SiW12、CsPbI3协同提高TiO2纳米管光电转换效率的研究

摘要/Abstract

摘要： 为克服TiO₂纳米管在光电转换时电子-空穴复合率高和吸收光谱范围窄的缺陷,利用多酸H₄SiW₁₂O₄₀(SiW₁₂)和CsPbI₃量子点对其协同修饰,采用电沉积法将SiW₁₂沉积在TiO₂纳米管上,制备了SiW₁₂/TiO₂纳米管复合薄膜;使用高温热注射法合成出CsPbI₃量子点,再通过化学浴沉积法沉积CsPbI₃量子点到复合薄膜上,得到SiW₁₂/CsPbI₃/TiO₂纳米管复合薄膜,探究SiW₁₂沉积时间、CsPbI₃沉积次数对TiO₂纳米管光电性能的影响。利用扫描电子显微镜(SEM)、能谱仪(EDS)、透射电子显微镜(TEM)、X射线衍射(XRD)仪、红外分光光度计(FT-IR)、紫外-可见分光光度计(UV-Vis)对薄膜进行表征,使用电化学工作站测试薄膜的光电化学性能。结果表明:TiO₂纳米管沉积多酸SiW₁₂和CsPbI₃量子点后,光吸收范围扩大、电荷转移电阻降低,光电转换效率得到显著提升,最高达到0.52%。说明SiW₁₂和CsPbI₃的协同作用很好地抑制了TiO₂纳米管电子-空穴的复合,并拓宽了吸收光谱范围,提高了TiO₂纳米管的光电转换效率。

关键词: 二氧化钛纳米管, 电子-空穴复合, 吸收光谱, 多酸, CsPbI₃量子点, 复合薄膜, 光电转换效率

Abstract: In order to overcome the defects of high electron-hole recombination rate and narrow absorption spectrum range of TiO₂ nanotubes during photoelectric conversion, TiO₂ nanotubes were synergistically modified by polyoxometalates H₄SiW₁₂O₄₀ (SiW₁₂) and CsPbI₃ quantum dots. SiW₁₂/TiO₂ nanotube composite films were prepared by electrodeposition of SiW₁₂ on TiO₂ nanotubes. The CsPbI₃ quantum dots were synthesized by high temperature thermal injection method, and then the CsPbI₃ quantum dots were deposited on the composite films by chemical bath deposition method to obtain the SiW₁₂/CsPbI₃/TiO₂ nanotube composite films. The effects of SiW₁₂ deposition time and CsPbI₃ deposition frequencies on the photoelectric properties of TiO₂ nanotubes were investigated. The films were characterized by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and ultraviolet visible spectrophotometer (UV-Vis). The photochemical properties of the films were tested by electrochemical workstation. The results show that the photoelectric conversion efficiency of TiO₂ nanotubes deposited with polyoxometalates SiW₁₂ and CsPbI₃ quantum dots can be significantly improved by increasing the light absorption range and decreasing the charge transfer resistance up to 0. 52%. It shows that the synergistic effect of SiW₁₂ and CsPbI₃ can effectively inhibit the electron-hole recombination of TiO₂ nanotubes, broaden the absorption spectrum and improve the photoelectric conversion efficiency of TiO₂ nanotubes.

Key words: TiO₂ nanotube, electron-hole recombination, absorption spectrum, polyoxometalate, CsPbI₃ quantum dot, composite film, photoelectric conversion efficiency

中图分类号:

张博, 蔺明宇, 孙淑艳, 罗新泽. SiW₁₂、CsPbI₃协同提高TiO₂纳米管光电转换效率的研究[J]. 人工晶体学报, 2022, 51(6): 1034-1041.

ZHANG Bo, LIN Mingyu, SUN Shuyan, LUO Xinze. SiW₁₂ Cooperating with CsPbI₃ to Improve the Photoelectric Conversion Efficiency of TiO₂ Nanotubes[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2022, 51(6): 1034-1041.

参考文献

[1] 夏冬林,郭锦华.CuInS₂量子点敏化ZnO基光阳极的制备与性能研究[J].人工晶体学报,2020,49(12):2274-2281.
XIA D L, GUO J H. Preparation and properties of CuInS₂ quantum dot-sensitized ZnO based photoanode[J]. Journal of Synthetic Crystals, 2020, 49(12): 2274-2281(in Chinese).
[2] WANG J Y, ZHANG T J, WANG D F, et al. Influence of CdSe quantum dot interlayer on the performance of polymer/TiO₂ nanorod arrays hybrid solar cell[J]. Chemical Physics Letters, 2012, 541: 105-109.
[3] WALSH J J, BOND A M, FORSTER R J, et al. Hybrid polyoxometalate materials for photo(electro-) chemical applications[J]. Coordination Chemistry Reviews, 2016, 306: 217-234.
[4] CHEN L, CHEN W L, WANG X L, et al. Polyoxometalates in dye-sensitized solar cells[J]. Chemical Society Reviews, 2019, 48(1): 260-284.
[5] HE P, LI X H, WANG T, et al. Keggin-type polyoxometalate/thiospinel octahedron heterostructures for photoelectronic devices[J]. Inorganic Chemistry Frontiers, 2020, 7(14): 2621-2628.
[6] NISHIMOTO Y, YOKOGAWA D, YOSHIKAWA H, et al. Super-reduced polyoxometalates: excellent molecular cluster battery components and semipermeable molecular capacitors[J]. Journal of the American Chemical Society, 2014, 136(25): 9042-9052.
[7] LIU R, SUN Z X, ZHANG Y Z, et al. Polyoxometalate-modified TiO₂ nanotube arrays photoanode materials for enhanced dye-sensitized solar cells[J]. Journal of Physics and Chemistry of Solids, 2017, 109: 64-69.
[8] WELLS H L. Über Die cäsium-und kalium-bleihalogenide[J]. Zeitschrift Für Anorganische Chemie, 1893, 3(1): 195-210.
[9] XIAO J Y, SHI J J, LI D M, et al. Perovskite thin-film solar cell: excitation in photovoltaic science[J]. Science China Chemistry, 2015, 58(2): 221-238.
[10] ALLA M, MANJUNATH V, CHAWKI N, et al. Optimized CH₃NH₃PbI_3-xCl_x based perovskite solar cell with theoretical efficiency exceeding 30%[J]. Optical Materials, 2022, 124: 112044.
[11] FAN X J. Flexible dye-sensitized solar cells assisted with lead-free perovskite halide[J]. Journal of Materials Research, 2022, 37(4): 866-875.
[12] WANG S X, PANG S Z, CHEN D Z, et al. Improving perovskite solar cell performance by compositional engineering via triple-mixed cations[J]. Solar Energy, 2021, 220: 412-417.
[13] WANG P Y, LI R J, CHEN B B, et al. Gradient energy alignment engineering for planar perovskite solar cells with efficiency over 23%[J]. Advanced Materials, 2020, 32(6): 1905766.
[14] LIU N, YOU F T, JI C, et al. Bright all-solution-processed CsPbBr₃ perovskite light emitting diodes optimized by quaternary ammonium salt[J]. Current Applied Physics, 2021, 31: 60-67.
[15] ZHAO H F, CHEN H T, BAI S, et al. High-brightness perovskite light-emitting diodes based on FAPbBr₃ nanocrystals with rationally designed aromatic ligands[J]. ACS Energy Letters, 2021, 6(7): 2395-2403.
[16] WANG Z B, ZHU X D, JIA H R, et al. Blue perovskite light-emitting diodes: from material preparation to device optimization[J]. Chinese Journal of Luminescence, 2020, 41(8): 879-898.
[17] WANG P, XIE J S, XIAO K, et al. CH₃NH₃PbBr₃ quantum dot-induced nucleation for high performance perovskite light-emitting solar cells[J]. ACS Applied Materials & Interfaces, 2018, 10(26): 22320-22328.
[18] WANG Y W, ZHU Y H, HUANG J F, et al. CsPbBr₃ perovskite quantum dots-based monolithic electrospun fiber membrane as an ultrastable and ultrasensitive fluorescent sensor in aqueous medium[J]. The Journal of Physical Chemistry Letters, 2016, 7(21): 4253-4258.
[19] DOANE T L, RYAN K L, PATHADE L, et al. Using perovskite nanoparticles as halide reservoirs in catalysis and as spectrochemical probes of ions in solution[J]. ACS Nano, 2016, 10(6): 5864-5872.
[20] BAG A, RADHAKRISHNAN R, NEKOVEI R, et al. Effect of absorber layer, hole transport layer thicknesses, and its doping density on the performance of perovskite solar cells by device simulation[J]. Solar Energy, 2020, 196: 177-182.
[21] CORREA-BAENA J P, ABATE A, SALIBA M, et al. The rapid evolution of highly efficient perovskite solar cells[J]. Energy & Environmental Science, 2017, 10(3): 710-727.
[22] WU H L, SI H N, ZHANG Z H, et al. All-inorganic perovskite quantum dot-monolayer MoS₂ mixed-dimensional van der Waals heterostructure for ultrasensitive photodetector[J]. Advanced Science, 2018, 5(12): 1801219.
[23] JEAN J, XIAO J, NICK R, et al. Synthesis cost dictates the commercial viability of lead sulfide and perovskite quantum dot photovoltaics[J]. Energy & Environmental Science, 2018, 11(9): 2295-2305.
[24] GU K, ZHENG D Q, LI L J, et al. High-efficiency and stable piezo-phototronic organic perovskite solar cell[J]. RSC Advances, 2018, 8(16): 8694-8698.
[25] SINGH H, DEY P, CHATTERJEE S, et al. Formamidinium containing tetra cation organic-inorganic hybrid perovskite solar cell[J]. Solar Energy, 2021, 220: 258-268.
[26] LU C, LI H, KOLODZIEJSKI K, et al. Enhanced stabilization of inorganic cesium lead triiodide (CsPbI₃) perovskite quantum dots with tri-octylphosphine[J]. Nano Research, 2018, 11(2): 762-768.
[27] WANG W Z, LI J K, NI P J, et al. Improved synthesis of perovskite CsPbX₃@SiO₂ (X=Cl, Br, and I) quantum dots with enhanced stability and excellent optical properties[J]. ES Materials & Manufacturing, 2019, 4: 66-73.
[28] JIA D L, CHEN J X, MEI X Y, et al. Surface matrix curing of inorganic CsPbI₃ perovskite quantum dots for solar cells with efficiency over 16%[J]. Energy & Environmental Science, 2021, 14(8): 4599-4609.
[29] LI Y H, ZHOU S, XIONG Z Y, et al. Size modulation and heterovalent doping facilitated hybrid organic and perovskite quantum dot bulk heterojunction solar cells[J]. ACS Applied Energy Materials, 2020, 3(11): 11359-11367.
[30] XU S S, WANG Y H, ZHAO Y, et al. Keplerate-type polyoxometalate/semiconductor composite electrodes with light-enhanced conductivity towards highly efficient photoelectronic devices[J]. Journal of Materials Chemistry A, 2016, 4(36): 14025-14032.
[31] TANG Y, CHENG Y L, XU H, et al. Binary oxide nanofiber bundle supported Keggin-type phosphotungstic acid for the synthesis of 5-hydroxymethylfurfural[J]. Catalysis Communications, 2019, 123: 96-99.
[32] ZHENG H, WANG C H, ZHANG X T, et al. Control over energy level match in Keggin polyoxometallate-TiO₂ microspheres for multielectron photocatalytic reactions[J]. Applied Catalysis B: Environmental, 2018, 234: 79-89.
[33] SONGSIRI N, REMPEL G L, PRASASSARAKICH P. Liquid-phase synthesis of isoprene from MTBE and formalin using cesium salts of silicotungstic acid[J]. Molecular Catalysis, 2017, 439: 41-49.
[34] ANDERSON N C, HENDRICKS M P, CHOI J J, et al. Ligand exchange and the stoichiometry of metal chalcogenide nanocrystals: spectroscopic observation of facile metal-carboxylate displacement and binding[J]. Journal of the American Chemical Society, 2013, 135(49): 18536-18548.
[35] WHEELER L M, SANEHIRA E M, MARSHALL A R, et al. Targeted ligand-exchange chemistry on cesium lead halide perovskite quantum dots for high-efficiency photovoltaics[J]. Journal of the American Chemical Society, 2018, 140(33): 10504-10513.
[36] LUO X Z, LI F Y, XU B B, et al. Enhanced photovoltaic response of the first polyoxometalate-modified zinc oxide photoanode for solar cell application[J]. Journal of Materials Chemistry, 2012, 22(30): 15050-15055.

SiW₁₂、CsPbI₃协同提高TiO₂纳米管光电转换效率的研究

SiW₁₂ Cooperating with CsPbI₃ to Improve the Photoelectric Conversion Efficiency of TiO₂ Nanotubes

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