基于锑烯纳米片的被动调Q激光器

摘要/Abstract

摘要： 为了探索二维材料作为被动调Q激光器的可饱和吸收体的更多可能性,利用预研磨液相剥离法(LPE)制备出锑烯纳米片,并借助拉曼光谱、X射线衍射(XRD)、扫描电子显微镜(SEM)、原子力显微镜(AFM)、UV-Vis-NIR分光光度计对样品的物相组成、微观结构及吸收性能进行表征。将锑烯纳米片作为可饱和吸收体首次在1.3 μm发射波长的Nd∶GYAP全固态激光器实现被动调Q,其最短脉冲宽度为589 ns,重复频率为424 kHz,峰值功率为1.14 W,平均输出功率为284 mW,最大单脉冲能量为669.43 nJ。实验证明了锑烯纳米片具有在近红外区域作为全固态调Q激光器的可饱和吸收体的潜力。

关键词: 锑烯纳米片, 可饱和吸收体, 预研磨液相剥离法, 被动调Q, 1.3 μm波段, 激光性能, 二维材料, 激光器

Abstract: In order to explore the possibility of using two-dimensional materials as saturable absorbers (SA) of passively Q-switched lasers, antimonene nanosheets were successfully prepared by pre-grinding liquid-phase-exfoliation (LPE) method. The phase composition, microstructure and absorption properties of the samples were characterized by Raman spectrometer, X-ray diffraction (XRD), scanning electron microscope (SEM), atomic force microscope (AFM) and UV-Vis-NIR spectrophotometer. Based on the prepared synthesized antimonene nanosheets SA, an all-solid-state passively Q-switched Nd∶GYAP laser at 1.3 μm was realized for the first time. The shortest pulse width is 589 ns, the repetition rate is 424 kHz, the peak power is 1.14 W, the average output power is 284 mW, and the maximum single pulse energy is 669.43 nJ. The results show that the antimonene nanosheets have the potential to become SA of all solid state Q-switched laser in the near infrared region.

Key words: antimonene nanosheet, saturable absorber, pre-grinding liquid-phase-exfoliation method, passively Q-switched, 1.3 μm, laser performance, 2D material, laser

中图分类号:

洪弘, 周貌, 陈鸿玲, 张沛雄, 李真, 尹浩, 陈振强. 基于锑烯纳米片的被动调Q激光器[J]. 人工晶体学报, 2022, 51(2): 216-221.

HONG Hong, ZHOU Mao, CHEN Hongling, ZHANG Peixiong, LI Zhen, YIN Hao, CHEN Zhenqiang. Passively Q-Switched Laser Based on Antimonene Nanosheets[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2022, 51(2): 216-221.

参考文献

[1] NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696): 666-669.
[2] LI L, PANG L H, ZHAO Q Y, et al. Niobium disulfide as a new saturable absorber for an ultrafast fiber laser[J]. Nanoscale, 2020, 12(7): 4537-4543.
[3] DONG N N, LI Y X, FENG Y Y, et al. Optical limiting and theoretical modelling of layered transition metal dichalcogenide nanosheets[J]. Scientific Reports, 2015, 5: 14646.
[4] YAN P, CHEN H, YIN J, et al. Large-area tungsten disulfide for ultrafast photonics[J]. Nanoscale, 2017, 9(5): 1871-1877.
[5] 张家旗,楚学影,李金华,等.溶剂依赖的MoS₂量子点光学性质[J].发光学报,2019,40(11):1359-1364.
ZHANG J Q, CHU X Y, LI J H, et al. Solvent-dependent optical properties of MoS₂ quantum dots[J]. Chinese Journal of Luminescence, 2019, 40(11): 1359-1364(in Chinese).
[6] QI X, ZHANG Y, OU Q, et al. Photonics and optoelectronics of 2D metal-halide perovskites[J]. Small (Weinheim an Der Bergstrasse, Germany), 2018: e1800682.
[7] ACHARYYA P, KUNDU K, BISWAS K. 2D layered all-inorganic halide perovskites: recent trends in their structure, synthesis and properties[J]. Nanoscale, 2020, 12(41): 21094-21117.
[8] LI X, HOFFMAN J M, KANATZIDIS M G. The 2D halide perovskite rulebook: how the spacer influences everything from the structure to optoelectronic device efficiency[J]. Chemical Reviews, 2021, 121(4): 2230-2291.
[9] LEE E, YOON Y S, KIM D J. Two-dimensional transition metal dichalcogenides and metal oxide hybrids for gas sensing[J]. ACS Sensors, 2018, 3(10): 2045-2060.
[10] JIA Y M, YI X Q, LI Z G, et al. Recent advance in biosensing applications based on two-dimensional transition metal oxide nanomaterials[J]. Talanta, 2020, 219: 121308.
[11] CHO C H, CHOE Y S, OH J Y, et al. Self-assembled 2D networks of metal oxide nanomaterials enabling sub-ppm level breathalyzers[J]. ACS Sensors, 2021, 6(9): 3195-3203.
[12] 庄文昌,张洁,李钦堂,等.氧化镓纳米材料的制备及其在光电探测方面的应用研究进展[J].人工晶体学报,2020,49(12):2376-2382.
ZHUANG W C, ZHANG J, LI Q T, et al. Research progress on preparation of gallium oxide nanomaterials and its application in photoelectric detection[J]. Journal of Synthetic Crystals, 2020, 49(12): 2376-2382(in Chinese).
[13] 陈星辉,唐颖慧,王加强,等.衬底温度对氧化锌薄膜微结构及光学性能的影响[J].人工晶体学报,2021,50(9):1681-1687+1722.
CHEN X H, TANG Y H, WANG J Q, et al. Effect of substrate temperature on microstructure and optical properties of ZnO thin films[J]. Journal of Synthetic Crystals, 2021, 50(9): 1681-1687+1722(in Chinese).
[14] SMITH J B, HAGAMAN D, JI H F. Growth of 2D black phosphorus film from chemical vapor deposition[J]. Nanotechnology, 2016, 27(21): 215602.
[15] LI L K, YU Y J, YE G J, et al. Black phosphorus field-effect transistors[J]. Nature Nanotechnology, 2014, 9(5): 372-377.
[16] SCIACCA D, PERIC N, BERTHE M, et al. Account of the diversity of tunneling spectra at the germanene/Al(1 1 1) interface[J]. Journal of Physics: Condensed Matter, 2020, 32(5): 055002.
[17] KOVALSKA E, ANTONATOS N, LUXA J, et al. “Top-down” arsenene production by low-potential electrochemical exfoliation[J]. Inorganic Chemistry, 2020, 59(16): 11259-11265.
[18] MOHAMED ISMAIL M, VIGNESHWARAN J, ARUNBALAJI S, et al. Antimonene nanosheets with enhanced electrochemical performance for energy storage applications[J]. Dalton Transactions, 2020, 49(39): 13717-13725.
[19] FENG T C, LI X H, CHAI T, et al. Bismuthene nanosheets for 1 μm multipulse generation[J]. Langmuir, 2020, 36(1): 3-8.
[20] SHEN C, LIU Y, WU J, et al. Tellurene photodetector with high gain and wide bandwidth[J]. ACS Nano, 2020, 14(1): 303-310.
[21] ZHANG L, FAHAD S, WU H R, et al. Tunable nonlinear optical responses and carrier dynamics of two-dimensional antimonene nanosheets[J]. Nanoscale Horizons, 2020, 5(10): 1420-1429.
[22] ARES P, PALACIOS J J, ABELLÁN G, et al. Recent progress on antimonene: a new bidimensional material[J]. Advanced Materials, 2018, 30(2): 1703771.
[23] WANG X, HE J J, ZHOU B Q, et al. Bandgap-tunable preparation of smooth and large two-dimensional antimonene[J]. Angewandte Chemie International Edition, 2018, 57(28): 8668-8673.
[24] PUMERA M, SOFER Z. 2D monoelemental arsenene, antimonene, and bismuthene: beyond black phosphorus[J]. Advanced Materials, 2017, 29(21): 1605299.
[25] SADICK N S, CARDONA A. Laser treatment for facial acne scars: a review[J]. Journal of Cosmetic and Laser Therapy, 2018, 20(7/8): 424-435.
[26] FILICE F P, DING Z F. Analysing single live cells by scanning electrochemical microscopy[J]. The Analyst, 2019, 144(3): 738-752.
[27] MASLOV N A. Ultraviolet pulsed laser-induced fluorescence nonlinearity in optically thick organic samples[J]. Journal of Fluorescence, 2018, 28(2): 689-693.
[28] CAI Y K, LUO X C, LIU Z Q, et al. Product and process fingerprint for nanosecond pulsed laser ablated superhydrophobic surface[J]. Micromachines, 2019, 10(3): 177.
[29] OGILVY H, PIPER J A. Compact, all solid-state, high-repetition-rate 336 nm source based on a frequency quadrupled, Q-switched, diode-pumped Nd∶YVO₄ laser[J]. Optics Express, 2005, 13(23): 9465.
[30] 付鑫鹏,付喜宏,姚聪,等.基于超薄层MoS₂可饱和吸收体的被动调Q固体Nd∶YAG激光器[J].发光学报,2021,42(5):668-673.
FU X P, FU X H, YAO C, et al. Passive Q-switched solid-state Nd∶YAG laser based on ultrathin MoS₂ saturable absorber[J]. Chinese Journal of Luminescence, 2021, 42(5): 668-673(in Chinese).
[31] SONG Y F, LIANG Z M, JIANG X T, et al. Few-layer antimonene decorated microfiber: ultra-short pulse generation and all-optical thresholding with enhanced long term stability[J]. 2D Materials, 2017, 4(4): 045010.
[32] WANG M, ZHANG F, WANG Z, et al. Passively Q-switched Nd³⁺ solid-state lasers with antimonene as saturable absorber[J]. Optics Express, 2018, 26(4): 4085-4095.
[33] PANARIN A Y, KHODASEVICH I A, GLADKOVA O L, et al. Determination of antimony by surface-enhanced Raman spectroscopy[J]. Applied Spectroscopy, 2014, 68(3): 297-306.
[34] JAFARI A, KLOBES B, SERGUEEV I, et al. Phonon spectroscopy in antimony and tellurium oxides[J]. The Journal of Physical Chemistry A, 2020, 124(39): 7869-7880.