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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 1885-1890.

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SnCl4醇水溶液制备SnO2电子传输层及其在钙钛矿太阳电池中的应用

朱世杰;丁毅;郑翠翠;侯福华;姚鑫;张德坤;魏长春;王广才;赵颖;张晓丹   

  1. 南开大学,光电子薄膜器件与技术研究所,天津市光电子薄膜器件与技术重点实验室,天津 300071
  • 出版日期:2017-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(61474065,61674084,61504069);天津市重点基金(15JCZDJC31300);江苏省重点项目(BE2014147-3);教育部111引智项目(B16027)

Preparation of SnO2 Electron Transport Layer Using SnCl4 Alcohol Aqueous Solution and Its Application in Perovskite Solar Cells

ZHU Shi-jie;DING Yi;ZHENG Cui-cui;HOU Fu-hua;YAO Xin;ZHANG De-kun;WEI Chang-chun;WANG Guang-cai;ZHAO Ying;ZHANG Xiao-dan   

  • Online:2017-10-15 Published:2021-01-20

摘要: 二氧化锡因其具有高透过率及高电子迁移率已被广泛应用于钙钛矿太阳电池中作为电子传输层.本文采用无水SnCl4作为锡源前驱,乙醇作为溶剂,水作为氧化剂,通过SnCl4的水解反应制备了SnO2电子传输薄膜.研究发现改变溶液中水的比例,可以调控SnO2薄膜的形貌及光电性能.通过制备工艺优化、将其作为电子传输层最终获得了效率高达17.38;的平面钙钛矿太阳电池.

关键词: 二氧化锡;掺水量;钙钛矿太阳电池

Abstract: Because of the high rate of transmittance and electron mobility , SnO2 was widely used as the electron transport layer in perovskite solar cells .This artical explored a method of preparing SnO 2 electron transport layer through SnCl 4 hydrolysis process , which utilizes anhydrous SnCl 4 as tin precursor , ethanol as solvent and water as oxidant .It is found that the morphology and photoelectric properties of SnO 2 film can be modulated by adjusting the ratio of water to the solution .Through the optimization of production process, efficiency of planar perovskite solar cell improves up to 17.38;.

Key words: Because of the high rate of transmittance and electron mobility , SnO2 was widely used as the electron transport layer in perovskite solar cells .This artical explored a method of preparing SnO 2 electron transport layer through SnCl 4 hydrolysis process , which utilizes anhydrous SnCl 4 as tin precursor , ethanol as solvent and water as oxidant .It is found that the morphology and photoelectric properties of SnO 2 film can be modulated by adjusting the ratio of water to the solution .Through the optimization of production process, efficiency of planar perovskite solar cell improves up to 17.38;.

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