Er3+单掺与Er3+/Yb3+共掺NBT-CT无铅压电陶瓷的上转换发光性能研究

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (1): 138-143.

Er³⁺单掺与Er³⁺/Yb³⁺共掺NBT-CT无铅压电陶瓷的上转换发光性能研究

马春林, 周越, 马晨宇, 董倩文, 吴瑾, 范雨香, 翟章印

淮阴师范学院物理与电子电气工程学院,淮安 223300

收稿日期:2020-09-30 出版日期:2021-01-15 发布日期:2021-03-01
作者简介:马春林(1980—),女,江苏省人,博士。E-mail:mchl88@163.com
基金资助:
江苏省高等学校自然科学研究基金(19KJA150011);淮安市自然科学研究计划(HAB202056);江苏省高等学校大学生创新创业训练计划(201917011XJ,202010323074Y)。

Up-Conversion Luminescence Property of Er³⁺ Doped and Er³⁺/Yb³⁺ Co-Doped NBT-CT Lead-Free Piezoelectric Ceramics

MA Chunlin, ZHOU Yue, MA Chenyu, DONG Qianwen, WU Jin, FAN Yuxiang, ZHAI Zhangyin

School of Physics and Electronic and Electrical Engineering, Huaiyin Normal University, Huai'an 223300, China

Received:2020-09-30 Online:2021-01-15 Published:2021-03-01

摘要/Abstract

摘要： 采用固相烧结法制备一系列Er³⁺单掺与Er³⁺/Yb³⁺共掺0.96Na_0.5Bi_0.5TiO₃-0.04CaTiO₃(NBT-CT∶xEr³⁺/yYb³⁺,x=0.002~0.015,y=0.010)无铅压电陶瓷。通过X射线衍射仪和荧光光谱仪分别对样品的物相结构和上转换发光特性进行表征和分析。结果表明,样品的主晶相为NBT晶相。在波长为980 nm的近红外光激发下,Er³⁺单掺与Er³⁺/Yb³⁺共掺NBT-CT陶瓷均呈现强的以绿光为主的Er³⁺特征上转换发光。在NBT-CT∶xEr³⁺中,当x=0.010时上转换发光性能最佳;Yb³⁺能够起到敏化作用,明显增强Er³⁺的上转换发光强度。

关键词: 无铅压电陶瓷, Na_0.5Bi_0.5TiO₃, Er³⁺/Yb³⁺, 固相烧结法, 上转换发光

Abstract: A series of Er³⁺ doped and Er³⁺/Yb³⁺ co-doped 0.96Na_0.5Bi_0.5TiO₃-0.04CaTiO₃(NBT-CT∶xEr³⁺/yYb³⁺,x=0.002~0.015, y=0.010) lead-free piezoelectric ceramics were prepared by a solid-state sintering method. The phase structure and up-conversion luminescence properties of the samples were characterized and analyzed by X-ray diffraction and fluorescence spectrofluorometer, respectively. These results show that the main crystal phase of the samples is that of NBT. Under the excitation of a 980 nm near-infrared light, the Er³⁺ doped and Er³⁺/Yb³⁺ co-doped NBT-CT ceramics exhibit characteristic emission of Er³⁺ with strong dominant green up-conversion emissions. The optimal up-conversion luminescence performance with x=0.010 in NBT-CT∶xEr³⁺ ceramics are obtained. Yb³⁺ can act as sensitizer and significantly enhance the up-conversion luminescence intensity of Er³⁺.

Key words: lead-free piezoelectric ceramics, Na_0.5Bi_0.5TiO₃, Er³⁺/Yb³⁺, solid-state sintering method, up-conversion luminescence

中图分类号:

O482.3

马春林, 周越, 马晨宇, 董倩文, 吴瑾, 范雨香, 翟章印. Er³⁺单掺与Er³⁺/Yb³⁺共掺NBT-CT无铅压电陶瓷的上转换发光性能研究[J]. 人工晶体学报, 2021, 50(1): 138-143.

MA Chunlin, ZHOU Yue, MA Chenyu, DONG Qianwen, WU Jin, FAN Yuxiang, ZHAI Zhangyin. Up-Conversion Luminescence Property of Er³⁺ Doped and Er³⁺/Yb³⁺ Co-Doped NBT-CT Lead-Free Piezoelectric Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(1): 138-143.

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Er³⁺单掺与Er³⁺/Yb³⁺共掺NBT-CT无铅压电陶瓷的上转换发光性能研究

Up-Conversion Luminescence Property of Er³⁺ Doped and Er³⁺/Yb³⁺ Co-Doped NBT-CT Lead-Free Piezoelectric Ceramics

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