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人工晶体学报 ›› 2021, Vol. 50 ›› Issue (3): 407-409.

• 研究快报 •    下一篇

8英寸氟化钙单晶生长

徐悟生1, 彭明林1, 杨春晖2   

  1. 1.秦皇岛本征晶体科技有限公司,秦皇岛 066000;
    2.哈尔滨工业大学化工与化学学院,哈尔滨 150006
  • 收稿日期:2021-02-18 出版日期:2021-03-15 发布日期:2021-04-15
  • 作者简介:徐悟生(1972—),男,黑龙江省人,博士。E-mail:wusheng.xu@icc-crystal.com
  • 基金资助:
    河北省省级科技计划(19211104D)

Growth of 8-Inch CaF2 Single Crystal

XU Wusheng1, PENG Minglin1, YANG Chunhui2   

  1. 1. Intrinsic Crystal Technology Co., Ltd., Qinhuangdao 066000, China;
    2. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150006, China
  • Received:2021-02-18 Online:2021-03-15 Published:2021-04-15

摘要: 氟化钙(CaF2)晶体是一种性能优良的光学晶体材料。本研究用坩埚下降法生长了8英寸(20.32 cm)氟化钙单晶,晶体外观完整,无开裂及散射等宏观缺陷。定向切割后得到ϕ40 mm×6 mm的透明圆柱形晶体毛坯,对毛坯样品进行二次退火处理后进行研磨抛光得到最终样品。对该系列样品进行紫外可见透过率、光学均匀性、应力双折射等测试。结果显示在200 nm波长处晶体透过率达到90%,平均应力双折射小于0.5 nm/cm,光学均匀性达到2.63×10-6

关键词: 氟化钙晶体, 坩埚下降法, 晶体退火, 透过率, 光学均匀性, 应力双折射

Abstract: Calcium fluoride (CaF2) crystal is a kind of excellent optical material. In this investigation, an 8-inch(20.32 cm) CaF2 single crystal was grown by the Bridgman method. The crystal has complete appearance and no macroscopic defects such as cracking and scattering. After orientational cutting, a transparent cylindrical crystal blank with diameter of 40 mm×6 mm was obtained, the blank sample was annealed twice and then polished to obtain the final sample. The ultraviolet-visible-near infrared transmittance, optical homogeneity, and average stress birefringence were measured. The results show that the transmittance at 200 nm reaches 90%. The average stress birefringence is less than 0.5 nm/cm. The optical homogeneity reaches 2.63×10-6.

Key words: CaF2 crystal, Bridgman method, crystal annealing, transmittance, optical homogeneity, stress birefringence

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