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人工晶体学报 ›› 2021, Vol. 50 ›› Issue (9): 1729-1734.

• 研究论文 • 上一篇    下一篇

共沉淀法合成ZnMoO4粉体及其抗菌性能

刘欣, 唐燕超, 刘芳, 李家科   

  1. 景德镇陶瓷大学材料科学与工程学院,景德镇 333403
  • 收稿日期:2021-06-23 出版日期:2021-09-15 发布日期:2021-10-15
  • 通讯作者: 李家科,博士,教授。E-mail:jiakeli.jci@163.com
  • 作者简介:刘 欣(1974—),女,湖北省人,高级实验师。E-mail:lxin6668@163.com
  • 基金资助:
    江西省重点研发计划(20181BBE58004);江西省教育厅科学技术研究项目(GJJ201316,GJJ201315);景德镇市科技计划(20182GYZD011-05);景德镇市陶瓷产业协同创新项目(20200924)

Synthesis of ZnMoO4 Powder by Coprecipitation Method and Its Antibacterial Performance

LIU Xin, TANG Yanchao, LIU Fang, LI Jiake   

  1. School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, China
  • Received:2021-06-23 Online:2021-09-15 Published:2021-10-15

摘要: 以Zn(NO3)2·6H2O、(NH4)6Mo7O24·4H2O为主要原料,采用共沉淀法合成ZnMoO4粉体。利用XRD、SEM等测试方法对合成样品的物相组成、微观结构进行表征。以培养的大肠杆菌为消杀对象,研究了不同热处理温度下的样品对大肠杆菌的抗菌性能。结果表明,前驱体主要为非晶态,含少量ZnMoO4、Zn2Mo3O8、Zn(OH)2和MoO3;前驱体经400~600 ℃、保温30 min热处理,其产物转化为ZnMoO4,且随着热处理温度的升高,合成的ZnMoO4晶型逐渐完善,抗菌性能增加,当热处理温度为600 ℃时,可以获得结晶良好的ZnMoO4,其晶粒呈颗粒状和片状,平均粒径约为1.5 μm。不同热处理温度合成的ZnMoO4均具有一定的抗菌性能,其中经600 ℃热处理得到的ZnMoO4具有最佳抗菌性能,经过24 h抗菌检测,其抗菌率达到99.2%,在商用涂料料浆中外加5%的ZnMoO4粉体,所制备涂层对大肠杆菌的抗菌率达到95.7%,表明ZnMoO4及其涂料具有良好的应用前景。

关键词: ZnMoO4, 共沉淀法, 物相组成, 微观结构, 抗菌性能

Abstract: ZnMoO4 powder was synthesized by coprecipitation method using Zn(NO3)2·6H2O and (NH4)6Mo7O24·4H2O as main materials. Phase composition, microstructure of the synthesized samples were characterized by XRD, SEM, and so on. Antibacterial performance of the synthesized samples with different treatment temperatures were studied through Escherichia coli as the killing object. The results show that precursor mainly consists of non-crystalline with a small amount of ZnMoO4, Zn2Mo3O8, Zn(OH)2 and MoO3; the precursor is transferred into ZnMoO4 when heat treated at 400 ℃ to 600 ℃ for 30 min. With the increase of heat treatment temperature, the crystal structure of ZnMoO4 is gradually improved, so antibacterial performance of ZnMoO4 is increased. When the heat treatment temperature is 600 ℃, ZnMoO4 with good crystallization can be obtained, and particle size of ZnMoO4 is granular and flake-like with average size of 1.5 μm. The as-synthesized ZnMoO4 owns better antibacterial performance. Among them, antibacterial performance of ZnMoO4 synthesized by heat treatment of 600 ℃ is the best, and its antibacterial rate arrives at 99.2% after 24 h antibacterial test. When 5% ZnMoO4 powder is added into commercial coating slurry, antibacterial rate of the coating reaches 95.7%, which has good application prospects.

Key words: ZnMoO4, coprecipitation method, phase composition, microstructure, antibacterial performance

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