稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究

人工晶体学报 ›› 2024, Vol. 53 ›› Issue (11): 1944-1955.

• 磁光、电光、压电晶体/ 透明陶瓷 • 上一篇下一篇

稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究

冯桂青¹, 徐刘伟², 袁亚舟^1,3, 郑熠¹, 黄鑫¹, 陈旻¹, 王帅华^1,2, 吴少凡^1,2

1.中国科学院福建物质结构研究所,福州 350002;
2.中国福建光电信息与技术创新实验室,福州 350108;
3.福建师范大学化学与材料学院,福州 350117

收稿日期:2024-09-16 出版日期:2024-11-15 发布日期:2024-12-09
通信作者: 王帅华,教授级高工。E-mail:shwang@fjirsm.ac.cn;吴少凡,研究员。E-mail:sfwu@fjirsm.ac.cn
作者简介:冯桂青(1997—),女,河南省人,博士研究生。E-mail:fengguiqing@fjirsm.ac.cn
基金资助:
国家重点研发计划(2021YFB3601501);福建省自然基金杰青项目(2023J06051);闽都创新实验室产学研项目(2024CXY109);中国科学院海西研究院前瞻跨越项目(CXZX-2022-JQ02);激光器件技术重点实验室开放课题(KLLDT202315)

Preparation and Properties of Rare Earth Ion Over-Doped TSAG and YAG/TSAG Composite Structural Transparent Ceramics

FENG Guiqing¹, XU Liuwei², YUAN Yazhou^1,3, ZHENG Yi¹, HUANG Xin¹, CHEN Min¹, WANG Shuaihua^1,2, WU Shaofan^1,2

1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2. Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China;
3. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350117, China

Received:2024-09-16 Online:2024-11-15 Published:2024-12-09

摘要/Abstract

摘要： 本文研究了Nd³⁺、Ho³⁺、Dy³⁺和Ce³⁺稀土离子过量掺杂对TSAG陶瓷制备及相关性能的影响,结果表明:稀土离子过量掺杂对TSAG陶瓷的微观缺陷和透过率产生了一定的影响,晶粒表面存在非二次相的少量细小颗粒,从而导致陶瓷样品透过率下降。在相同测试波长下,稀土离子过量掺杂TSAG陶瓷的Verdet常数优于纯相TSAG陶瓷。此外,本文还探索了YAG/TSAG基双层复合结构陶瓷,成功制备了YAG/TSAG及YAG/2.0%Ce∶TSAG双层复合结构陶瓷,双层结构接触面形成了亚微米级厚度的过渡层,YAG/TSAG陶瓷在波长1 064 nm处的透过率达到71.0%,YAG/TSAG基复合陶瓷的成功制备,拓宽了TSAG材料在高功率激光器上的应用前景。

关键词: 稀土离子, 过量掺杂, 透明陶瓷, Verdet常数, 双层复合结构陶瓷, 微观结构, 光学性能

Abstract: In this paper, the effects of over-doping of Nd³⁺, Ho³⁺, Dy³⁺ and Ce³⁺ rare earth ions on the preparation and related properties of TSAG ceramics were investigated, and the results show that over-doping of rare earth ions has a certain effect on the micro-defects and transmittance of TSAG ceramics. The existence of a small number of fine particles which are not in the secondary phase on the grain surface, led to the decrease of the transmittance of the ceramic samples. The Verdet constant of rare earth ion over-doped TSAG ceramics is better than that of pure phase TSAG ceramics at the same test wavelength. In addition, YAG/TSAG-based bilayer composite structural ceramics were explored. The YAG/TSAG and YAG/2.0%Ce∶TSAG bilayer composite structural ceramics were successfully prepared, with sub-micron thickness transition layer formed on the contact surface, and the transmittance of the YAG/TSAG ceramics at 1 064 nm reaches 71.0%. The successful preparation of YAG/TSAG-based composite ceramics broadens the application prospects of TSAG materials in high-power lasers.

Key words: rare earth ion, over-doping, transparent ceramics, Verdet constant, bilayer composite structural ceramics, microstructure, optical property

中图分类号:

冯桂青, 徐刘伟, 袁亚舟, 郑熠, 黄鑫, 陈旻, 王帅华, 吴少凡. 稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究[J]. 人工晶体学报, 2024, 53(11): 1944-1955.

FENG Guiqing, XU Liuwei, YUAN Yazhou, ZHENG Yi, HUANG Xin, CHEN Min, WANG Shuaihua, WU Shaofan. Preparation and Properties of Rare Earth Ion Over-Doped TSAG and YAG/TSAG Composite Structural Transparent Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1944-1955.

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稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究

Preparation and Properties of Rare Earth Ion Over-Doped TSAG and YAG/TSAG Composite Structural Transparent Ceramics

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