金刚石UV-Vis-MIR光谱常见特征综述

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (1): 158-166.

金刚石UV-Vis-MIR光谱常见特征综述

李建军^1,2, 范澄兴³, 程佑法^1,2, 刘雪松², 王岳², 山广祺², 李婷², 李桂华¹, 丁秀云², 赵潇雪², 黄准², 燕菲², 杜冉²

1.山东省计量科学研究院,山东省计量检测重点实验室,济南 250014;
2.国家黄金钻石制品质量监督检验中心,济南 250014;
3.国家首饰质量监督检验中心深圳实验室,深圳 518020

收稿日期:2020-08-24 出版日期:2021-01-15 发布日期:2021-03-01
通讯作者: 程佑法,研究员。E-mail:sdcyf2002@yahoo.com.cn
作者简介:李建军(1976—),男,山东省人,工程技术应用研究员。E-mail:geoli@vip.sina.com
基金资助:
国家质量监督检验检疫总局科技发展计划(2012QK258)

Review for Frequent Characteristics of Diamond UV-Vis-MIR Spectra

LI Jianjun^1,2, FAN Chengxing³, CHENG Youfa^1,2, LIU Xuesong², WANG Yue², SHAN Guangqi², LI Ting², LI Guihua¹, DING Xiuyun², ZHAO Xiaoxue², HUANG Zhun², YAN Fei², DU Ran²

1. Shandong Provincial Key Laboratory of Metrology and Measurement, Shandong Institute of Metrology, Jinan 250014, China;
2. National Gold & Diamond Testing Center(NGDTC) of PRC, Jinan 250014, China;
3. Shenzhen Laboratory of National Jewellery Quality Supervision and Inspection Center (NJQSIC), Shenzhen 518020, China

Received:2020-08-24 Online:2021-01-15 Published:2021-03-01

摘要/Abstract

摘要： 金刚石分类体系经过上百年发展已趋于成熟。以光谱为基础的分类依据是紫外可见近红外光谱(UV-Vis-NIR)和中红外光谱(MIR),主要涉及氮、硼杂质元素,所识别的有关晶格缺陷模型已得到较为合理的解释,但大量的晶格缺陷,包括跟氮有关的晶格缺陷研究尚不透彻,这将限制金刚石应用领域的开拓进程。本文汇集了金刚石紫外-可见光-红外光光谱中呈现的部分吸收特征,特别是对金刚石分类系统进行了完整地说明。除此以外,一些在光谱中较易识别的特征,也已经有了较为合理的理论解释和结构模型,总结汇总这些谱学特征以及其对应的结构模型,可以为金刚石材料的进一步研究和应用提供参考。

关键词: 金刚石, 硼, 氮, 缺陷模型, 吸收光谱

Abstract: The “type” of diamond had been developed and trended to perfect in last century. The spectral classification depends on ultraviolet visible near infrared spectrum (UV-Vis-NIR) and mid-infrared spectrum (MIR), mainly relates to nitrogen and boron impurity element. The structure models of nitrogen and boron in each type of diamond have tended to be more plausibility, but an enormous number of lattice defects even related to nitrogen are huge challenge for future work to reach a better understanding. This is an impenetrable wall on the way to explore new application areas for diamond. This article compiles some absorption characteristics in the spectra ranged from ultraviolet, visible light to infrared region. Especially the diamond classification system has been summarized completely. Furthermore, some absorbing features detected in the ultraviolet-visible and infrared spectral lines (UV-Vis-MIR) have been come up with a plausible explanation and/or established somewhat more reasonable structure models. It is very referential collecting these spectral characteristics and their corresponding theoretical models for further research and apply diamond materials.

Key words: diamond, boron, nitrogen, defect model, absorption spectrum

中图分类号:

李建军, 范澄兴, 程佑法, 刘雪松, 王岳, 山广祺, 李婷, 李桂华, 丁秀云, 赵潇雪, 黄准, 燕菲, 杜冉. 金刚石UV-Vis-MIR光谱常见特征综述[J]. 人工晶体学报, 2021, 50(1): 158-166.

LI Jianjun, FAN Chengxing, CHENG Youfa, LIU Xuesong, WANG Yue, SHAN Guangqi, LI Ting, LI Guihua, DING Xiuyun, ZHAO Xiaoxue, HUANG Zhun, YAN Fei, DU Ran. Review for Frequent Characteristics of Diamond UV-Vis-MIR Spectra[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(1): 158-166.

参考文献

[1] 谢有赞.金刚石理论与合成技术[M].长沙:湖南科学技术出版社,1993:43.
XIE Y Z. Theory and synthetic technology of diamond[M]. Changsha: Hunan Science and Technology Press,1993: 43(in Chinese).
[2] 罗锡裕,徐燕军,刘一波.中国人造金刚石的发展及其关键技术的进步[J].粉末冶金工业,2016,26(1):1-13.
LUO X Y, XU Y J, LIU Y B. The development and key technological improvement of synthetic diamond in China[J]. Powder Metallurgy Industry, 2016, 26(1): 1-13(in Chinese).
[3] 李志宏,赵博,孙兆达.2014年超硬材料行业经济运行情况简析[J].金刚石与磨料磨具工程,2015,35(6):1-7.
LI Z H, ZHAO B, SUN Z D. Analysis on economic situation of China's super abrasives industry in 2014[J]. Diamond & Abrsives Engineering, 2015, 35(6): 1-7(in Chinese).
[4] 周连科.粉末法合成人造金刚石技术的研究与应用[J].人工晶体学报,2008,37(1):109-113.
ZHOU L K. Study and application of diamond synthesized by powder technics[J]. Journal of Synthetic Crystals, 2008, 37(1): 109-113(in Chinese).
[5] ROBERTSON R, FOX J J, MARTIN A E. Two types of diamond[J]. Philosophical Transactions of the Royal Society A, 1934, 232(1): 463-535.
[6] ROBERTSON R, FOX J J, MARTIN A E. Further work on two types of diamond[J]. Proceedings of the Royal Society A, 1936, 157(892): 579-593.
[7] RAMAN C V. The nature and origin of the luminescence of diamond[J]. Proceedings of the Indian Academy of Sciences - Section A, 1944, 19(5): 199-215.
[8] BIPM. The international system of units (SI)[EB/OL]. [2020.10.17]. https://www.bipm.org/en/measurement-units/.
[9] NAYAR P G N. Luminescence, absorption and scattering of light in diamonds: part I. fluorescence[J]. Proceedings of the Indian Academy of Sciences-Section A, 1941, 13(6): 483-497.
[10] NAYAR P G N. The luminescence, absorption and scattering of light in diamonds: part III. Absorption[J]. Proceedings of the Indian Academy of Sciences-Section A, 1941, 14(1): 1-17.
[11] ANDERSON B W. Absorption and luminescence in diamond I[J]. The Gemmologist, 1943, 12(138): 21-22.
[12] ANDERSON B W. Absorption and luminescence in diamond II[J]. The Gemmologist, 1943, 12(139): 25-27.
[13] ANDERSON B W. Absorption and luminescence in diamond III[J]. The Gemmologist, 1943, 12(141): 33-35.
[14] MITCHELL E W J. Optical properties of diamond. Diamond research[M]. London: NAG Press, Robert Hale Ltd, 1964: 13-16.
[15] SUTHERLAND G B B M, WILLIS H A. Some new peculiarities in the infra-red spectrum of diamond[J]. Transactions of the Faraday Society, 1945, 41: 289.
[16] BLACKWELL D E, SUTHERLAND G B B M. The vibrational spectrum of diamond[J]. Journal De Chimie Physique, 1949, 46: 9-15.
[17] DYER H B, RAAL F A, DU PREEZ L, et al. Optical absorption features associated with paramagnetic nitrogen in diamond[J]. Philosophical Magazine, 1965, 11(112): 763-774.
[18] CUSTERS J F H. Unusual phosphorescence of a diamond[J]. Physica, 1952, 18(8/9): 489-496.
[19] WENTORF R H Jr, BOVENKERK H P. Preparation of semiconducting diamonds[J]. The Journal of Chemical Physics, 1962, 36(8): 1987-1990.
[20] CHRENKO R M. Boron, the dominant acceptor in semiconducting diamond[J]. Physical Review B, 1973, 7(10): 4560.
[21] COLLINS A T. Spectroscopy of defects and transition metals in diamond[J]. Diamond and Related Materials, 2000, 9(3/4/5/6): 417-423.
[22] COLLINS A T. The colour of diamond and how it may be changed[J]. The Journal of Gemmology, 2001, 27(6): 341-359.
[23] WANG W Y. With extremely strong 578.9 nm emission center[J]. Gems and Gemology, 2013, 49(1): 47.
[24] ZAITSEV A M. Lattice defects in diamonds: a data handbook[M]. Berlin: Springer-Verlag, 2001: 123-201.
[25] ZAITSEV A M. Vibronic spectra of impurity-related optical centers in diamond[J]. Physical Review B, 2000, 61(19): 12909.
[26] TAPPERT R, TAPPERT M C. Diamonds in nature-a guide to rough diamonds[EB/OL]. 2011.
[27] EATON-MAGAÑA S, POST J E, HEANEY P J, et al. Fluorescence spectra of colored diamonds using A rapid, mobile spectrometer[J]. Gems & Gemology, 2007, 43(4): 332-351.
[28] CUNNINGHAM D. The diamond compendium[M]. London: NAG Press, Robert Hale Ltd, 2011: 352-366.
[29] COLLINS A T. The detection of colour-enhanced and synthetic gem diamonds by optical spectroscopy[J]. Diamond and Related Materials, 2003, 12(10/11): 1976-1983.
[30] FRITSCH E. The nature of diamonds. Cambridge university press in association with the American museum of natural history[M]. New York: Springer, 1998: 23-47.
[31] MARTINEAU P M, LAWSON S C, TAYLOR A J, et al. Identification of synthetic diamond grown using chemical vapor deposition (CVD)[J]. Gems & Gemology, 2004, 40(1): 2-25.
[32] SHIGLEY J E, BREEDING C M, SHEN A H T. An updated chart on the characteristics of HPHT-grown synthetic diamonds[J]. Gems & Gemology, 2004, 40(4): 303-313.
[33] VISHNEVSKIY A S, MALOGOLOVETS A F, NIKITYUK L S, et al. Sinteticheskiye Lamaze[J]. 1975, 3: 215.
[34] COLLINS A T. Colour centres in diamond[J]. The Journal of Gemmology, 1982, 18(1): 37-75.
[35] HOFER S C. Collecting and classifying coloured diamonds: an illustrated study of the Aurora collection[J]. Choice Reviews Online, 1998, 36(2): 36-0970.