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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 2090-2094.

• • 上一篇    

多晶硅的反应离子刻蚀(R IE)制绒绒面研究

张婷;郭永刚;屈小勇;陈璐;王举亮   

  1. 国家电投集团西安太阳能电力有限公司,西安,710000
  • 发布日期:2021-01-20

Research on Surface Texture of Multicrystalline Silicon by Reactive Ion Etching

ZHANG Ting;GUO Yong-gang;QU Xiao-yong;CHEN Lu;WANG Ju-liang   

  • Published:2021-01-20

摘要: 实验基于反应离子刻蚀(Reaction Ion Eatching RIE)技术进行的多晶硅片纳米绒面制备,这种结构的绒面可明显降低晶体硅电池反射率,提高电池短路电流.实验具体指将多晶硅片在同一条件混酸溶液中腐蚀去除表面损伤,然后利用RIE制绒技术进行不同尺寸纳米绒面制备,根据绒面变化分别调整工艺进行清洗及电池制备,发现绒面小到一定程度时RIE制绒过程造成的损伤不易清洗去除且抗反射SiNx膜沉积困难.所以多晶硅片RIE制绒不可单纯的追求小绒面和低反射率,实验证明纳米绒面凹坑尺寸最小应控制在240~360 nm才能更稳定地匹配清洗、沉积抗反射膜等工艺从而制备出高光电转换效率的多晶硅电池.

关键词: 反应离子刻蚀(RIE);纳米凹坑绒面;反射率;SiNx膜沉积

Abstract: The experiment was based on ( Reaction Ion Eatching ) RIE technology to prepare polycrystalline silicon wafer with nano scale , the surface texture structure can obviously reduce the reflectivity and improve the short-circuit current of crystalline silicon cells .The experiment specifically refers to the etching of polysilicon wafers in the same mixed acid solution to remove surface damage , and used RIE technology to make texture with different size , then we adjusted the cleaning process and cleaned the wafer by according to the different texture to prepare cells .Finally we find that if the texture structure is very minimum , the damage on wafer can not be stripped completely and the antireflective SiNx is hard to deposition .The experiment results show that when prepared cells by RIE technology , the minimum texture structure and lowest reflectivity is not good , but the texture size of Nano pit should be controlled at 240 nm to 360 nm to match the cleaning and deposition of antireflective coatings more effectively , to be better made polycrystalline cells of high conversion efficiency .

Key words: The experiment was based on ( Reaction Ion Eatching ) RIE technology to prepare polycrystalline silicon wafer with nano scale , the surface texture structure can obviously reduce the reflectivity and improve the short-circuit current of crystalline silicon cells .The experiment specifically refers to the etching of polysilicon wafers in the same mixed acid solution to remove surface damage , and used RIE technology to make texture with different size , then we adjusted the cleaning process and cleaned the wafer by according to the different texture to prepare cells .Finally we find that if the texture structure is very minimum , the damage on wafer can not be stripped completely and the antireflective SiNx is hard to deposition .The experiment results show that when prepared cells by RIE technology , the minimum texture structure and lowest reflectivity is not good , but the texture size of Nano pit should be controlled at 240 nm to 360 nm to match the cleaning and deposition of antireflective coatings more effectively , to be better made polycrystalline cells of high conversion efficiency .

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