压致响应碳基晶体材料的设计与构筑

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (7): 1307-1313.

压致响应碳基晶体材料的设计与构筑

陈德斯, 董家君, 翟春光, 姚明光, 刘冰冰

吉林大学物理学院,超硬材料国家重点实验室,长春 130012

收稿日期:2021-05-06 出版日期:2021-07-15 发布日期:2021-08-16
通讯作者: 姚明光,教授。E-mail:yaomg@jlu.edu.cn
作者简介:陈德斯(1999—),男,吉林省人,硕士研究生。E-mail:chends20@jlu.edu.cn
基金资助:
国家自然科学基金(51822204)

Design and Construction of Carbon-Based Crystal Materials with Pressure Response

CHEN Desi, DONG Jiajun, ZHAI Chunguang, YAO Mingguang, LIU Bingbing

State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China

Received:2021-05-06 Online:2021-07-15 Published:2021-08-16

摘要/Abstract

摘要： 材料在压力作用下可出现不同的响应行为,如硬化、压缩性、光学性质改变等,依此设计出具有优异力学、机械以及发光性能的材料,是设计新型功能材料的重要途径。本文将介绍课题组近年来在新型压致响应功能晶体材料研究中取得的进展,基于碳及碳骨架分子,设计不同的碳基分子共晶,利用高压技术,设计构筑出系列具有潜在超硬特性、负体积压缩性的材料以及反常压力响应的发光材料。

关键词: 共晶体, 高压, 压致响应, 富勒烯, 溶剂化富勒烯, 压致膨胀, 反常荧光响应

Abstract: Materials that exhibit obvious pressure responses upon compression, such as hardening, compressibility and optical properties change, and so on, which have been explored as an important way to design new functional materials with desired mechanical properties and luminescent properties. Here, we will introduce some recent progress on the research of new pressure responsive functional crystalline materials with novel properties. A new strategy has been developed to design and construct new functional materials by application of high pressure to the designed co-crystals. The co-crystals have been designed based on carbon and carbon-based molecules and studied by high pressure technique. A series of new materials with potentially superhard properties, negative volume compressibility and anomalous pressure response in luminescence has been obtained.

Key words: co-crystal, high pressure, pressure response, fullerene, solvated fullerene, pressure-induced expansion, abnormal fluorescence response

中图分类号:

TB34

陈德斯, 董家君, 翟春光, 姚明光, 刘冰冰. 压致响应碳基晶体材料的设计与构筑[J]. 人工晶体学报, 2021, 50(7): 1307-1313.

CHEN Desi, DONG Jiajun, ZHAI Chunguang, YAO Mingguang, LIU Bingbing. Design and Construction of Carbon-Based Crystal Materials with Pressure Response[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(7): 1307-1313.

参考文献

[1] RUOFF R S, RUOFF A L. Is C₆₀ stiffer than diamond?[J]. Nature, 350 (1991): 663-664.
[2] SAUNDERS M, JIMÉNEZ-VÁZQUEZ H A, JAMES CROSS R, et al. Stable compounds of helium and neon: He@C₆₀ and Ne@C₆₀[J]. Science, 1993, 259(5100): 1428-1430.
[3] HU K, YAO M G, YANG Z X, et al. Pressure tuned photoluminescence and band gap in two-dimensional layered g-C₃N₄: the effect of interlayer interactions[J]. Nanoscale, 2020, 12(23): 12300-12307.
[4] SNIDER E, DASENBROCK-GAMMON N, MCBRIDE R, et al. Room-temperature superconductivity in a carbonaceous sulfur hydride[J]. Nature, 2020, 586(7829): 373-377.
[5] HEINEY P A. Structure, dynamics and ordering transition of solid C₆₀[J]. Journal of Physics and Chemistry of Solids, 1992, 53(11): 1333-1352.
[6] HEINEY P A, FISCHER J E, MCGHIE A R, et al. Orientational ordering transition in solid C₆₀[J]. Physical Review Letters, 1991, 66(22): 2911-2914.
[7] WANG L, LIU B B, LIU D D, et al. Synthesis and high pressure induced amorphization of C₆₀ nanosheets[J]. Applied Physics Letters, 2007, 91(10): 103112.
[8] FISCHER J E. Structure and dynamics of solid C₆₀ and its intercalation compounds[J]. Materials Science and Engineering: B, 1993, 19(1/2): 90-99.
[9] RANJAN K, DHARAMVIR K, JINDAL V K. Comparative study of alkali metal-doped C₆₀ solids[J]. Physica B: Condensed Matter, 2006, 371(2): 232-240.
[10] ZHOU P, WANG K A, WANG Y, et al. Raman scattering in C₆₀ and alkali-metal-saturated C₆₀[J]. Physical Review B, Condensed Matter, 1992, 46(4): 2595-2605.
[11] LIU D D, CUI W, YAO M G, et al. Effects of alcohols on shape-tuning and luminescence-enhancing of C₇₀ nanocrystals[J]. Optical Materials, 2013, 36(2): 449-454.
[12] YAO M G, FAN X H, LIU D D, et al. Synthesis of differently shaped C₇₀ nano/microcrystals by using various aromatic solvents and their crystallinity-dependent photoluminescence[J]. Carbon, 2012, 50(1): 209-215.
[13] WANG L, LIU B B, YU S D, et al. Highly enhanced luminescence from single-crystalline C₆₀·1m-xylene nanorods[J]. Chemistry of Materials, 2006, 18(17): 4190-4194.
[14] PARK C, YOON E, KAWANO M, et al. Self-crystallization of C₇₀ cubes and remarkable enhancement of photoluminescence[J]. Angewandte Chemie International Edition, 2010, 49(50): 9670-9675.
[15] DU M R, YAO M G, DONG J J, et al. New ordered structure of amorphous carbon clusters induced by fullerene-cubane reactions[J]. Advanced Materials, 2018, 30(22): 1706916.
[16] WANG L, LIU B B, LI H, et al. Long-range ordered carbon clusters: a crystalline material with amorphous building blocks[J]. Science, 2012, 337(6096): 825-828.
[17] YAO M G, CUI W, XIAO J P, et al. Pressure-induced transformation and superhard phase in fullerenes: the effect of solvent intercalation[J]. Applied Physics Letters, 2013, 103(7): 071913.
[18] CUI W, YAO M G, LIU S J, et al. A new carbon phase constructed by long-range ordered carbon clusters from compressing C₇₀ solvates[J]. Advanced Materials, 2014, 26(42): 7257-7263.
[19] CUI J X, YAO M G, YANG H, et al. Structural stability and deformation of solvated Sm@C₂(42)-C₉₀ under high pressure[J]. Scientific Reports, 2016, 6(1): 1-10.
[20] AN C, ZHOU Y H, CHEN C H, et al. Long-range ordered amorphous atomic chains as building blocks of a superconducting quasi-one-dimensional crystal[J]. Advanced Materials, 2020, 32(38): 2002352.
[21] ZHANG Y, YAO M G, DU M R, et al. Negative volume compressibility in Sc₃N@C₈₀-cubane cocrystal with charge transfer[J]. Journal of the American Chemical Society, 2020, 142(16): 7584-7590.
[22] LIU H, GU Y, WANG K, et al. Pressure-induced blue-shifted and enhanced emission: a cooperative effect between aggregation-induced emission and energy-transfer suppression[J]. J Am Chem Soc, 2020, 142(3): 1153-1158.
[23] ZHAI C G, YIN X, NIU S F, et al. Molecular insertion regulates the donor-acceptor interactions in cocrystals for the design of piezochromic luminescent materials[EB/OL]. 2021.