基于磁光应用的TbO1.81和Tb2O3超细粉末的合成

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (1): 80-87.

基于磁光应用的TbO_1.81和Tb₂O₃超细粉末的合成

冯凯¹, 吕滨¹, 程红梅¹, 吴少凡^2,3, 王燕^2,3, 刘永兴⁴

1.宁波大学材料科学与化学工程学院,宁波 315211;
2.中国科学院福建物质结构研究所,光电材料化学与物理重点实验室,福州 350002;
3.福建光电信息科学与技术创新实验室,福州 350108;
4.浙江省光电探测材料及器件重点实验室,宁波 315211

收稿日期:2020-10-09 出版日期:2021-01-15 发布日期:2021-03-01

Synthesis of Ultrafine TbO_1.81 and Tb₂O₃ Powders for Magneto-Optical Application

FENG Kai¹, LÜ Bin¹, CHENG Hongmei¹, WU Shaofan^2,3, WANG Yan^2,3, LIU Yongxing⁴

1. School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China;
2. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
3. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China;
4. Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province, Ningbo 315211, China

Received:2020-10-09 Online:2021-01-15 Published:2021-03-01
Contact: LÜ Bin, doctor, associate professor. E-mail:lvbin@nbu.edu.cn
WANG Yan, doctor, professor. E-mail:wy@fjirsm.ac.cn
About author:FENG Kai(1996—), male, from Liaoning Province, postgraduates. E-mail:1109503281@qq.com
Supported by:
National Natural Science Foundation of China (51702171, 51872286, 51832007); Zhejiang Provincial Qianjiang Talent Program of China (QJD1702017); Natural Science Foundation of Ningbo (2019A610052); Key Laboratory of Optoelectronic Materials Chemistry and Physics, Chinese Academy of Sciences (2008DP173016); Science and Technology Plan Leading Project of Fujian Province (2018H0046)

摘要/Abstract

摘要： 以碳酸氢铵(AHC)为沉淀剂,采用液相沉淀法结合高温热分解获得了TbO_1.81和Tb₂O₃超细粉体。研究表明,沉淀前驱体呈现出一维纳米线形貌特征,纳米线的平均宽度随碳酸氢铵含量的增加而增长。前驱体在空气中直接加热煅烧经过脱水、脱碳和颗粒生长等过程得到了平均粒径约为140 nm的类球状TbO_1.81纳米粉体;而前驱体在流动氢气气氛下加热则获得了颗粒尺寸更小的Tb₂O₃粉体(平均粒度约为85 nm)。碳酸氢铵与Tb³⁺的摩尔比对氧化物粉体的分散有显著影响,最佳摩尔比为1∶1。TbO_1.81和Tb₂O₃的禁带宽度分别约为1.67 eV和5.20 eV。

关键词: 超细粉末, Tb₂O₃, TbO_1.81, 共沉淀法, 磁光效应, 形貌

Abstract: Ultrafine TbO_1.81 and Tb₂O₃ powders were obtained from the pyrolytic precursor prepared via a wet chemical route using ammonium hydrogen carbonate (AHC) as the precipitant. The precipitation precursor has a chemical composition of hydrated terbium carbonate and exhibits one-dimensional nanorod morphology. The average width of the nanorods rises as the increase of AHC concentration. Calcining the precursor in air directly yields a round TbO_1.81 nanopowder with an average particle size of ~140 nm through dehydration, decarbonation and particle growth processes. On the other hand, a Tb₂O₃ powder with a finer particle size of ~85 nm is reduced under flowing hydrogen atmosphere upon heating. The molar ratio of AHC to Tb³⁺ significantly affects the particle dispersion of final oxide products and the best molar ratio for the synthesis of well dispersed powder is 1∶1. The bandgap energies of TbO_1.81 and Tb₂O₃ are ~1.67 eV and 5.20 eV, respectively.

Key words: ultrafine powder, Tb₂O₃, TbO_1.81, co-precipitation method, magneto-optical effect, morphology

中图分类号:

冯凯, 吕滨, 程红梅, 吴少凡, 王燕, 刘永兴. 基于磁光应用的TbO_1.81和Tb₂O₃超细粉末的合成[J]. 人工晶体学报, 2021, 50(1): 80-87.

FENG Kai, LÜ Bin, CHENG Hongmei, WU Shaofan, WANG Yan, LIU Yongxing. Synthesis of Ultrafine TbO_1.81 and Tb₂O₃ Powders for Magneto-Optical Application[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(1): 80-87.

参考文献

[1] SNETKOV I L, VOITOVICH A V, PALASHOV O V, et al. Review of Faraday isolators for kilowatt average power lasers[J]. IEEE J Quantum Electron, 2014, 50(6): 434-443.
[2] YASUHAR R, SNETKOV I, STAROBOR A, et al. Terbium gallium garnet ceramic Faraday rotator for high-power laser application[J]. Opt Lett, 2014, 39(6): 1145-1148.
[3] CHEN Z, YANG L, WANG X Y, et al. Highly transparent terbium gallium garnet crystal fabricated by the floating zone method for visibleeinfrared optical isolators[J]. Opt Mater, 2015, 46: 12-15.
[4] YASUHAR R, FURUSE H. Thermally induced depolarization in TGG ceramics[J]. Opt Lett, 2013, 38(10): 1751-1753.
[5] ZHELEZNOV D, STAROBOR A, PALASHOV O, et al. High-power Faraday isolators based on TAG ceramics[J]. Opt Express, 2014, 2(3)2: 2578-2583.
[6] CHEN C, YI X Z, ZHANG S, et al. Vacuum sintering of Tb₃Al₅O₁₂transparent ceramics with combined TEOS+MgO sintering aids[J]. Ceram Int, 2015, 41(10): 12823-12827.
[7] YOSHIDA H, TSUBAKIMOTO K, FUJIMOTO Y, et al. Optical properties and Faraday effect of ceramic terbium gallium garnet for a room temperature Faraday rotator[J]. Opt Express, 2011, 19(16): 15181-15197.
[8] ZHELEZNOV D, STAROBOR A, PALASHOV O, et al. Improving characteristics of Faraday isolators based on TAG ceramics by cerium doping[J]. Opt Lett, 2014, 39(7): 2183-2186.
[9] STAROBOR A, PALASHOV O, ZHOU S M. Thermo-optical properties of terbium aluminum garnet ceramics doped with silicon and titanium[J]. Opt Lett, 2016, 41(7): 1510-1513.
[10] SNETKOV I L, YASUHARA R, STAROBOR A V, et al. Thermooptical and magneto-optical characteristics of terbium scandium aluminum garnet crystals[J]. IEEE Quantum Electron, 2015, 51: 7000307.
[11] SNETKOV I L, PERMIN D A, BALABANOV S S, et al. Wavelength dependence of verdet constant of Tb³⁺∶Y₂O₃ ceramics[J]. Appl. Phys. Lett., 2016, 108(16): 161905.
[12] IKESUE A, AUNG Y L, MAKIKAWA S, et al. Polycrystalline (Tb_xY_1-x)₂O₃ Faraday rotator[J]. Opt Lett, 2017, 42(21): 4399-4401.
[13] IKESUE A, AUNG Y L, MAKIKAWA S, et al. Total performance of magneto-optical ceramics with a bixbyite structure[J]. Materials, 2019, 12(3): 421.
[14] LU B, CHENG H M, XU X X, et al. Preparation and characterization of transparent magneto-optical Ho₂O₃ ceramics[J]. J Am Ceram Soc, 2019, 102(1): 118-122.
[15] CHENG H M, LU B, LIU Y X, et al. Transparent magneto-optical Ho₂O₃ ceramics: role of self-reactive resultant oxyfluoride additive and investigation of vacuum sintering kinetics[J]. Ceram Int, 2019, 45(12): 14761-14767.
[16] SNETKOV I L, YAKOVLEV A I, PERMIN D A, et al. Magneto-optical Faraday effect in dysprosium oxide (Dy₂O₃) based ceramics obtained by vacuum sintering[J]. Opt Lett, 2018, 43(16): 4041-4044.
[17] SLEZAKl O, YASUHARA R, VOJNA D, et al. Temperature-wavelength dependence of verdet constant of Dy₂O₃ ceramics[J]. Opt Mater Express, 2019, 9(7): 2971-2981.
[18] WAKEFIELD G, KERON H A, DOBSON P J, et al. Structural and optical properties of terbium oxide nanoparticles[J]. J Phys Chem Solids, 1999, 60: 503-508.
[19] YANG M Q, ZHOU D, XU J Y, et al. Fabrication and magneto-optical property of yttria stabilized Tb₂O₃ transparent ceramics[J]. J Eur Ceram Soc,2019, 39: 5005-5009.
[20] STANISLAV S, BALABANOV D A, PERMIN E Y, et al. Synthesis and structural characterization of ultrafine terbium oxide powders[J]. Ceram Int, 2017, 43(18): 16569-16574.
[21] LU B, SUN Z G, WANG X Y, et al. Photoluminescent and scintillant properties of highly transparent [(Y_1-xGd_x)_0.99Dy_0.01]₂O₃ (x = 0 and 0.4) ceramics[J]. J Am Ceram Soc, 2019, 102(8): 4773-4780.
[22] 王晴晴,石云,冯亚刚,等.太阳光泵浦Cr,Nd∶YAG透明陶瓷的光谱特性和激光参数[J].发光学报, 2019, 40(11): 1365-1372.
WANG Q Q, SHI Y, FENG Y G, et al. Spectral characteristics and laser parameters of solar pumped Cr, Nd∶YAG transparent ceramics[J]. Chinese Journal of Luminescence, 2019, 40(11): 1365-1372(in Chinese).
[23] 代雨航,李剑,张莹,等.Er,Yb∶(LaLu)₂O₃透明陶瓷制备及上转换发光性能[J].发光学报, 2018, 39(4): 488-493.
DAI Y H, LI J, ZHANG Y, et al. Preparation of Er, Yb∶(LaLu)₂O₃ ceramic and its upconversion luminescent properties[J]. Chinese Journal of Luminescence, 2018, 39(4): 488-493(in Chinese).
[24] SAITO N, MATSUDA S, IKEGAMI T. Fabrication of transparent yttria ceramics at low temperature using carbonate-derived powder[J]. J Am Ceram Soc, 1998, 81(8): 2023-2028.
[25] LU B, LI J G, SAKKA Y. Controlled Processing of (Gd,Ln)₂O₃∶Eu (Ln=Y, Lu) red phosphor particles and compositional effects on photoluminescence[J]. Sci Technol Adv Mater, 2013, 14(6):064202.
[26] LU B, CHENG H M, SUN Z G, et al. Controlled preparation of red-light-emitting (Y_0.95Eu_0.05)₂O₃ phosphors and vacuum sintering of transparent (Y_0.95Eu_0.05)₂O₃ ceramics[J]. J Ceram Sci Technol, 2018, 9(1): 53-60.
[27] SUN Z G, CHEN Z Y, WANG M Y, et al. Production and optical properties of Ce³⁺-activated and Lu³⁺-stabilized transparent gadolinium aluminate garnet ceramics[J]. J Am Ceram Soc, 2020, 103(2): 809-818.
[28] ZHANG J Y, CHEN H T, WANG J P, et al. Phase transformation process of Tb₂O₃ at elevated temperature[J]. Scripta Mater, 2019, 171: 108-111.
[29] XU X X, LU B, HU J X, et al. Controlled synthesis and photoluminescence behaviors of Lu₂O₃∶Eu and Lu₂O₂S∶Eu phosphor particles[J]. J Lumin, 2019, 215: 116702.
[30] LU B, LI J G, SUZUKI T S, et al. Controlled synthesis of layered rare-earth hydroxide nanosheets leading to highly transparent (Y_0.95Eu_0.05)₂O₃ ceramics[J]. J Am Ceram Soc, 2015, 98(5): 1413-1422.
[31] WANG L R, LU B, LIU X, et al. Fabrication and upconversion luminescence of novel transparent Er₂O₃ ceramics[J]. J Eur Ceram Soc, 2020, 40(4): 1767-1772.
[32] HOROZ S, SIMSEK S, PALAZ S, et al. Electronic and optical properties of rare earth oxides:Ab initio calculation[J]. World J Condens Matter Phys, 2015, 5: 78-85.

基于磁光应用的TbO_1.81和Tb₂O₃超细粉末的合成

Synthesis of Ultrafine TbO_1.81 and Tb₂O₃ Powders for Magneto-Optical Application

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	罗诗健, 熊子龙, 杨凤华, 陈前林, 李翠芹. 快离子导体Li_1.5Y_0.5Zr_1.5(PO₄)₃包覆层对富镍三元正极材料电化学性能的影响[J]. 人工晶体学报, 2022, 51(7): 1257-1269.
[2]	殷梓萌, 郑凯文, 邹幸洁, 路鑫宇, 陈凯, 叶煜聪, 胡文晓, 陶涛. 人造金刚石单晶薄膜的制备及表面形貌优化[J]. 人工晶体学报, 2022, 51(5): 901-909.
[3]	王贝贝, 刘文鹏, 任浩, 张传成, 刘海莲, 邹勇, 丁守军. 钆钪铝石榴石单晶缺陷的微观形貌与成因研究[J]. 人工晶体学报, 2022, 51(11): 1851-1857.
[4]	高腾, 邢锟, 吴功辉, 陈新, 胡晓琳, 庄乃锋. Bi_26-x-yM_xN_yO₄₀(M, N=Fe, Co, Gd)软铋矿薄膜的制备和强磁光效应[J]. 人工晶体学报, 2021, 50(9): 1655-1661.
[5]	刘欣, 唐燕超, 刘芳, 李家科. 共沉淀法合成ZnMoO₄粉体及其抗菌性能[J]. 人工晶体学报, 2021, 50(9): 1729-1734.
[6]	范兴其, 姚梦琴, 刘飞, 王晓丹, 曹建新. 制备方法对Al₂O₃-CeO₂物化性质及CO₂加氢制甲醇催化性能的影响[J]. 人工晶体学报, 2021, 50(9): 1745-1755.
[7]	吴钦, 杨林, 易芸, 耿平兰, 曹建新. Ca(H₂PO₄)₂-H₃PO₄-K₂SO₄体系中石膏晶型及形貌调控[J]. 人工晶体学报, 2021, 50(6): 1104-1111.
[8]	高洁, 姚威振, 杨少延, 魏洁, 李成明, 魏鸿源. 磁控溅射ZrN薄膜的生长机理及光学性能[J]. 人工晶体学报, 2021, 50(5): 831-837.
[9]	马海鑫, 丁广玉, 邢艳辉, 韩军, 张尧, 崔博垚, 林文魁, 尹浩田, 黄兴杰. 不同退火条件对PEALD制备的Ga₂O₃薄膜特性的影响[J]. 人工晶体学报, 2021, 50(5): 838-844.
[10]	胡斌, 郭亮, 杨淑敏, 曹丽萍. Pb²⁺掺杂CaMoO₄∶Dy³⁺,Eu³⁺荧光粉发光性能及能量传递机理的研究[J]. 人工晶体学报, 2021, 50(5): 871-876.
[11]	王东意, 郑强, 于亚杰, 徐少伟, 王禹博, 邓晓阳, 曹笑宁, 岳岩, 李雪, 刘云义. 白云石精制液中不同离子对碳酸钙晶须的影响[J]. 人工晶体学报, 2021, 50(5): 908-914.
[12]	张利繁, 贾伟, 董海亮, 李天保, 贾志刚, 许并社. InGaN/GaN微米阵列结构的生长及发光性能研究[J]. 人工晶体学报, 2021, 50(4): 776-782.
[13]	王龙, 汪刘应, 刘顾, 唐修检, 阳能军, 油银峰, 刘国浩. 基于单磨粒微米划刻的单晶硅精密切削机理研究[J]. 人工晶体学报, 2021, 50(3): 558-564.
[14]	高灿灿, 姬凯迪, 马奎, 杨发顺. 磁控溅射衬底加热温度和后退火温度对制备β-Ga₂O₃薄膜材料的影响[J]. 人工晶体学报, 2021, 50(2): 296-301.
[15]	刘文鹏, 任浩, 李泓沅, 丁守军, 张庆礼. 共沉淀法制备LuGG∶Ce纳米荧光粉及其发光性能研究[J]. 人工晶体学报, 2021, 50(2): 325-330.