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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (1): 43-49.

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化学气相沉积法制备CNOs及其磁选纯化研究

张敏;张卫珂;焦琛;杨宏艳;蔡慧中;张玉军   

  1. 太原理工大学环境科学与工程学院,太原,030024;太原理工大学环境科学与工程学院,太原030024; 电子科技大学光电信息学院,成都610054;山东大学材料科学与工程学院,济南,250100
  • 出版日期:2017-01-15 发布日期:2021-01-20
  • 基金资助:
    山西省自然科学基金(2015021062);中国博士后基金第59批面上基金(167747)

Synthesis and Magnetic Purification Research of CNOs by Chemical Vapor Deposition Method

ZHANG Min;ZHANG Wei-ke;JIAO Chen;YANG Hong-Yan;CHUA Hui-tong;ZHANG Yu-jun   

  • Online:2017-01-15 Published:2021-01-20

摘要: 以金属镍铁为催化剂,通过化学气相沉积法高选择性地制备了纳米洋葱碳( CNOs)。所制备的CNOs为内嵌金属核心与中空CNOs的混合物,常规的酸洗-煅烧纯化工艺往往会造成外层碳壳的破坏,形成无定型碳。通过对CNOs的铁磁性分析,提出了磁选分离工艺,可以有效地将内嵌金属的CNOs与空心CNOs分离,分离后空心CNOs纯度在95;以上。

关键词: 纳米洋葱碳;化学气相沉积;磁选法;纯化

Abstract: Carbon nano onions ( CNOs ) were high selectively synthesized through chemical vapor deposition method using Ni-Fe metal as catalysts. As harvested CNOs contains metal core inside and hollowed CNOs. Amorphous is formed with the broken of carbon shells through the normal acid wash -burning technology. The magnetic properties of CNOs were analysised and magnetic separating technology was proposed. The results show that CNOs with metal core inside can be separated from the hollowed CNOs efficiently using this method and the purification rate reaches up to 95;.

Key words: Carbon nano onions ( CNOs ) were high selectively synthesized through chemical vapor deposition method using Ni-Fe metal as catalysts. As harvested CNOs contains metal core inside and hollowed CNOs. Amorphous is formed with the broken of carbon shells through the normal acid wash -burning technology. The magnetic properties of CNOs were analysised and magnetic separating technology was proposed. The results show that CNOs with metal core inside can be separated from the hollowed CNOs efficiently using this method and the purification rate reaches up to 95;.

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