非线性光学晶体K3B6O10Br的生长与光电性能研究

人工晶体学报 ›› 2023, Vol. 52 ›› Issue (7): 1296-1301.

• 激光与非线性光学晶体高通量制备与表征 • 上一篇下一篇

非线性光学晶体K₃B₆O₁₀Br的生长与光电性能研究

刘青雄^1,2, 王天予^1,2, 刘孚安³, 吴倩¹, 尹延如³, 赫崇君⁴, 高泽亮³, 夏明军¹

1.中国科学院理化技术研究所人工晶体研究发展中心,北京 100190;
2.中国科学院大学未来技术学院,北京 100049;
3.山东大学晶体材料国家重点实验室&晶体材料研究院,济南 250100;
4.南京航天航空大学航天学院,南京 211106

收稿日期:2023-05-15 出版日期:2023-07-15 发布日期:2023-08-16
通信作者: 吴倩,博士,助理研究员。E-mail:wuqian910230@mail.ipc.ac.cn
夏明军,博士,研究员。E-mail:xiamingjun@mail.ipc.ac.cn
作者简介:刘青雄(1998—),男,江西省人,硕士研究生。E-mail:liuqingxiong20@mails.ucas.ac.cn
基金资助:
国家重点研发计划(2021YFB3601502,2021YFB3601403);中科院稳定支持基础研究领域青年团队计划(YSBR-024)

Growth and Photoelectric Properties of Nonlinear Optical Crystal K₃B₆O₁₀Br

LIU Qingxiong^1,2, WANG Tianyu^1,2, LIU Fuan³, WU Qian¹, YIN Yanru³, HE Chongjun⁴, GAO Zeliang³, XIA Mingjun¹

1. Beijing Center for Crystal Research and Development, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3. State Key Laboratory of Crystal Materials & Institute of Crystal Materials, Shandong University, Jinan 250100, China;
4. College of Astronautics, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China

Received:2023-05-15 Online:2023-07-15 Published:2023-08-16

摘要/Abstract

摘要： 采用顶部籽晶溶液生长法成功生长出尺寸为42 mm×20 mm×18 mm的高光学质量的紫外非线性光学晶体K₃B₆O₁₀Br(KBB)。根据其结构对称性要求,将KBB晶体定向加工成不同的器件切型,系统表征其光电性能。对KBB晶体电弹常数进行了系统的表征,受微观结构影响,压电常数各向异性较大,最大的压电常数d₃₃=6.69 pC/N。KBB晶体具有良好的激光频率变换、电光及压电性能,在光电子领域显示出潜在的应用前景。

关键词: 紫外非线性光学晶体, K₃B₆O₁₀Br, 顶部籽晶溶液生长法, 晶体生长, 电光系数, 压电性能

Abstract: High optical quality ultraviolet nonlinear optical (NLO) crystal K₃B₆O₁₀Br (KBB) with dimensions of 42 mm×20 mm×18 mm was successfully grown by the top-seeded solution growth method. According to its structural symmetry requirements, the crystal was cut and fabricated into different devices for the complete characterizations of its photoelectric properties. Additionally, the electric-elastic constants of the KBB crystal were systematically characterized, and the significant differences in piezoelectric anisotropy are observed due to its microscopic structure. The maximum piezoelectric constant d₃₃ is measured to be 6.69 pC/N. Considering its good NLO frequency conversion, electro-optical and piezoelectrical properties, KBB crystal shows potential applications in the optoelectronics fields.

Key words: ultraviolet nonlinear optical crystal, K₃B₆O₁₀Br, top-seeded solution growth method, crystal growth, electro-optical coefficient, piezoelectric property

中图分类号:

O78
O738

刘青雄, 王天予, 刘孚安, 吴倩, 尹延如, 赫崇君, 高泽亮, 夏明军. 非线性光学晶体K₃B₆O₁₀Br的生长与光电性能研究[J]. 人工晶体学报, 2023, 52(7): 1296-1301.

LIU Qingxiong, WANG Tianyu, LIU Fuan, WU Qian, YIN Yanru, HE Chongjun, GAO Zeliang, XIA Mingjun. Growth and Photoelectric Properties of Nonlinear Optical Crystal K₃B₆O₁₀Br[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(7): 1296-1301.

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非线性光学晶体K₃B₆O₁₀Br的生长与光电性能研究

Growth and Photoelectric Properties of Nonlinear Optical Crystal K₃B₆O₁₀Br

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