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人工晶体学报 ›› 2021, Vol. 50 ›› Issue (2): 345-352.

• 研究论文 • 上一篇    下一篇

[(Epy)2][MnBr2I2]配合物的合成、晶体结构及发光性能

杨晨乐1, 李凌燕1, 李嫚1, 沈轶明1, 潘尚可1,2, 潘建国1,2   

  1. 1.宁波大学材料科学与化学工程学院,宁波 315211;
    2.浙江省光电探测材料及器件重点实验室,宁波 315211
  • 收稿日期:2020-11-25 发布日期:2021-03-24
  • 通讯作者: 潘建国,教授。E-mail:panjianguo@nbu.edu.cn
  • 作者简介:杨晨乐(1996—),女,浙江省人,硕士研究生。E-mail:1160317676@qq.com
  • 基金资助:
    国家自然科学基金(61775108,61875096)

Synthesis, Crystal Structure and Luminescence Properties of [(Epy)2][MnBr2I2] Complex

YANG Chenyue1, LI Lingyan1, LI Man1, SHEN Yiming1, PAN Shangke1,2, PAN Jianguo1,2   

  1. 1.School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China;
    2.Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, China
  • Received:2020-11-25 Published:2021-03-24

摘要: 室温下,以N-乙基吡啶碘盐(Epy)I和四水溴化锰(MnBr2·4H2O)为原料合成了一种零维发光材料[(Epy)2][MnBr2I2]。对该配合物进行元素含量分析、红外光谱、单晶X射线衍射、粉末X射线衍射、紫外可见吸收光谱、光致发光光谱及X射线激发发射光谱等测试。单晶X射线衍射结果表明:配合物为单斜晶系,C2/c空间群,中心离子Mn(Ⅱ)为四面体构型,晶胞参数为a=2.825 5(6) nm,b=0.839 71(17) nm,c=1.836 0(4) nm。在332 nm紫外光激发下,配合物发出528 nm的绿光,对应于四面体Mn(Ⅱ)配合物的4T1(G)→6A1特征辐射跃迁,荧光寿命为58.85 μs,荧光量子产率为58.29%。X射线激发光谱表明配合物发光强度较高,具有X射线荧光性能。

关键词: 离子液体, 锰(Ⅱ)配合物, 晶体结构, 发光性能

Abstract: A zero-dimensional luminescent material [(Epy)2][MnBr2I2] was synthesized using N-ethylpyridine iodized salt (Epy)I and manganese bromide tetrahydrate (MnBr2·4H2O) as raw material at room temperature. The complex was tested by element content analysis, infrared spectrum, single crystal X-ray diffraction, powder X-ray diffraction, UV-visible absorption spectrum, photoluminescence spectrum X-ray excitation emission spectrum and so on. The single crystal X-ray diffraction results show that the complex is monoclinic, space group of C2/c, and the central Mn(Ⅱ) has a tetrahedron configuration. The crystal cell parameters are a=2.825 5(6) nm, b=0.839 71(17) nm, and c=1.836 0(4) nm. Under the UV light (λex=332 nm), the complex emits green light at 528 nm, corresponding to the tetrahedron Mn(Ⅱ) complex of 4T1(G) →6A1 radiation characteristics of the transition. Moreover, the fluorescence lifetime is 58.85 μs and the corresponding fluorescence quantum yield is 58.29%. X-ray excitation spectrum shows that the complex has high luminescence intensity, and it has certain X-ray fluorescence properties.

Key words: ionic liquid, manganese(Ⅱ) complex, crystal structure, luminescence performance

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