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人工晶体学报 ›› 2007, Vol. 36 ›› Issue (5): 1173-1177.

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大气开放式MOCVD氧化镁薄膜的生长及表征

王树彬;韩夏;马学锋   

  1. 北京航空航天大学材料科学与工程学院,北京,100083
  • 出版日期:2007-10-15 发布日期:2021-01-20

Growth and Characterization of the Magnesia Thin Film by Atmospheric-pressure MOCVD

WANG Shu-bin;HAN Xia;MA Xue-feng   

  • Online:2007-10-15 Published:2021-01-20

摘要: 以2,4-乙酰丙酮化镁为前驱体,衬底温度为480℃,采用MOCVD工艺,分别在玻璃、氧化铝陶瓷、单晶Si(111)和Si(100)衬底上生长了取向生长的氧化镁薄膜.X射线衍射结果表明,无论是采用玻璃、氧化铝、单晶Si(111)和Si(100)衬底,氧化镁薄膜都是沿着(100)晶面取向生长.通过扫描电镜观察得到,在单晶Si(100)衬底上生长的氧化镁薄膜表面平整致密.模拟卢瑟福背散射结果显示,沉积时间超过70min时,界面处发生硅向氧化镁层少量扩散现象.

关键词: 氧化镁薄膜;大气开放式金属有机化学气相沉积;X射线衍射;扩散

Abstract: High quality MgO thin films have been successfully grown on glass, Al2O3, Si(111) and Si (100) substrates at 480℃ by using atmospheric-pressure metalorganic chemical vapor deposition (APMOCVD) technique. Magnesium 2,4-pentanedionate was used as metalorganic source. X-ray diffraction experiments provided evidence that the MgO films grown on glass, Al2O3, Si (111) and Si (100) with (100) orientation were regardless of the substrate materials and orientations. The as-grown MgO film on Si(100) has a very smooth surface morphology and a nearly stoichiometric composition by scanning electron microscopy (SEM) and Rutherford backscattering (RBS). According to the simulation, diffusion of Si near the interface was found when the growth time reached 70min.

Key words: High quality MgO thin films have been successfully grown on glass, Al2O3, Si(111) and Si (100) substrates at 480℃ by using atmospheric-pressure metalorganic chemical vapor deposition (APMOCVD) technique. Magnesium 2,4-pentanedionate was used as metalorganic source. X-ray diffraction experiments provided evidence that the MgO films grown on glass, Al2O3, Si (111) and Si (100) with (100) orientation were regardless of the substrate materials and orientations. The as-grown MgO film on Si(100) has a very smooth surface morphology and a nearly stoichiometric composition by scanning electron microscopy (SEM) and Rutherford backscattering (RBS). According to the simulation, diffusion of Si near the interface was found when the growth time reached 70min.

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