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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 1992-1998.

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白光LED用荧光粉SrAl2Si2O8:Eu2+合成条件优化研究

王飞;田一光;张乔   

  1. 安徽三联学院实验中心,合肥 230601;安徽大学化学化工学院,合肥230601;温州大学化学与材料工程学院,温州,325035
  • 出版日期:2017-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(20771086);安徽省高校自然科学研究重点项目(KJ2016A893);安徽三联学院科研项目(2015Z001, 2013Z001);安徽三联学院质量工程项目(15zlgc008);国家级大学生创新创业项目(201710959055)

Study on Optimization of Synthesis Conditions of Phosphor SrAl2Si2O8:Eu2+for White LED

WANG Fei;TIAN Yi-guang;ZHANG Qiao   

  • Online:2017-10-15 Published:2021-01-20

摘要: Sr0.975 Al2 Si2 O8:Eu2+0.025系列荧光粉利用高温固相法合成,系统研究了预烧温度、预烧时间、烧成温度和助溶剂硼酸的量对荧光体晶体结构和发光性能的影响;研究结果表明,各试样均为单斜晶系SrAl2 Si2 O8,荧光体的X射线衍射强度、荧光体的晶粒尺寸及荧光体的发射强度,均随着预烧温度、预烧时间、烧成温度和助溶剂硼酸量的增加,呈先增加后减小的变化趋势.当预烧温度为1000℃,预烧时间为150 min,烧成温度为1250℃,助溶剂硼酸的量为6wt;,制得的荧光体Sr0.975 Al2 Si2 O8:Eu2+0.025的发光强度最强,优化了合成条件.

关键词: LED;SrAl2Si2O8:Eu2+;合成条件

Abstract: A series of luminescence phosphors Sr 0.975 Al2 Si2 O8 :Eu2+0.025 were prepared by solid-state reaction, the effect of the fisrt firing temperature ( T1 ), the fisrt firing time ( t), the second firing temperature(T2) and the concentration of flux H3BO3(W) on the spectrum characteristics and structure of the sample was investigated .The results show that the samples are monoclinic SrAl 2 Si2 O8 , emission intensity, grain size and intensity of X-ray diffraction of the phosphor increase with T1 , t, T2 and W, show the trend of increasing first and then decreasing .When the T1 =1000 ℃, t=150 min, T2 =1250℃, W=6wt;, the synthesis of phosphor Sr 0.975 Al2 Si2 O8:Eu2+0.025 luminescence intensity is strongest , the synthesis conditions are optimized .

Key words: A series of luminescence phosphors Sr 0.975 Al2 Si2 O8 :Eu2+0.025 were prepared by solid-state reaction, the effect of the fisrt firing temperature ( T1 ), the fisrt firing time ( t), the second firing temperature(T2) and the concentration of flux H3BO3(W) on the spectrum characteristics and structure of the sample was investigated .The results show that the samples are monoclinic SrAl 2 Si2 O8 , emission intensity, grain size and intensity of X-ray diffraction of the phosphor increase with T1 , t, T2 and W, show the trend of increasing first and then decreasing .When the T1 =1000 ℃, t=150 min, T2 =1250℃, W=6wt;, the synthesis of phosphor Sr 0.975 Al2 Si2 O8:Eu2+0.025 luminescence intensity is strongest , the synthesis conditions are optimized .

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