直接碳燃料电池燃料的研究进展

摘要/Abstract

摘要： 直接碳燃料电池(DCFC)是一种清洁高效利用碳资源发电的装置。其因能量转换率高,对环境污染小,燃料选择范围广等优点获得了越来越多的关注。DCFC的性能与使用的燃料密切相关,为了探究燃料对DCFC的影响,本文分别阐述了石墨、炭黑、中密度纤维板、生物质、煤、活性炭的特性及改性方法,分析讨论了燃料表面含氧官能团以及燃料中的金属催化剂对阳极电化学反应的促进作用,发现燃料表面化学性质要比比表面积更加重要。同时,本文也提出了对生物质这一优良的可再生资源的期待,为未来DCFC燃料的发展提供参考。

关键词: 直接碳燃料电池, 碳资源, 含氧官能团, 金属催化剂, 生物质, 燃料

Abstract: The direct carbon fuel cell (DCFC) is a clean and efficient power generation device using carbon resources. It has attracted more and more attention due to its high energy conversion efficiency, low environmental pollution and wide range of fuel selection. The performance of DCFC is closely related to the fuel used, in order to explore the influence of fuel on DCFC, the characteristics and modification methods of graphite, carbon black, medium density fiberboard, biomass, coal and activated carbon are expounded in this paper. The surface oxygen-containing functional groups and the promoting effect of metal catalysts in fuel on anode electrochemical reactions are analyzed and discussed. It is found that fuel surface chemical properties are more important than the specific surface area. Simultaneously, this paper also puts forward the expectation of biomass as an excellent renewable resource, it will provide a reference for the development and utilization of DCFC fuel in the future.

Key words: DCFC, carbon resource, oxygen-containing functional group, metal catalyst, biomass, fuel

中图分类号:

TM911.4

郝森然, 陈晓, 曾晓苑, 肖杰. 直接碳燃料电池燃料的研究进展[J]. 人工晶体学报, 2022, 51(2): 360-369.

HAO Senran, CHEN Xiao, ZENG Xiaoyuan, XIAO Jie. Research Progress of Fuels for Direct Carbon Fuel Cells[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2022, 51(2): 360-369.

参考文献

[1] LI G, ZHU R, YANG Y. Polymer solar cells[J]. Nature Photonics, 2012, 6(3): 153-161.
[2] O′ROURKE F, BOYLE F, REYNOLDS A. Tidal energy update 2009[J]. Applied Energy, 2010, 87(2): 398-409.
[3] ZARFL C, LUMSDON A E, BERLEKAMP J, et al. A global boom in hydropower dam construction[J]. Aquatic Sciences, 2015, 77(1): 161-170.
[4] DÍAZ-GONZÁLEZ F, SUMPER A, GOMIS-BELLMUNT O, et al. A review of energy storage technologies for wind power applications[J]. Renewable and Sustainable Energy Reviews, 2012, 16(4): 2154-2171.
[5] BIE K, FU P F, LIU Y, et al. Comparative study on the performance of different carbon fuels in a molten carbonate direct carbon fuel cell with a novel anode structure[J]. Journal of Power Sources, 2020, 460: 228101.
[6] XIE H P, ZHAI S, CHEN B, et al. Coal pretreatment and Ag-infiltrated anode for high-performance hybrid direct coal fuel cell[J]. Applied Energy, 2020, 260: 114197.
[7] LI X, ZHU Z H, CHEN J L, et al. Surface modification of carbon fuels for direct carbon fuel cells[J]. Journal of Power Sources, 2009, 186(1): 1-9.
[8] CAI W Z, LIU J, LIU P P, et al. A direct carbon solid oxide fuel cell fueled with char from wheat straw[J]. International Journal of Energy Research, 2019, 43(7): 2468-2477.
[9] XIE Y M, LU Z B, MA C C, et al. High-performance gas-electricity cogeneration using a direct carbon solid oxide fuel cell fueled by biochar derived from camellia oleifera shells[J]. International Journal of Hydrogen Energy, 2020, 45(53): 29322-29330.
[10] JIANG C R, CUI C, MA J J, et al. Insight into graphite oxidation in a NiO-based hybrid direct carbon fuel cell[J]. International Journal of Hydrogen Energy, 2020, 45(17): 10559-10568.
[11] JIANG C R, MA J J, BONACCORSO A D, et al. Demonstration of high power, direct conversion of waste-derived carbon in a hybrid direct carbon fuel cell[J]. Energy & Environmental Science, 2012, 5(5): 6973.
[12] CAI W Z, LIU J, XIE Y M, et al. An investigation on the kinetics of direct carbon solid oxide fuel cells[J]. Journal of Solid State Electrochemistry, 2016, 20(8): 2207-2216.
[13] RADY A C, GIDDEY S, KULKARNI A, et al. Direct carbon fuel cell operation on brown coal[J]. Applied Energy, 2014, 120: 56-64.
[14] LIU J, ZHOU M Y, ZHANG Y P, et al. Electrochemical oxidation of carbon at high temperature: principles and applications[J]. Energy & Fuels, 2018, 32(4): 4107-4117.
[15] PALNIANDY L K, YOON L W, WONG W Y, et al. Application of biochar derived from different types of biomass and treatment methods as a fuel source for direct carbon fuel cells[J]. Energies, 2019, 12(13): 2477.
[16] YU F Y, HAN T T, WANG Z G, et al. Recent progress in direct carbon solid oxide fuel cell: advanced anode catalysts, diversified carbon fuels, and heat management[J]. International Journal of Hydrogen Energy, 2021, 46(5): 4283-4300.
[17] ZECEVIC S, PATTON E M, PARHAMI P. Carbon-air fuel cell without a reforming process[J]. Carbon, 2004, 42(10): 1983-1993.
[18] CHEREPY N J, KRUEGER R, FIET K J, et al. Direct conversion of carbon fuels in a molten carbonate fuel cell[J]. Journal of the Electrochemical Society, 2005, 152(1): A80.
[19] CHEN M M, WANG C Y, NIU X M, et al. Carbon anode in direct carbon fuel cell[J]. International Journal of Hydrogen Energy, 2010, 35(7): 2732-2736.
[20] WU H, XIAO J, ZENG X Y, et al. A high performance direct carbon solid oxide fuel cell: a green pathway for brown coal utilization[J]. Applied Energy, 2019, 248: 679-687.
[21] EOM S, CHO J, AHN S, et al. Comparison of the electrochemical reaction parameter of graphite and sub-bituminous coal in a direct carbon fuel cell[J]. Energy & Fuels, 2016, 30(4): 3502-3508.
[22] LI S B, PAN W Z, WANG S R, et al. Electrochemical performance of different carbon fuels on a hybrid direct carbon fuel cell[J]. International Journal of Hydrogen Energy, 2017, 42(25): 16279-16287.
[23] SCHMIDT M W I, NOACK A G. Black carbon in soils and sediments: analysis, distribution, implications, and current challenges[J]. Global Biogeochemical Cycles, 2000, 14(3): 777-793.
[24] RAZDYAKONOVA G I, LIKHOLOBOV V A, KOKHANOVSKAYA O A. Khimiya v interesakh ustoichivogo razvitiya, 2016, 24(4): 473-82.
[25] LIU R Z, ZHAO C H, LI J L, et al. A novel direct carbon fuel cell by approach of tubular solid oxide fuel cells[J]. Journal of Power Sources, 2010, 195(2): 480-482.
[26] LI C, SHI Y X, CAI N S. Performance improvement of direct carbon fuel cell by introducing catalytic gasification process[J]. Journal of Power Sources, 2010, 195(15): 4660-4666.
[27] JAIN S L, BARRY LAKEMAN J, POINTON K D, et al. Electrochemical performance of a hybrid direct carbon fuel cell powered by pyrolysed MDF[J]. Energy & Environmental Science, 2009, 2(6): 687.
[28] GAN Q, ALLEN S J, MATTHEWS R. Activation of waste MDF sawdust charcoal and its reactive dye adsorption characteristics[J]. Waste Management, 2004, 24(8): 841-848.
[29] QIU Q Y, ZHOU M Y, CAI W Z, et al. A comparative investigation on direct carbon solid oxide fuel cells operated with fuels of biochar derived from wheat straw, corncob, and bagasse[J]. Biomass and Bioenergy, 2019, 121: 56-63.
[30] 刘跃岭,景琦,徐帆,等.直接利用生物质的化学燃料电池研究进展[J].化工进展,2018,37(9):3346-3354.
LIU Y L, JING Q, XU F, et al. Research progress of chemical fuel cells by direct use of biomass[J]. Chemical Industry and Engineering Progress, 2018, 37(9): 3346-3354(in Chinese).
[31] JAFRI N, WONG W Y, YOON L W, et al. Pretreated mesocarp fibre biochars as carbon fuel for direct carbon fuel cells[J]. International Journal of Hydrogen Energy, 2021, 46(31): 16762-16775.
[32] LIU G Y, ZHANG Y T, ZHOU A N, et al. A comparative study on the performance of direct carbon solid oxide fuel cells powered with different rank coals[J]. Energy & Fuels, 2021, 35(8): 6835-6844.
[33] GONZALEZ-SALAZAR M A, KIRSTEN T, PRCHLIK L. Review of the operational flexibility and emissions of gas- and coal-fired power plants in a future with growing renewables[J]. Renewable and Sustainable Energy Reviews, 2018, 82: 1497-1513.
[34] JIAO Y, XUE X T, AN W T, et al. Purified high-sulfur coal as a fuel for direct carbon solid oxide fuel cells[J]. International Journal of Energy Research, 2019, 43(7): 2501-2513.
[35] CAO T, HUANG K, SHI Y X, et al. Recent advances in high-temperature carbon-air fuel cells[J]. Energy & Environmental Science, 2017, 10(2): 460-490.
[36] TANG Y B, LIU J. Effect of anode and Boudouard reaction catalysts on the performance of direct carbon solid oxide fuel cells[J]. International Journal of Hydrogen Energy, 2010, 35(20): 11188-11193.
[37] LIU G Y, ZHOU A N, QIU J S, et al. Utilization of bituminous coal in a direct carbon fuel cell[J]. International Journal of Hydrogen Energy, 2016, 41(20): 8576-8582.
[38] LI X, ZHU Z H, DE MARCO R, et al. Evaluation of raw coals as fuels for direct carbon fuel cells[J]. Journal of Power Sources, 2010, 195(13): 4051-4058.
[39] XU K, DONG J Z, HU H Y, et al. Effect of ash components on the performance of solid oxide electrolyte-based carbon fuel cells[J]. Energy & Fuels, 2018, 32(4): 4538-4546.
[40] YAN J C, BAI Z Q, HAO P, et al. Comparative study of low-temperature pyrolysis and solvent treatment on upgrading and hydro-liquefaction of brown coal[J]. Fuel, 2017, 199: 598-605.
[41] 崔帅,唐晓宁,张彬,等.云南褐煤成型工艺条件的研究与优化[J].硅酸盐通报,2015,34(7):1744-1749.
CUI S, TANG X N, ZHANG B, et al. Experimental study and optimization for the molding process condition of lignite in Yunnan[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(7): 1744-1749(in Chinese).
[42] 张跃东.活性炭吸附法在工业废水处理中的应用[J].河北化工,2011,34(6):74-76.
ZHANG Y D. Application of active carbon adsorption methoel in treating industrial wastewater[J]. Hebei Chemical Industry, 2011, 34(6): 74-76(in Chinese).
[43] 王程,曹强,汤海涌.活性炭的应用研究进展[J].化学与生物工程,2019,36(1):11-14.
WANG C, CAO Q, TANG H Y. Research progress in application of activated carbon[J]. Chemistry & Bioengineering, 2019, 36(1): 11-14(in Chinese).
[44] XIE Y M, TANG Y B, LIU J. A verification of the reaction mechanism of direct carbon solid oxide fuel cells[J]. Journal of Solid State Electrochemistry, 2013, 17(1): 121-127.
[45] JIAO Y, TIAN W J, CHEN H L, et al. In situ catalyzed Boudouard reaction of coal char for solid oxide-based carbon fuel cells with improved performance[J]. Applied Energy, 2015, 141: 200-208.
[46] YU X K, SHI Y X, WANG H J, et al. Using potassium catalytic gasification to improve the performance of solid oxide direct carbon fuel cells: experimental characterization and elementary reaction modeling[J]. Journal of Power Sources, 2014, 252: 130-137.
[47] CAI W Z, LIU J, YU F Y, et al. A high performance direct carbon solid oxide fuel cell fueled by Ca-loaded activated carbon[J]. International Journal of Hydrogen Energy, 2017, 42(33): 21167-21176.
[48] TANG H Q, YU F Y, WANG Y S, et al. Enhancing the power output of direct carbon solid oxide fuel cell using Ba-loaded activated carbon fuel[J]. Energy Technology, 2019, 7(4): 1800885.