欢迎访问《人工晶体学报》官方网站,今天是 分享到:

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (12): 2205-2211.

• 研究论文 •    下一篇

梯度掺杂的YVO4-Nd∶YVO4复合晶体

邱科彬1, 庄乃锋1, 陈新1, 陈玮冬2, 张戈2, 赵斌1   

  1. 1.福州大学化学学院,福州 350108;
    2.中国科学院福建物质结构研究所,福州 350002
  • 收稿日期:2021-08-16 出版日期:2021-12-15 发布日期:2022-01-06
  • 通讯作者: 赵 斌,博士,副教授。E-mail:tigerzhao@fzu.edu.cn
  • 作者简介:邱科彬(1997—),男,福建省人,硕士研究生。E-mail:1024984032@qq.com
  • 基金资助:
    国家自然科学基金(51972062)

Gradient Doping YVO4-Nd∶YVO4 Composite Crystal

QIU Kebin1, ZHUAN Naifeng1, CHEN Xin1, CHEN Weidong2, ZHANG Ge2, ZHAO Bin1   

  1. 1. College of Chemistry, Fuzhou University, Fuzhou 350108, China;
    2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, China
  • Received:2021-08-16 Online:2021-12-15 Published:2022-01-06

摘要: 利用改进的提拉法生长了一种新型YVO4-Nd∶YVO4 复合晶体,在晶体中部实现了Nd3+的0.10%~0.25%(原子数分数)浓度梯度掺杂。晶体中, Nd3+掺杂区的弱吸收系数较未掺杂区大,表现出界面吸收现象。观测了复合晶体对泵浦光的吸收和温度分布,发现晶体沿轴向的泵浦吸收相对均匀,温度梯度相对较小。未镀膜的复合晶体样品在1 064 nm波段显示了良好的连续激光性能,光-光转换效率为37.0%,斜效率为40.9%。

关键词: 钒酸盐晶体, 复合晶体, 激光晶体, 浓度梯度, 弱吸收, 温度梯度, 激光性能

Abstract: A new YVO4-Nd∶YVO4 composite crystal was grown by a modified Cz method, a 0.10%~0.25%(atomic ratio) concentration gradient doping of Nd3+ in the middle part of the crystal was achieved. In the crystal, the weak absorption coefficient of the Nd3+ doped region is larger than that of the un-doped region, indicating the interface absorption phenomenon. By observing the absorption of the pump light by the composite crystal and temperature distribution in the crystal, it is found that the pumping absorption of the crystal along the axial direction is relatively uniform, and the temperature gradient in the crystal is relatively small. The uncoated composite crystal samples achieve well performance of CW laser at 1 064 nm, with a light-to-light conversion efficiency of 37.0% and a slope efficiency of 40.9%.

Key words: vanadate crystal, composite crystal, laser crystal, concentration gradient, weak absorption, temperature gradient, laser performance

中图分类号: