大尺寸CsPbBr3晶体的熔体法生长研究进展

doi:10.16553/j.cnki.issn1000-985x.2024.0187

摘要/Abstract

摘要： 由于出色的高能射线解析能力和优秀的环境适应性,全无机卤化物CsPbBr₃吸引了众多研究者的关注。然而由于结构相变和热应力的存在,大尺寸CsPbBr₃晶体生长过程中容易产生应力,从而导致晶体表面出现裂纹、亚晶界或孪晶等缺陷,严重影响其性能。目前大尺寸高质量CsPbBr₃晶体仍然无法通过有效的手段进行批量化生产,因此开展大尺寸CsPbBr₃晶体的生长与性能研究具有重大理论意义和实际价值。本文简要综述了CsPbBr₃晶体的基本性质、制备方法及研究进展,主要讨论了垂直布里奇曼法生长CsPbBr₃晶体的影响因素,并对高质量CsPbBr₃晶体的生长提出了新的思路。

关键词: CsPbBr₃, 熔体法, 全无机卤化物, 区域熔炼, 辐射探测

Abstract: All-inorganic halide crystal CsPbBr₃ has gained significant attention due to its outstanding high-energy ray resolution capability and excellent environmental adaptability. However, due to the presence of structural phase transitions and thermal stresses, stress is prone to arise during the growth process of large-sized CsPbBr₃ crystals, leading to defects such as cracks on the crystal surface, subgrain boundaries and twin crystals. These defects have severely impact on the performance of CsPbBr₃ crystals. Currently, large-sized high-quality CsPbBr₃still can't be mass-produced through effective means, restricting its further application. Hence, conducting research on the growth and performance of large-sized CsPbBr₃ crystals holds great theoretical significance and practical value. This paper briefly summarizes the fundamental properties, crystal preparation methods and research progress of CsPbBr₃ crystals, mainly discussing the influencing factors of the vertical Bridgman growth method, and proposing novel optimization ideas for the growth of high-quality CsPbBr₃ crystals.

Key words: CsPbBr₃, melt method, all-inorganic halide, zone melting, radiation detection

中图分类号:

唐嘉, 孙志成, 张祖邦, 罗辉. 大尺寸CsPbBr₃晶体的熔体法生长研究进展[J]. 人工晶体学报, 2025, 54(1): 1-10.

TANG Jia, SUN Zhicheng, ZHANG Zubang, LUO Hui. Research Progress on the Growth of Large-Sized CsPbBr₃ Crystals by the Melt Method[J]. Journal of Synthetic Crystals, 2025, 54(1): 1-10.

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大尺寸CsPbBr₃晶体的熔体法生长研究进展

Research Progress on the Growth of Large-Sized CsPbBr₃ Crystals by the Melt Method

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