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人工晶体学报 ›› 2020, Vol. 49 ›› Issue (12): 2297-2301.

• 研究论文 • 上一篇    下一篇

炭吸附水热法制备TmFeO3及其光催化性能研究

张明远, 张彦斌, 牛宇彤, 郭贵宝   

  1. 内蒙古科技大学化学与化工学院,包头 014010
  • 出版日期:2020-12-15 发布日期:2021-01-25
  • 通信作者: 郭贵宝,教授。E-mail:ggb66733@sohu.com
  • 作者简介:张明远(1999—),男,山东省人。E-mail:1085349281@qq.com
  • 基金资助:
    国家自然科学基金(21463026)

Photocatalytic Properties of TmFeO3 Adsorbed on Carbon Prepared by Hydrothermal Method

ZHANG Mingyuan, ZHANG Yanbin, NIU Yutong, GUO Guibao   

  1. School of Chemistry and Chemical Engineering, Inner Mongolia University of Science & Technology, Baotou 014010, China
  • Online:2020-12-15 Published:2021-01-25

摘要: 利用炭吸附水热法制备钙钛矿型TmFeO3纳米粉体,通过X射线衍射仪(XRD),热重-差热分析仪(TG-DTA),紫外可见分光光度计(UV-Vis)和气相色谱仪等设备分析晶体比表面积、热稳定性、吸光性能及物相结构。以全谱镝灯为可见光光源,通过催化甲基橙降解,评价TmFeO3粉体的光催化性能。实验结果表明,炭吸附水热法制得的TmFeO3粉体有更高的结晶度和热稳定性,且比表面积大,吸收可见光范围增大,吸光性能更好。光催化降解甲基橙实验结果表明,光照140 min时对甲基橙的降解率达88%,是普通水热合成法制得的TmFeO3催化性能的1.5倍。

关键词: 铁酸铥, 炭吸附, 水热法, 纳米粉体, 光催化性能

Abstract: The TmFeO3 nano powder with perovskite type adsorbed on carbon were prepared by hydrothermal method. Their specific surface area, thermal stability, absorption property and physical structure of the crystal were analyzed by X-ray diffraction(XRD), thermal gravimetric-differential thermal analyzer(TG-DTA), ultraviolet visible spectrophotometer(UV-Vis) and gas chromatograph. The photocatalytic properties of TmFeO3 powder was evaluated by degradation of methyl orange using dysprosium lamp as visible light source. The experimental results show that TmFeO3 adsorbed on carbon prepared by hydrothermal method has better crystallinity, higher thermal stability, larger specific surface area, larger visible absorption range and better absorptivity. The experimental results of photocatalytic degradation of methyl orange show that the degradation rate of TmFeO3 adsorbed on carbon methyl orange reaches 88% after light irradiation for 140 min and is 1.5 times of TmFeO3 prepared by ordinary hydrothermal method.

Key words: TmFeO3, carbon adsorption, hydrothermal method, nano powder, photocatalytic property

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