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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (5): 832-836.

• • 上一篇    下一篇

钙长石对刚玉-莫来石质陶粒支撑剂结构及性能的影响

马海强;田玉明;力国民;王凯悦;周毅;白频波   

  1. 太原科技大学材料科学与工程学院,太原,030024;山西工程职业技术学院,太原,030009;长青石油压裂支撑剂有限公司,阳泉,045240
  • 出版日期:2017-05-15 发布日期:2021-01-20
  • 基金资助:
    山西省高等学校科技创新项目(2016-59);山西省自然科学基金项目(201601D102019);山西省研究生联合培养基地人才培养项目(2016JD37、2017JD33);太原科技大学博士科研启动经费(20152030);山西省重点学科建设经费;山西省关键基础材料协同创新中心建设经费

Effect of Ca-Feldspar on the Structure and Performance of the Prepared Corundum-Mullite Ceramic Proppant

MA Hai-qiang;TIAN Yu-ming;LI Guo-min;WANG Kai-yue;ZHOU Yi;BAI Pin-bo   

  • Online:2017-05-15 Published:2021-01-20

摘要: 以二级铝矾土为主要原料,通过添加不同含量的长石在1350 ℃烧结温度下制备了高强度的刚玉-莫来石质陶粒支撑剂.通过X射线衍射(XRD)和扫描电子显微分析(SEM)对陶粒的物相组成及显微形貌进行表征.结果表明,所制备陶粒支撑剂的物相成组为刚玉和莫来石,而且发现随着长石添加量的逐步增加,可以明显促进莫来石的形核过程,并抑制其进一步长大.当长石添加量为8wt;时,所制备的陶粒支撑剂体积密度为1.72 g/cm3,在52 MPa闭合压力下的破碎率为3.2;,酸溶度为5.0;,满足油气开采行业的要求.

关键词: 陶粒支撑剂;长石;烧结温度;形核

Abstract: Ceramic proppant was prepared by the main raw material of 2nd grade bauxite and the additive of feldspar at 1350 ℃.The phase composition and microstructure of the proppant were characterized by XRD and SEM respectively.The results show that the phase composition of ceramic proppant is composed of corundum and mullite.As the content of feldspar increases, it is beneficial to boost the nucleation of mullite phase and restrain the growth of mullite.The prepared proppant displays the lowest breakage ratio of 3.2; under 52 MPa closed pressure, the bulk density of 1.72 g/cm3 and the acid solubility of 5.0; when adding 8wt; feldspar, which can meet the requirement in the field of oil and gas exploitation.

Key words: Ceramic proppant was prepared by the main raw material of 2nd grade bauxite and the additive of feldspar at 1350 ℃.The phase composition and microstructure of the proppant were characterized by XRD and SEM respectively.The results show that the phase composition of ceramic proppant is composed of corundum and mullite.As the content of feldspar increases, it is beneficial to boost the nucleation of mullite phase and restrain the growth of mullite.The prepared proppant displays the lowest breakage ratio of 3.2; under 52 MPa closed pressure, the bulk density of 1.72 g/cm3 and the acid solubility of 5.0; when adding 8wt; feldspar, which can meet the requirement in the field of oil and gas exploitation.

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