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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 1902-1906.

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Ho3+/Yb3+:8 YSZ纳米粉体制备及发光性能研究

罗军明;曹志超;邓莉萍;徐吉林   

  1. 南昌航空大学材料科学与工程学院,南昌,330063
  • 出版日期:2017-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(51362022);江西省自然科学基金重大项目(20152ACB2013)

Preparation and Luminescence Property of Ho3+/Yb3 +:8YSZ Nanopowders

LUO Jun-ming;CAO Zhi-chao;DENG Li-ping;XU Ji-lin   

  • Online:2017-10-15 Published:2021-01-20

摘要: 通过化学共沉淀法制备Ho3+/Yb3+共掺杂的氧化钇稳定的氧化锆(8YSZ)纳米粉体.研究了煅烧温度对Ho3+/Yb3+共掺杂8YSZ纳米粉体荧光光谱和上转换发光性能的影响.结果表明:在448 nm波长激发光激发下,Ho3+/Yb3+:8YSZ纳米粉体有一个549 nm的绿光发射峰,随着煅烧温度的升高,Ho3+/Yb3+:8YSZ纳米粉体的荧光强度先升高后降低.980 nm波长激光激发下,Ho3+/Yb3+:8YSZ纳米粉体在450~750 nm范围内有一个中心波长在539 nm的绿光发射峰和一个中心波长在650 nm的红光发射峰,随着煅烧温度的升高,纳米粉体的颗粒尺寸增大的同时,其上转换发光强度也逐渐增大.

关键词: Ho3+/Yb3+:8YSZ纳米粉体;化学共沉淀法;荧光光谱;上转换发光;煅烧温度

Abstract: Ho3 +/Yb3 + co-doped yttria-stabilized zirconia ( 8YSZ ) nano powders were prepared by chemical coprecipitation .The effect of calcination temperatures on the fluorescence spectra and up-conversion luminescence properties of the Ho 3+/Yb3+co-doped nano 8YSZ was investigated .The results show that the Ho 3+/Yb3 +co-doped 8YSZ nano powders have a green emission peak at 549 nm under excitation of the 448 nm wavelength excitation light .The luorescence intensity of the Ho 3+/Yb3+ co-doped 8 YSZ nanopowders increases first , and then decreases with increasing the calcination temperatures.Under excitation of the 980 nm wavelength laser , the Ho3+/Yb3+ co-doped 8YSZ nanopowders have a green emission peak at a central wavelength of 539 nm and a red emission peak at a central wavelength of 650 nm in the range of 450-750 nm.With increasing the calcination temperatures , the particle sizes of the nano powders increase and the upper conversion luminescence intensity also gradually increases .

Key words: Ho3 +/Yb3 + co-doped yttria-stabilized zirconia ( 8YSZ ) nano powders were prepared by chemical coprecipitation .The effect of calcination temperatures on the fluorescence spectra and up-conversion luminescence properties of the Ho 3+/Yb3+co-doped nano 8YSZ was investigated .The results show that the Ho 3+/Yb3 +co-doped 8YSZ nano powders have a green emission peak at 549 nm under excitation of the 448 nm wavelength excitation light .The luorescence intensity of the Ho 3+/Yb3+ co-doped 8 YSZ nanopowders increases first , and then decreases with increasing the calcination temperatures.Under excitation of the 980 nm wavelength laser , the Ho3+/Yb3+ co-doped 8YSZ nanopowders have a green emission peak at a central wavelength of 539 nm and a red emission peak at a central wavelength of 650 nm in the range of 450-750 nm.With increasing the calcination temperatures , the particle sizes of the nano powders increase and the upper conversion luminescence intensity also gradually increases .

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