CuxSy-MoS2异质结构的介电损耗调控及其高效电磁波吸收

摘要/Abstract

摘要： 二硫化钼(MoS₂)因高的比表面积和独特的电子结构在电磁波(EMW)吸收领域备受关注,但其高导电性导致EMW吸收性能较差。为了解决这个问题,本文引入Cu_xS_y纳米颗粒,构建一种独特的Cu_xS_y-MoS₂异质结构,以实现适当的阻抗匹配和衰减能力。通过调控Cu_xS_y纳米颗粒,达到调节介电损耗能力,以使Cu_xS_y-MoS₂材料在低、中、高频率下都能表现出优异的EMW吸收性能。Cu_xS_y-MoS₂样品在12.68 GHz的频率下,表现出高达-72.77 dB的反射损耗(R_L),而材料的匹配厚度仅为1.99 mm,优于大多数金属硫化物异质结构。此外,它还具有宽的有效吸收带宽(EAB),在1.73 mm处达到5.1 GHz (12.9~18.0 GHz)。这项工作为设计具有强吸收、宽频带和薄厚度的MoS₂基吸波材料提供了新的策略。

关键词: Cu_xS_y, MoS₂, 异质结构, 介电损耗, 电磁波吸收

Abstract: Molybdenum disulfide (MoS₂) has attracted much attention in the field of electromagnetic wave (EMW) absorption due to its high specific surface area and unique electronic structure, but its high conductivity leads to poor EMW absorption performance. To address this issue, this work introduces Cu_xS_y nanoparticles and constructs a unique Cu_xS_y-MoS₂ heterostructure to achieve appropriate impedance matching and attenuation capabilities. By regulating Cu_xS_y nanoparticles, the dielectric loss capacity of heterostructure is adjusted. As a result, Cu_xS_y-MoS₂ exhibits excellent EMW absorption performance at low, medium and high frequencies. The Cu_xS_y-MoS₂ heterostructure shows a reflection loss (R_L) of -72.77 dB at a frequency of 12.68 GHz, with a matching thickness of only 1.99 mm, surpassing most metal sulfide heterostructures. Moreover, it also exhibits a wide effective absorption bandwidth (EAB), reaching 5.1 GHz (12.9~18.0 GHz) at 1.73 mm. This work provides a new strategy for designing MoS₂-based absorption materials with strong absorption, broadband and thin matching thickness.

Key words: Cu_xS_y, MoS₂, heterostructure, dielectric loss, electromagnetic wave absorption

中图分类号:

O441.4

蒋肖, 李博, 何邦, 曾小军. Cu_xS_y-MoS₂异质结构的介电损耗调控及其高效电磁波吸收[J]. 人工晶体学报, 2024, 53(2): 276-285.

JIANG Xiao, LI Bo, HE Bang, ZENG Xiaojun. Dielectric Loss Regulation and Efficient Electromagnetic Wave Absorption of Cu_xS_y-MoS₂ Heterostructure[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(2): 276-285.

参考文献

[1] OU P X, ZHENG Q, JIANG W. Design and performance regulation of MOFs-derived carbon composites for electromagnetic wave absorption[J]. Journal of Ceramics, 2023, 44(04): 651-661.
[2] CHANG M, JIA Z R, HE S Q, et al. Two-dimensional interface engineering of NiS/MoS₂/Ti₃C₂T_x heterostructures for promoting electromagnetic wave absorption capability[J]. Composites Part B: Engineering, 2021, 225: 109306.
[3] CHEN C J, SHAN Z, TAO S F, et al. Atomic tuning in electrically conducting bimetallic organic frameworks for controllable electromagnetic wave absorption[J]. Advanced Functional Materials, 2023, 33(45): 2305082.
[4] YANG K, CUI Y H, LIU Z H, et al. Design of core-shell structure NC@MoS₂ hierarchical nanotubes as high-performance electromagnetic wave absorber[J]. Chemical Engineering Journal, 2021, 426: 131308.
[5] LIU Z C, PAN F, DENG B W, et al. Self-assembled MoS₂/3D worm-like expanded graphite hybrids for high-efficiency microwave absorption[J]. Carbon, 2021, 174: 59-69.
[6] DENG B W, XIANG Z, XIONG J, et al. Sandwich-like Fe&TiO₂@C nanocomposites derived from MXene/Fe-MOFs hybrids for electromagnetic absorption[J]. Nano-Micro Letters, 2020, 12(1): 55.
[7] XU Z H, TANG L, ZHANG S W, et al. 2D MoS₂/CuPc heterojunction based highly sensitive photodetectors through ultrafast charge transfer[J]. Materials Today Physics, 2020, 15: 100273.
[8] XIE X Q, AO Z M, SU D W, et al. MoS₂/graphene composite anodes with enhanced performance for sodium-ion batteries: the role of the two-dimensional heterointerface[J]. Advanced Functional Materials, 2015, 25(9): 1393-1403.
[9] ZHANG X J, LI S, WANG S W, et al. Self-supported construction of three-dimensional MoS₂ hierarchical nanospheres with tunable high-performance microwave absorption in broadband[J]. The Journal of Physical Chemistry C, 2016, 120(38): 22019-22027.
[10] NING M Q, JIANG P H, DING W, et al. Phase manipulating toward molybdenum disulfide for optimizing electromagnetic wave absorbing in gigahertz[J]. Advanced Functional Materials, 2021, 31(19): 2011229.
[11] BAI J L, HUANG S J, YAO X M, et al. Surface engineering of nanoflower-like MoS₂ decorated porous Si₃N₄ ceramics for electromagnetic wave absorption[J]. Journal of Materials Chemistry A, 2023, 11(12): 6274-6285.
[12] WANG J Q, LIU L, JIAO S L, et al. Hierarchical carbon Fiber@MXene@MoS₂ core-sheath synergistic microstructure for tunable and efficient microwave absorption[J]. Advanced Functional Materials, 2020, 30(45): 2002595.
[13] DU H, ZHANG Q P, ZHAO B, et al. Novel hierarchical structure of MoS₂/TiO₂/Ti₃C₂T_x composites for dramatically enhanced electromagnetic absorbing properties[J]. Journal of Advanced Ceramics, 2021, 10(5): 1042-1051.
[14] ZHANG D Q, XIONG Y F, CHENG J Y, et al. Construction of low-frequency and high-efficiency electromagnetic wave absorber enabled by texturing rod-like TiO₂ on few-layer of WS₂ nanosheets[J]. Applied Surface Science, 2021, 548: 149158.
[15] LI Y Y, GAI L X, SONG G L, et al. Enhanced properties of CoS₂/Cu₂S embedded N/S co-doped mesh-like carbonaceous composites for electromagnetic wave absorption[J]. Carbon, 2022, 186: 238-252.
[16] LIU X F, NIE X Y, YU R H, et al. Design of dual-frequency electromagnetic wave absorption by interface modulation strategy[J]. Chemical Engineering Journal, 2018, 334: 153-161.
[17] ZENG X J, ZHAO C, JIANG X A, et al. Functional tailoring of multi-dimensional pure MXene nanostructures for significantly accelerated electromagnetic wave absorption[J]. Small, 2023, 19(41): 2303393.
[18] WANG H Q, WANG J W, WANG X Z, et al. Dielectric properties and energy storage performance of PVDF-based composites with MoS₂@MXene nanofiller[J]. Chemical Engineering Journal, 2022, 437: 135431.
[19] ZENG X, ZHAO C, NIE T, et al. Construction of 0D/1D/2D MXene nanoribbons-NiCo@NC hierarchical network and their coupling effect on electromagnetic wave absorption[J]. Materials Today Physics, 2022, 28: 100888.
[20] XIN X, SONG Y R, GUO S H, et al. In-situ growth of high-content 1T phase MoS₂ confined in the CuS nanoframe for efficient photocatalytic hydrogen evolution[J]. Applied Catalysis B: Environmental, 2020, 269: 118773.
[21] WANG X Y, ZHU T, CHANG S C, et al. 3D nest-like architecture of core-shell CoFe₂O₄@1T/2H-MoS₂ composites with tunable microwave absorption performance[J]. ACS Applied Materials & Interfaces, 2020, 12(9): 11252-11264.
[22] ZENG X J, ZHANG Z L, JIN C L. Construction of Ti₃C₂T_x nanoribbons/MoCoP_x heterostructures and high-efficient electrocatalytic OER performance[J]. Journal of China University of Petroleum (Edition of Natural Science), 2023, 47(4): 190-197.
[23] XU J, LIU L N, ZHANG X C, et al. Tailoring electronic properties and polarization relaxation behavior of MoS₂ monolayers for electromagnetic energy dissipation and wireless pressure micro-sensor[J]. Chemical Engineering Journal, 2021, 425: 131700.
[24] PAN Z H, CAO F, HU X, et al. A facile method for synthesizing CuS decorated Ti₃C₂ MXene with enhanced performance for asymmetric supercapacitors[J]. Journal of Materials Chemistry A, 2019, 7(15): 8984-8992.
[25] ZENG X J, JIANG X A, NING Y, et al. Construction of dual heterogeneous interface between zigzag-like Mo-MXene nanofibers and small CoNi@NC nanoparticles for electromagnetic wave absorption[J]. Journal of Advanced Ceramics, 2023, 12(8): 1562-1576.
[26] ZENG X J, ZHANG H Q, YU R H, et al. A phase and interface co-engineered MoP_xS_y@NiFeP_xS_y@NPS-C hierarchical heterostructure for sustainable oxygen evolution reaction[J]. Journal of Materials Chemistry A, 2023, 11(26): 14272-14283.
[27] YU X P, YANG C, SONG P, et al. Self-assembly of Au/MoS₂ quantum dots core-satellite hybrid as efficient electrocatalyst for hydrogen production[J]. Tungsten, 2020, 2(2): 194-202.
[28] WU P K, CHEN T, LIU C Y, et al. Confinement engineering to enhance broadband microwave absorption of hierarchically magnetic carbon tubular composite[J]. Carbon, 2023, 214: 118353.
[29] LIU J L, ZHANG L M, ZANG D Y, et al. A competitive reaction strategy toward binary metal sulfides for tailoring electromagnetic wave absorption[J]. Advanced Functional Materials, 2021, 31(45): 2105018.
[30] ZHENG C L, NING M Q, ZOU Z, et al. Two birds with one stone: broadband electromagnetic wave absorption and anticorrosion performance in 2-18 GHz for Prussian blue analog derivatives aimed for practical applications[J]. Small, 2023, 19(32): e2208211.
[31] ZHOU X F, JIA Z R, ZHANG X X, et al. Electromagnetic wave absorption performance of NiCo₂X₄ (X=O, S, Se, Te) spinel structures[J]. Chemical Engineering Journal, 2021, 420: 129907.
[32] CHENG J, CAI L, SHI Y Y, et al. Polarization loss-enhanced honeycomb-like MoS₂ nanoflowers/undaria pinnatifida-derived porous carbon composites with high-efficient electromagnetic wave absorption[J]. Chemical Engineering Journal, 2022, 431: 134284.
[33] GAO X R, JIA Z R, WANG B B, et al. Synthesis of NiCo-LDH/MXene hybrids with abundant heterojunction surfaces as a lightweight electromagnetic wave absorber[J]. Chemical Engineering Journal, 2021, 419: 130019.
[34] YAN J, HUANG Y, CHEN C, et al. The 3D CoNi alloy particles embedded in N-doped porous carbon foams for high-performance microwave absorbers[J]. Carbon, 2019, 152: 545-555.
[35] WANG J W, WANG B B, WANG Z, et al. Synthesis of 3D flower-like ZnO/ZnCo₂O₄ composites with the heterogeneous interface for excellent electromagnetic wave absorption properties[J]. Journal of Colloid and Interface Science, 2021, 586: 479-490.
[36] ZHOU Y, ZHOU W J, NI C H, et al. “Tree blossom” Ni/NC/C composites as high-efficiency microwave absorbents[J]. Chemical Engineering Journal, 2022, 430: 132621.
[37] PENG H, HE M, ZHOU Y M, et al. Low-temperature carbonized biomimetic cellulose nanofiber/MXene composite membrane with excellent microwave absorption performance and tunable absorption bands[J]. Chemical Engineering Journal, 2022, 433: 133269.

Cu_xS_y-MoS₂异质结构的介电损耗调控及其高效电磁波吸收

Dielectric Loss Regulation and Efficient Electromagnetic Wave Absorption of Cu_xS_y-MoS₂ Heterostructure

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