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人工晶体学报 ›› 2022, Vol. 51 ›› Issue (7): 1227-1232.

• 研究论文 • 上一篇    下一篇

吡啶鎓盐配体构筑的多钼酸基配合物的合成、结构及光催化性能

王静怡, 张众, 王梓兰, 于鑫颖, 由君颐, 朱君怡, 杨琳   

  1. 渤海大学化学与材料工程学院,辽宁省全谱太阳能电池转光材料专业技术创新中心,锦州 121013
  • 收稿日期:2022-04-11 出版日期:2022-07-15 发布日期:2022-08-11
  • 通讯作者: 张 众,博士,讲师。E-mail:zhangz@bhu.edu.cn
  • 作者简介:王静怡(2002—),女,辽宁省人。E-mail:wjy20020829@126.com
  • 基金资助:
    国家自然科学基金青年科学基金(21901018);渤海大学博士启动基金(0520bs027)

Synthesis, Structure and Photocatalytic Properties of Polymolybdate-Based Complex Constructed by Pyridinium Ligand

WANG Jingyi, ZHANG Zhong, WANG Zilan, YU Xinying, YOU Junyi, ZHU Junyi, YANG Lin   

  1. Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, College of Chemistry and Materials Engineering, Bohai University, Jinzhou 121013, China
  • Received:2022-04-11 Online:2022-07-15 Published:2022-08-11

摘要: 本文在水热条件下合成了一例同多钼酸阴离子[δ-Mo8O26]4-基配合物[Co(bipbc)(δ-Mo8O26)0.5(H2O)3] (bipbc=4,4-双[(4-羧基吡啶)甲基]联苯),其为一维链状结构,包含环型双核钴配合物[Co2(bipbc)2]4+和[δ-Mo8O26]4-簇。该配合物结晶于单斜晶系,P21/n空间群,a=1.147 9(8) nm,b=1.440 9(11) nm,c=2.082 9(16) nm,β=93.469(2)°,V=3.438 8(4) nm3,Z=4,Mr=1 129.18,F(000)=2 204,μ=1.979 mm-1,Dc=2.181 mg·m-3,S=1.019,R1=0.056 2,wR2=0.137 7。光催化性质研究表明,在可见光、近红外光和全光谱的光照条件下,标题配合物对龙胆紫(GV)和亚甲基蓝(MB)的降解,表现出一定的光催化活性。

关键词: 多金属氧酸盐, 水热合成, 吡啶鎓盐配体, 钴配合物, 有机染料, 光催化降解

Abstract: In this paper, a new isopolymolybdate anion [δ-Mo8O26]4--based complex [Co(bipbc)(δ-Mo8O26)0.5(H2O)3] (bipbc=4,4′-bis[(4-carboxypyridino)methyl]biphenyl) was synthesized under hydrothermal conditions. The title complex shows a 1D chain, which consists of the cyclic dinuclear cobalt complexes [Co2(bipbc)2]4+ and [δ-Mo8O26]4-clusters, and crystallizes in the monoclinic system, space group P21/n with a=1.147 9 (8) nm, b=1.440 9 (11) nm, c=2.082 9 (16) nm, β=93.469(2)°, V=3.438 8(4) nm3, Z=4, Mr=1 129.18, F(000)=2 204, μ=1.979 mm-1, Dc=2.181 mg·m-3, S=1.019, R1=0.056 2, wR2=0.137 7. The investigations on photocatalytic properties show that the title complex has photocatalytic activities toward the degradation of gentian violet (GV) and methylene blue (MB) under visible, even near-infrared and full spectrum light irradiation.

Key words: polyoxometalate, hydrothermal synthesis, pyridinium ligand, cobalt complex, organic dye, photocatalytic degradation

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