZHANG C J, FU X, MA H Y, et al. A Ag-La heterometallic 2D layer based on mono-lacunary Keggin polyoxometalate: synthesis, structure, and photocatalytic property[J]. Solid State Sciences, 2017, 73: 36-40.

Synthesis, Crystal Structure and Photocatalytic Properties of Nanosized La³⁺-Substituted Arsenotungstate Cluster

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	CHU Dongdong, YANG Zhihua, PAN Shilie. Research Progress on Theoretical Design of Nonlinear Optical Materials via Data-Driven Approach [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1475-1493.
[2]	ZHENG Quan, LIU Xuechao, WANG Hao, ZHU Xinfeng, PAN Xiuhong, CHEN Kun, DENG Weijie, TANG Meibo, XU Hao, WU Honghui, JIN Min. Effect of Aluminum Doping on the Crystal Structure and Properties of Indium Selenide Crystals [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1528-1535.
[3]	JIAO Sihui, WU Hongping, YU Hongwei. CsBa₂ScB₈O₁₆: the First Rare-Earth Borate Simultaneously Containing Zero-Dimensional [B₃O₆] Units and One-Dimensional B—O Chains [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1550-1559.
[4]	WU Miao, SONG Juan, ZHOU Yunlong, REN Chuanqing. Synthesis, Crystal Structure and Fluorescence Properties of Zn(II) Complex Based on Pyrazine Carboxylic Acid Ligand [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1576-1582.
[5]	SHI Yiwei, YANG Ruijie, ZHANG Yingchun, WANG Xin, WANG Min, SONG Zhiguo. Synthesis, Characterization and Quantum Chemical Calculation of Cobalt Coordination Polymer with 4,4′-bipy Bridge [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1583-1590.
[6]	AN Hangyi, HUANG Yanxi, WANG Airong, WANG Xiaoli, LI Jiaming, SHI Zhongfeng. A Novel Three-Dimensional Ni (II) Complex: Synthesis, Crystal Structure and Detection for Fe³⁺, CrO^2-₄ and Cr₂O^2-₇ in Water [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1599-1607.
[7]	CHENG Jiajia, WU Mengqi, YANG Min, WANG Limei, WEI Rongmin. Synthesis, Crystal Structure and Quantum Chemistry Study on [Co^Ⅲ(DIEN)(N₃)₃] Complex [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(8): 1409-1415.
[8]	MAO Yunhong, ZHAO Chunshen. Synthesis, Crystal Structure and Antitumor Activity of 6-Fluoro-4-Hydroxy-3-Oxo-3,4-Dihydroquinoxaline-1 (2H)-Carboxylic Acid Tert-Butyl Ester [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(7): 1257-1268.
[9]	ZHOU Yunlong, SONG Juan, WU Miao, REN Chuanqing, JIN Lingxia. Synthesis, Crystal Structure and Properties of a Pyrazinyl Bipyridine Nickel Complex [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(6): 1026-1033.
[10]	LI Bo, WANG Feiyu, SHEN Hong, MAO Fengyin, LI Yonghui. Synthesis, Crystal Structures and Fluorescent Properties of Zn(II) Complexes Based on 4-Hydroxyisophthalic Acid and Nitrogen-Containing Heterocyclic Ligands [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(4): 692-700.
[11]	QIU Shiming, YAN Guanjie, LI Chunliu, WANG Shengjie. Process of Preparing Aurichalcite by Ammonia Distillation Method [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(4): 701-706.
[12]	LIN Taohai, ZHANG Jun, GE Qing, ZHANG Gangqiang, ZHANG Meili. Construction and Electrochemical Properties of Co/Ni Coordination Polymer Based on Flexible Phenyldiacetate [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(3): 534-540.
[13]	ZHANG Feipeng, LU Qingmei, LIU Weiqiang, ZHANG Dongtao, YUE Ming. Study on Electronic Structure and Magnetic Property of MnGa Binary Alloy under Isostatic Pressure [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(3): 541-550.
[14]	BAO Yuting, LIANG Yinong, SUN Zan. Synthesis, Structure and Characterization of a Strontium Complex [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(2): 293-299.
[15]	QI Jinyang, WANG Min, YANG Ruijie, ZHANG Yingchun, SONG Zhiguo. Study on the Structure and Catalytic Property of a Novel Benzenesulfonate-Imidazole Complex [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(2): 300-306.