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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (9): 1875-1878.

• • 上一篇    

γ-Bi2Sn2O7的水热合成及其可见光区光电响应研究

焦岳超;刘献省;瞿博阳;张鹏;闫李;朱永胜;付凯   

  1. 中原工学院电子信息学院,郑州,450007;河南大学物理电子学院,光伏材料省重点实验室,开封 475004
  • 出版日期:2017-09-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金面上项目(61673404);国家自然科学基金青年基金(61305080)

Hydrothermal Synthesis ofγ-Bi2 Sn2 O7 and Its Photoelectric Response Research in Visible Light Zone

JIAO Yue-chao;LIU Xian-sheng;QU Bo-yang;ZHANG Peng;YAN Li;ZHU Yong-sheng;FU Kai   

  • Online:2017-09-15 Published:2021-01-20

摘要: 本文采用水热法制备了γ-Bi2Sn2O7并研究了其在可见光区的光电响应.Bi2Sn2O7的晶体结构和光电响应特性分别用X射线衍射和表面光电压谱进行表征.研究结果表明,合成的Bi2Sn2O7呈现γ相立方结构,通过吸收光谱估算光学带隙为2.67eV,比α-Bi2O3(2.85eV)的光学带隙小.Bi2Sn2O7的光电响应相对于α-Bi2O3在可见光区展现出一定的优势,同时对外加电压有很强的响应.

关键词: Bi2Sn2O7;光电响应;可见光吸收;表面光电压谱;电场诱导

Abstract: Gamma phase (γ) Bi2 Sn2 O7 was synthesized by hydrothermal method and its photoelectric response in visible light was investigated .The structure and photoelectric response properties were characterized by X-ray diffraction and surface photovoltage spectroscopy . The results show the as-prepared Bi2 Sn2 O7 presents a presents a gamma (γ) phase cubic structure and has an optical band gap (2.67 eV) measured by absorption spectrum , which is narrower than that of α-Bi2O3 (2.85 eV).The photoelectric response of Bi 2 Sn2 O7 in visible light area displays its advantage compared with α-Bi2 O3 . Meanwhile , it has strong response under the applied voltage .

Key words: Gamma phase (γ) Bi2 Sn2 O7 was synthesized by hydrothermal method and its photoelectric response in visible light was investigated .The structure and photoelectric response properties were characterized by X-ray diffraction and surface photovoltage spectroscopy . The results show the as-prepared Bi2 Sn2 O7 presents a presents a gamma (γ) phase cubic structure and has an optical band gap (2.67 eV) measured by absorption spectrum , which is narrower than that of α-Bi2O3 (2.85 eV).The photoelectric response of Bi 2 Sn2 O7 in visible light area displays its advantage compared with α-Bi2 O3 . Meanwhile , it has strong response under the applied voltage .

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