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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (9): 1709-1713.

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石墨衬底上铝诱导法制备多晶硅薄膜

魏立帅;陈诺夫;张航;王从杰;贺凯;白一鸣;陈吉堃   

  1. 华北电力大学可再生能源学院,北京,102206;北京科技大学材料科学与工程学院,北京,100083
  • 出版日期:2017-09-15 发布日期:2021-01-20
  • 基金资助:
    北京市自然科学基金(2151004);中央高校基本科研业务费专项资金(2016MS50)

Preparation of Polycrystalline Silicon Thin Film by AIC on Graphite Substrate

WEI Li-shuai;CHEN Nuo-fu;ZHANG Hang;WANG Cong-jie;HE Kai;BAI Yi-ming;CHEN Ji-kun   

  • Online:2017-09-15 Published:2021-01-20

摘要: 利用磁控溅射技术在石墨衬底上制备了石墨/a-Si/Al和石墨/Al/a-Si叠层结构,采用常规退火(CTA)和快速热退火(RTA)对样品进行退火,系统研究了不同退火条件对多晶硅薄膜制备的影响.利用X射线衍射(XRD),拉曼光谱(Raman)对制备的多晶硅薄膜进行表征,并利用谢乐公式计算了晶粒尺寸,结果表明制备的多晶硅薄膜具有高度(111)择优取向,结晶质量良好,利于后续外延制作多晶硅厚膜电池.基于实验结果,建立了铝诱导晶化模型,很好的解释了实验现象.

关键词: 磁控溅射;铝诱导;石墨衬底;多晶硅薄膜

Abstract: In this paper , graphite/a-Si/Al and graphite/Al/a-Si laminated structures were prepared on graphite substrate by magnetron sputtering , and systematically studied the effects of the samples annealed by conventional annealing ( CTA) and rapid annealing ( RTA) .The poly-Si thin films were characterized by means of X-ray diffraction (XRD), Raman spectroscopy (Raman), and the grain size was calculated by the Scherrer formula , which show that the samples with strong preferred ( 111 ) orientation and high crystallization quality are ideal for epitaxial growth poly-Si thick film cells.At the same time, we established the AIC model to explain the mechanism in the inverted AIC process .

Key words: In this paper , graphite/a-Si/Al and graphite/Al/a-Si laminated structures were prepared on graphite substrate by magnetron sputtering , and systematically studied the effects of the samples annealed by conventional annealing ( CTA) and rapid annealing ( RTA) .The poly-Si thin films were characterized by means of X-ray diffraction (XRD), Raman spectroscopy (Raman), and the grain size was calculated by the Scherrer formula , which show that the samples with strong preferred ( 111 ) orientation and high crystallization quality are ideal for epitaxial growth poly-Si thick film cells.At the same time, we established the AIC model to explain the mechanism in the inverted AIC process .

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