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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (8): 1480-1486.

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PbS量子点/MoO3纳米带复合材料的低温气敏性能研究

曹敏驰;刘洋;侯淑新;陈春润;徐腾;何竞;杨爽;王浩然;李心宏;刘曰利   

  1. 武汉理工大学材料科学与工程学院,硅酸盐建筑材料国家重点实验室,武汉 430070
  • 出版日期:2017-08-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(11674258);国家级大学生创新创业训练计划(20161049714005,20161049701007);武汉理工大学大学生创新创业训练计划(2016-CL-AL-03)

Study on the Gas Sensing Properties of PbS Quantum Dots/MoO3 Nanobelts at Low Temperature

CAO Min-chi;LIU Yang;HOU Shu-xin;CHEN Chun-run;XU Teng;HE Jing;YANG Shuang;WANG Hao-ran;LI Xin-hong;LIU Yue-li   

  • Online:2017-08-15 Published:2021-01-20

摘要: 采用液相法制备PbS量子点修饰MoO3纳米带复合材料.利用XRD、FESEM、TEM、EDS等表征手段分析样品组成、结构与形貌,分别将MoO3纳米带、PbS量子点、PbS量子点/MoO3纳米带组装成陶瓷管气敏元件并测试其对NH3的气敏性能.结果表明,在低温(20~100 ℃)下PbS量子点/MoO3纳米带复合材料对NH3具有良好检测能力,最低测试限为10 ppm.由于PbS量子点均匀分布在MoO3纳米带表面可形成异质结界面,这可有助于电子、空穴的分离,从而显著改善电子传输性能和气敏特性.

关键词: MoO3纳米带;PbS量子点;液相法;气敏性能;低温

Abstract: PbS quantum dots (QDs) decorated MoO3 nanobelts were prepared by liquid phase method.The composition, structure and morphology of PbS QDs/MoO3 nanobelts were charactered by XRD, FESEM, TEM and EDS measurements.Gas sensors based on MoO3, PbS QDs and PbS QDs/MoO3 nanobelts were assembled using commercial ceramic tubes and their gas sensing properties towards NH3 were tested.The results show that gas sensors based on PbS QDs/MoO3 nanobelts have a good gas sensing response to NH3 at a relative low temperature range (20-100 ℃), and the lowest detect limit is 10 ppm.PbS QDs are uniformly dispersed on the surface of the MoO3 nanobelts, and then the formed heterojunction interface may favor for the separation of electrons and holes, which will greatly improve their electron transfer ability and gas sensing performance.

Key words: PbS quantum dots (QDs) decorated MoO3 nanobelts were prepared by liquid phase method.The composition, structure and morphology of PbS QDs/MoO3 nanobelts were charactered by XRD, FESEM, TEM and EDS measurements.Gas sensors based on MoO3, PbS QDs and PbS QDs/MoO3 nanobelts were assembled using commercial ceramic tubes and their gas sensing properties towards NH3 were tested.The results show that gas sensors based on PbS QDs/MoO3 nanobelts have a good gas sensing response to NH3 at a relative low temperature range (20-100 ℃), and the lowest detect limit is 10 ppm.PbS QDs are uniformly dispersed on the surface of the MoO3 nanobelts, and then the formed heterojunction interface may favor for the separation of electrons and holes, which will greatly improve their electron transfer ability and gas sensing performance.

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